Loading...
Search for: ethanol
0.006 seconds
Total 117 records

    A general model for multicomponent transport in nonporous membranes based on Maxwell-Stefan formulation

    , Article Chemical Engineering Communications ; Volume 191, Issue 4 , 2004 , Pages 460-499 ; 00986445 (ISSN) Ghoreyshi, A. A ; Farhadpour, F. A ; Soltanieh, M ; Sharif University of Technology
    Taylor and Francis Ltd  2004
    Abstract
    A "general" model of membrane transport was formulated using the mechanistic Maxwell-Stefan approach and generalized driving forces, which included the contribution from the various internal and external driving forces. Transient models of dialysis and pervaporation were developed that used exactly the same general model to describe the transport through the membrane. In this model, the bulk solution/polymer equilibria were described by a modified Flory-Huggins model, and the concentration dependence of ternary Maxwell-Stefan diffusivities was described by a natural extension of the binary Vignes relationship to a multicomponent system. A notable advantage of the general model lies in the... 

    Multicomponent transport across nonporous polymeric membranes

    , Article Desalination ; Volume 144, Issue 1-3 , 2002 , Pages 93-101 ; 00119164 (ISSN) Ghoreyshi, S. A. A ; Farhadpour, F. A ; Soltanieh, M ; Sharif University of Technology
    Elsevier  2002
    Abstract
    The theoretical description of multicomponent transport across nonporous polymeric membranes was investigated using two alternative frameworks: the phenomenological approach of irreversible thermodynamics and the mechanistic Stefan-Maxwell formulation. The transport models developed account for potential equilibrium and/or kinetic coupling of fluxes and the contribution of diffusion induced non-selective flow within the polymer. The models were validated against transient dialysis and pervaporation data for the {ethanol-water}/silicone rubber system. A critical assessment was obtained by recovering the model parameters from the dialysis data and using the same parameters to predict the... 

    Modeling and Simulation of Alcoholic Fermentation of Sugarcane Blackstrap Molasses

    , M.Sc. Thesis Sharif University of Technology Soroush, Mohammad (Author) ; Yaghmaee, Sohila (Supervisor)
    Abstract
    Fed-batch fermentation is a valuable and cost-effective method for bio-based production of various products such as ethanol, which has various applications in various industries.In recent years, bioethanol production has been given special attention in many countries. For this reason, the mathematical modeling of production of these products is very important for their optimal and cost-effective production. Given the transient and dynamic nature of fermentation and its specific complexity, mathematical modeling of fed-batch bioreactors is difficult and complicated. In this research, an unstructured model was used to predict the production of ethanol from blackstrap sugar cane molasses based... 

    Electrophoretic deposition of titania nanoparticles in different alcohols: Kinetics of deposition

    , Article Journal of the American Ceramic Society ; Volume 94, Issue 8 , 2011 , Pages 2354-2361 ; 00027820 (ISSN) Farrokhi Rad, M ; Ghorbani, M ; Sharif University of Technology
    2011
    Abstract
    The suspension of titania nanoparticles in different alcohols (methanol, ethanol, and butanol) was prepared and triethanolamine (TEA) was used as a dispersant. The suspensions were characterized by different tests such as sedimentation, zeta potential, and Fourier transform infrared spectroscopy. The electrophoretic deposition (EPD) was performed at various voltages and times. EPD from butanolic suspension (0.8 g/L TEA) showed the slowest kinetics, because of the low electrophoretic mobility of titania nanoparticles in it (2.40 × 10-5 cm2·(V·s)-1). Also, it was observed that at low voltages (5, 10, and 20 V), the EPD kinetics from methanolic suspension (0 g/L TEA) was the fastest; however,... 

    Supercritical synthesis and characterization of graphene-pbs quantum dots composite with enhanced photovoltaic properties

    , Article Industrial and Engineering Chemistry Research ; Volume 54, Issue 30 , 2015 , Pages 7382-7392 ; 08885885 (ISSN) Tayyebi, A ; Tavakoli, M. M ; Outokesh, M ; Shafiekhani, A ; Simchi, A ; Sharif University of Technology
    American Chemical Society  2015
    Abstract
    Lead sulfide quantum dots (PbS QDs) were decorated onto a graphene surface in a semi-core-shell structure using supercritical ethanol. The temperature of ethanol played significant role in controlling size and agglomeration of QDs as well as the extent of reduction of graphene. Average size of the QDs was estimated by transmission electron microscopy to be around 3.96 nm and by quantum models to be about 4.34 nm. PbS QDs prepared at 330 °C were of high purity, and the yield was 99%. Instrumental and chemical analyses demonstrated formation of a strong bond between PbS QDs and graphene, through a Pb-O-C bridge. UV and photoluminescence measurements along with theoretical considerations... 

    Ethanol spray combustion under a MILD condition: a chemical kinetic study

    , Article Energy and Fuels ; Volume 33, Issue 11 , 2019 , Pages 11861-11886 ; 08870624 (ISSN) Karimi Motaalegh Mahalegi, H ; Mardani, A ; Sharif University of Technology
    American Chemical Society  2019
    Abstract
    Moderate or intense low-oxygen dilution (MILD) combustion of liquid fuels has attracted attention because of its advantages in industrial burners and gas turbine applications. Here, numerical investigation has been conducted on an experimental MILD turbulent spray burner. The H∥ flame of Delft spray in a hot co-flow burner is selected, and the Reynolds averaged Navier-Stokes/eddy dissipation concept framework with 40 species/180 reversible reactions through a skeletal chemical mechanism is used in addition to unsteady Lagrangian tracking of spray droplets to investigate the flame structure and chemical kinetic of reacting flow field. At first, current numerical results were compared with... 

    Turbocharged spark-ignition engine performance prediction in various inlet charged air temperatures fueled with gasoline–ethanol blends

    , Article International Journal of Engine Research ; Volume 22, Issue 7 , 2021 , Pages 2233-2243 ; 14680874 (ISSN) Farzam, R ; Jafari, B ; Kalaki, F ; Sharif University of Technology
    SAGE Publications Ltd  2021
    Abstract
    In this research, the effect of alternative fuels and the inlet charged air temperature is numerically investigated on the performance of a turbocharged spark-ignition engine. For this purpose, a one-dimensional engine and turbocharger model is created in an engine simulation and performance analysis software and validated with former experimental results. Then, the model is run with four fuel types, including two gasoline types with different octane numbers and two ethanol–gasoline blend fuels—E25 and E85. In each case, the inlet charged air temperature is changed from cold to hot condition and performance characteristics such as the spark advance timing, brake torque, brake-specific fuel... 

    Comparative assessment of bioethanol supply chain: insights from Iran

    , Article Biofuels ; Volume 12, Issue 4 , 2021 , Pages 475-483 ; 17597269 (ISSN) Haj Hasan, A ; Avami, A ; Sharif University of Technology
    Taylor and Francis Ltd  2021
    Abstract
    Biofuels are important alternative fuel in recent years. In this work, the bioethanol supply chain planning is performed by BioEnergy Supply Model to optimally find the best pathways using economic and environmental objective functions in Iran. Then, different sustainability criteria focusing on environmental, economic, and social concerns are assessed for possible routes of the bioethanol production from available resources. Although agriculture residues and wastes, decrease the greenhouse gas emissions but municipal solid wastes are more economic and require less water. The agricultural wastes and residues improve the sustainability. Then, criteria focusing on environmental, economic, and... 

    Continuous decolorization of anaerobically digested distillery wastewater

    , Article Process Biochemistry ; Volume 40, Issue 3-4 , 2005 , Pages 1323-1329 ; 13595113 (ISSN) Shayegan, J ; Pazouki, M ; Afshari, A ; Sharif University of Technology
    2005
    Abstract
    The aim of this research work was to decolorize anaerobically digested (UASB) and aerobically treated distillery wastewater of a process for ethanol production. An Aspergillus species isolated from the soil was used for decolorization. A sequential Plackett-Burman design in three stages was used for optimization of decolorization conditions. Both maximum decolorization and COD reduction under optimized conditions were obtained as 84%. By implementing the optimum values in a pilot scale of an activated sludge system a continuous process for decolorization was conducted. The decolorization efficiency of this system with 48 h retention time was about 75% in a limited period of 4 days. For... 

    AC characterization of three-dimensional reduced graphene oxide/molybdenum disulfide nanorose hybrids for ethanol vapor detection

    , Article Applied Surface Science ; Volume 520 , August , 2020 Mirmotallebi, M ; Iraji zad, A ; Sharif University of Technology
    Elsevier B. V  2020
    Abstract
    A novel AC impedance study on three-dimensional hybrid structures of graphene sheets/MoS2 nanorose (GMS) toward ethanol vapor detection is presented in this work. These defective 3D hybrid porous structures are sensitive to the presence of different gases as a result of charge transfer with gas species, as well as a change in the effective capacitance of the system. The sensing behavior of the samples is investigated throughout time-dependent impedance measurement and electrochemical impedance spectroscopy (EIS). The sensor response is estimated at about 20% to 10 ppm ethanol vapor, with the response and recovery times about 3.2 s and 0.8 s, respectively. Sensing mechanism proposed to... 

    Assessment of optimal reaction progress variable characteristics for partially premixed flames

    , Article Combustion Theory and Modelling ; Volume 26, Issue 5 , 2022 , Pages 797-830 ; 13647830 (ISSN) Chitgarha, F ; Ommi, F ; Farshchi, M ; Sharif University of Technology
    Taylor and Francis Ltd  2022
    Abstract
    The reaction progress variable is a crucial concept in the advanced flamelet combustion models. As a controlling variable, a well-defined progress variable must consider the essential features of the combustion process. It is usually a heuristically defined linear combination of some major chemical species mass fractions. However, such a simple definition could lead to inaccurate results for the fuel-rich reactive mixtures or complicated fuels, due to the vast number of chemical species in the combustion process. In this paper, a new method for generating a reaction progress variable is proposed through solving a constrained optimisation problem. The proposed method uses a genetic algorithm... 

    Nanocomposite with promoted electrocatalytic behavior based on bimetallic pd-ni nanoparticles, manganese dioxide, and reduced graphene oxide for efficient electrooxidation of ethanol

    , Article Journal of Physical Chemistry C ; Volume 122, Issue 18 , 2018 , Pages 9783-9794 ; 19327447 (ISSN) Rezaee, S ; Shahrokhian, S ; Amini, M. K ; Sharif University of Technology
    American Chemical Society  2018
    Abstract
    In this work, a nanocomposite containing manganese dioxide (MnO2) modified reduced graphene oxide (rGO) supported bimetallic palladium-nickel (Pd-Ni) catalyst is prepared by electrodeposition method. The nanocomposite modifier film is prepared by forming a thin layer of graphene oxide (GO) via drop-casting of GO nanosheet dispersion on glassy carbon electrode (GCE), followed by electrochemical reduction of the film to provide rGO/GCE. Then, a two-step potential procedure is applied to deposit MnO2 nanoparticles on rGO/GCE. At the optimum deposition conditions, MnO2 nanoparticles with a thickness of 30-50 nm homogeneously covered the rGO surface (MnO2/rGO/GCE). Finally, the bimetallic Pd-Ni... 

    Study and Fabrication of Electrical & Electromechanical Resonators Based on Nanostructures for Sensing Application

    , Ph.D. Dissertation Sharif University of Technology Fardindoost, Somayeh (Author) ; Iraji Zad, Azam (Supervisor) ; Sarvari, Reza (Supervisor) ; Mohajerzadeh, Shamsoddin (Co-Advisor)
    Abstract
    In this thesis we present fabrication, characterization, and experimental results describing electrical actuation and readout of the mechanical vibratory response of PVP, graphene-doped and ZnO fibers by employing electrical actuation. For a fiber resonator with an approximate radius of 850 nm and length of 100 µm, we observed a resonance frequency around 580 kHz with a quality factor (Q) of about 2511 in air at ambient conditions. Through the use of finite element simulations, we show that the reported frequency of resonance is relevant. Also, the measurements were performed in an enclosed chamber with controlled levels of ethanol vapor. The adsorption of ethanol causes a shift in the... 

    The Effect of Solvent Type on the Characteristic of TiO2 Nanometric Coatings Produced by Electrophoretic Method

    , M.Sc. Thesis Sharif University of Technology Farrokhi Rad, Morteza (Author) ; Ghorbani, Mohammad (Supervisor)
    Abstract
    Titania is semiconductor material and have many applications including photocatalysis, photochromic, air and water purification, sensors, and solar cell. In electrophoretic deposition, charged particles dispersed in a stable suspension move towards an oppositely charged electrode, and form dense layer of deposit on it. In this investigation electrophoretic deposition of titania nano-particles in suspensions prepared by different solvents (methanol, ethanol and butanol) with and without dispersant (triethanolamine and polyethylenimine), was studied. Well stabilized suspensions, prepared for electrophoretic deposition. The effects of solvent type, additive concentration, mechanism of particles... 

    An Investigation of SI Engine Performance Characteristics Changes under Fuel Switch from Gasoline to Bioethanol

    , M.Sc. Thesis Sharif University of Technology Imani, Amin (Author) ; Hosseini, Vahid (Supervisor) ; Shafii, Behshad (Supervisor)
    Abstract
    Alternative fuels are considered as a solution to increase energy security, reduce dependence on conventional fossil fuels (gasoline and diesel), and reduce greenhouse gas emissions. In this context, bioethanol has been very much considered in recent years. This fuel is combined with gasoline and used by cars. Flexible fuel vehicles are cars that can be used in various blend of gasoline and ethanol. Ethanol has a higher octane number than gasoline, and its mixture with gasoline increases the number of octane fuels. However, this fuel has a lower thermal energy than gasoline, which increases the fuel consumption of ethanol and gasoline relative to pure gasoline. The purpose of this study is... 

    Fabrication and Characterization of Hydrogen Gas sensors Based on Metal Oxides/Carbon Nanotubes Hybrid System

    , Ph.D. Dissertation Sharif University of Technology Ghasempour, Roghayeh (Author) ; Iraji zad, Azam (Supervisor) ; Taghavinia, Nima (Supervisor)
    Abstract
    We have studied binary structures contain; as grown thin film of carbon nanotubes (CNTs) , CNT rich polymeric composite, Pd doped WO3 thin film, and also hybrid thin film which was mixed CNTs and WO3 nanoparticles and ternary structure which was obtained by adding Pd to hybrid structure as a hydrogen gas sensor. The structure, morphology, chemical composition and quality of as–grown and functionalized CNTs and sensitive films were studied by SEM, TEM, XRD, XPS, DLS, FTIR and Raman spectroscopy methods. Variation of film’s electrical resistance after exposure gases is utilized as the principle of gas sensing. Multi-Walled Carbon Nanotube (MWCNTs) films were obtained by Thermal Chemical Vapor... 

    Investigation of Fuel Physical Properties Change Effects on Performance of Fuel Delivery Systems of Si Engine

    , M.Sc. Thesis Sharif University of Technology Abdolalinejad Shiramin, Majid (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    Ethanol is a promising alternative fuel in terms of addressing future energy and environmental problems, so we can use ethanol as a fuel in passenger cars to eliminate enviremental problems. in this study, the CEV13-038 injector from ACRUS company is modeled. the research purpose is focused on the effect of ethanol , geometrical parameters, and the fuel type on the injected mass quantity and on turning the fuel supply system from a gasoline based system to ethanol based one.
    In the first step of this study, The effect of ethanol, fuel temperature, needle lift, nozzle diameter and number of nozzles... 

    Numerical Investigation of Turbulent Spray Combustion in Hot Diluted Co-Flow

    , Ph.D. Dissertation Sharif University of Technology Karimi Motaalegh Mahalegi, Hamed (Author) ; Mardani, Amir (Supervisor)
    Abstract
    The Moderate or Intense Low-oxygen Dilution (MILD) combustion of liquid fuels has attracted attention to use its advantages in industrial burners and gas turbines applications. Here numerical investigation has been conducted on a research experimental MILD turbulent spray burner (Deft Spray in Hot Co-flow, DSHC). RANS approach has been adopted for modeling of the reactive turbulent flow field of continues phase with the Lagrangian approach for droplet modeling of pressure-swirl atomizer fuel spray. The EDC combustion model is used which has the ability to take into account the detailed chemical mechanisms. The accuracy of different turbulence and droplet injection sub-models are examined and... 

    Simultaneous Impact of Multiple Boiling Droplets on a Molten Phase Change Material as a Direct-Contact Solidification Method

    , M.Sc. Thesis Sharif University of Technology Poureslami, Parham (Author) ; Shafii, Mohammad Behshad (Supervisor)
    Abstract
    Encompassing an interaction between the phase change material (PCM) and the droplets of a heat transfer fluid, the direct contact (DC) method provides a state-of-the-art solution for the meager melting and solidification rates of PCMs. In the DC procedure, when impinging on the molten PCM pool, droplets evaporate, solidifying the portion of the PCM. For the first time, the impact of single and simultaneous double ethanol droplets, having an average diameter of 2.68 mm, on the molten paraffin wax has been scrutinized exhaustively. Experiments have been carried out through high-speed imaging for various Weber numbers ranging from 179 to 464, pool temperatures from 70 to 95°C, and horizontal... 

    Fire dynamics simulation of multiple ethanol poll fires

    , Article Research Journal of Chemistry and Environment ; Volume 17, Issue 9 , 2013 , Pages 3-9 ; 09720626 (ISSN) Abdolhamidzadeh, B ; Bab, V ; Rashtchian, D ; Reniers, G ; Sharif University of Technology
    2013
    Abstract
    In this study, a well-known Computational Fluid Dynamics software, so-called Fire Dynamics Simulator (FDS), has been used to simulate multiple ethanol pool fire scenarios. Influences and reciprocal impacts in terms of dynamics and growth of the pool fires have been investigated. Heat release rates temperature and flame shapes have been monitored as the main outputs of the simulations. Based on the simulation results, it can be concluded that the amounts of mass burning rate, the radiation energy and the pool fire flame height were significantly higher in multiple pool fires, when compared with the theoretical values obtained by the mere summation of single pool fires. Furthermore, the...