Sharif Digital Repository

Absorber is an important component in absorption machines and its characteristics have significant effects on the overall efficiency of absorption machines. This article reports a model of simultaneous heat and mass transfer process in absorption of refrigerant vapor into a lithium bromide solution of water - cooled vertical plate absorber in the Reynolds number range of 5 < Re < 150. The boundary layer assumptions were used for the transport of mass, momentum and energy equations and the fully implicit finite difference method was employed to solve the governing equations in the film flow. Dependence of lithium bromide aqueous properties to the temperature and concentration and film... 

Hydrophobic titania nanoparticles were synthesized by a novel in situ sol-gel method and applied in a single drop liquid-liquid extraction column to enhance the overall dispersed-phase mass transfer coefficient (Kod). The chemical system of toluene, acetic acid and water was used, and the direction of solute (acetic acid) mass transfer was from dispersed phase, including: toluene and acetic acid to the continuous phase of water. For such system, much of the mass transfer resistance exists in the dispersed phase, which is nonpolar organic liquid. Hence, modified titania nanoparticles (MTNP's), prepared by sol-gel route, in five different concentrations of 0.001–0.005 wt.% were added in the... 

In this article, a comprehensive 2D mathematical model has been developed to simulate process intensification of carbon dioxide absorption in the presence of nanoparticles in hollow fiber membrane contactors (HFMCs). The influences of nanoparticle were taken into account considering Brownian motion and Grazing effect as dominant phenomena of mass-transfer enhancement in nanofluids. The obtained simulation results were validated against experimental data reported in the literature and excellent agreement was obtained. It was found that by adding 0.05 wt % silica nanoparticles, the absorption rate could be enhanced by 16%, while the corresponding value is 32% for CNT nanoparticles. High... 

In this research, a continuous microsolvent extraction-reaction was developed for the efficient separation of calcium ion. This study gives a preliminary possible practical application of microfluidic devices in chemical exchange reaction for enrichment of 48Ca stable isotope. For this purpose, in the first stage, the hydrodynamic behavior of two immiscible liquids in a simple Y-shaped microfluidic junction is experimentally investigated, and then ion-pair extraction-reaction of Ca2+ using picric acid as a counter-ion and dicyclohexano-18-crown-6 (DC18C6) as a lipophilic ionophore is studied in this microfluidic and conventional batch method. The impact of main process parameters, including... 

In this study, mass transfer experimental data from the present column with 70 cm active column length and 11.3 cm internal diameter were interpreted for molybdenum extraction with a mixture of D2EHPA and TBP in terms of the axial diffusion model. The influence of extractants concentration and the initial aqueous pH have studied in the bench-scale experiments. The experimental finding demonstrated that the synergistic solvent extraction increases the constancy of the extracted complexes for transfer into the organic phase. The effect of operating parameters, including agitation speed and inlet phase velocities on the overall mass transfer coefficients under the chemical reaction system, is... 

In the present work we studied the use of a membrane contactor system for simultaneous absorption of H2S and CO2 from a gas mixture similar to natural gas. MDEA solution and mixtures of MDEA/DEA and MDEA/MEA were used as absorbent liquid. PVDF and PSf hollow fiber membranes were used in the membrane contactor modules. Design of experiments were carried out by Taguchi method in a manner that a systematical investigation of the effect of operational parameters (temperature, pressure, gas and liquid flow rates, absorbent concentration and acid gas content of the feed), in addition to the effect of membrane material and absorbent liquid, was implemented on process performance parameters... 

Mass-transfer rates to and from drops in liquid-liquid extraction processes are often reduced by the presence of contaminants. To design an industrial extractor, it is essential to consider this contamination effect in a quantitative manner. To achieve this goal, an experimental investigation was conducted on the mass transfer into single drops for n-butanol-succinic acid-water, as the recommended test system by the European Federation of Chemical Engineering (EFCE). The effects of anionic (sodium dodecyl sulfate, SDS), cationic (dodecyl trimethyl ammonium chloride, DTMAC), and nonionic (octylphenol decaethylene glycol ether, Triton X-100) surfactants on the hydrodynamic and mass-transfer...