Sharif Digital Repository

In this article, a comprehensive 2D mathematical model has been developed to simulate process intensification of carbon dioxide absorption in the presence of nanoparticles in hollow fiber membrane contactors (HFMCs). The influences of nanoparticle were taken into account considering Brownian motion and Grazing effect as dominant phenomena of mass-transfer enhancement in nanofluids. The obtained simulation results were validated against experimental data reported in the literature and excellent agreement was obtained. It was found that by adding 0.05 wt % silica nanoparticles, the absorption rate could be enhanced by 16%, while the corresponding value is 32% for CNT nanoparticles. High... 

In this research, a continuous microsolvent extraction-reaction was developed for the efficient separation of calcium ion. This study gives a preliminary possible practical application of microfluidic devices in chemical exchange reaction for enrichment of 48Ca stable isotope. For this purpose, in the first stage, the hydrodynamic behavior of two immiscible liquids in a simple Y-shaped microfluidic junction is experimentally investigated, and then ion-pair extraction-reaction of Ca2+ using picric acid as a counter-ion and dicyclohexano-18-crown-6 (DC18C6) as a lipophilic ionophore is studied in this microfluidic and conventional batch method. The impact of main process parameters, including... 

In this study, the mass transfer evaluation of an agitated liquid-liquid system for the extraction of molybdenum and tungsten from aqueous sulfate solution was investigated. It was found from batch experiments for separation of molybdenum from tungsten that the initial aqueous pH, Cyanex272 and D2EHPA concentration, contact time, dispersed phase volume fraction and impeller speed were optimized at 1.3, 0.07 M, 0.29 M, 15 min, 0.09 and 280 rpm, respectively. The results indicate that a suitable composition for stripping is 1.5 M NH4OH and 0.6 M NH4F. Furthermore, a modified correlation based on dimensionless numbers was derived for the prediction of continuous phase mass transfer in the... 

This paper deals with mathematical modeling and simulation of methanol carbonylation reactor in acetic acid production plant that consisted of a continuous stirred tank reactor (CSTR), a flash drum, a Joule-Thomson valve, and a condenser. The model was based on material and energy balances that considered liquid-gas mass transfer, thermodynamics, and reactor hydrodynamics. The most important aspect of the model was the selection of an appropriate correlation for prediction of mass transfer coefficient. Several correlations were examined and comparison of the model results with plant data indicated that the correlation reported by Lemoine was most appropriate. The simulation results were... 

In this study, the mass transfer evaluation of an agitated liquid-liquid system for the extraction of molybdenum and tungsten from aqueous sulfate solution was investigated. It was found from batch experiments for separation of molybdenum from tungsten that the initial aqueous pH, Cyanex272 and D2EHPA concentration, contact time, dispersed phase volume fraction and impeller speed were optimized at 1.3, 0.07 M, 0.29 M, 15 min, 0.09 and 280 rpm, respectively. The results indicate that a suitable composition for stripping is 1.5 M NH4OH and 0.6 M NH4F. Furthermore, a modified correlation based on dimensionless numbers was derived for the prediction of continuous phase mass transfer in the... 

A research investigation of the overall mass transfer coefficients, holdup and mean drops of dispersed phase as well as slip and characteristic velocities were carried out in the pulsed scale-up column with disc and doughnut structure for extraction of tellurium and selenium from a hydrochloric acid medium with TBP extractant. The impact of operating conditions containing the pulse intensity, inlet aqueous and solvent phase velocities have been studied on the mass transfer rates, and the special column characteristic. By considering the reactive extraction situations, modified models were derived for predicting of holdup, d32, and slip velocity in this extractor. The axial diffusion model... 

In this study, mass transfer experimental data from the present column with 70 cm active column length and 11.3 cm internal diameter were interpreted for molybdenum extraction with a mixture of D2EHPA and TBP in terms of the axial diffusion model. The influence of extractants concentration and the initial aqueous pH have studied in the bench-scale experiments. The experimental finding demonstrated that the synergistic solvent extraction increases the constancy of the extracted complexes for transfer into the organic phase. The effect of operating parameters, including agitation speed and inlet phase velocities on the overall mass transfer coefficients under the chemical reaction system, is... 

The influence of fluid flow on the corrosion of simple carbon steel ST37 (AISI 1020) in aqueous solution of Bandar-Abbas gas well was studied at 25°C under air-saturated condition. The mechanism and kinetic of corrosion in different hydrodynamic conditions were determined using a rotating disk electrode. Increasing the velocity of rotating disk ≤ 1000 rpm caused an augmentation in corrosion rate from 9.89 to 18.95 mill in./yr. Increasing the velocity beyond 1000 rpm changed the corrosion mechanism so that the activation polarization will control the corrosion process, and the variation in corrosion rates was due to various corrosion mechanisms rather than mass transfer of reactant component.... 

The prediction of mass-transfer rates into and from moving drops in the liquid-liquid systems has usually used the well-known Whitman two-film theory approach. According to the latter, the total resistance to mass transfer resides on each side of the interface and is described by the individual film mass-transfer coefficients for the continuous and dispersed phases in the absence of surface-active agents (contaminants). In the present work, the same approach has been used to model the excess mass-transfer resistance exerted by surface-active agents in the continuous phase. To achieve this goal, an experimental investigation has been conducted on the mass transfer into and from single drops... 

An attempt was made to introduce a new approach for evaluating mass transfer during drop formation via definition of a parameter related to the extent of the convective mixing within the growing drop. For this purpose it was assumed that the entrance of the dispersed flow into the growing drop from the nozzle is analogous to the entrance of the flow from a smaller channel to a larger one. This transfer mechanism has been dubbed the "flow expansion." A global time-dependent Reynolds number of growing drop (Regd) was defined based on the equivalent diameter of growing drop as a length scale and also on a velocity scale, which is obtained using this flow expansion assumption. The results show... 

Although there is extensive experimental, theoretical and numerical research on dynamics of drop formation in liquid-liquid systems, the evaluation of mass transfer during drop formation is rather complex and there has been little research on that. The various mathematical models developed for this problem are generally based on a solution of the diffusion equation without any allowance for circulation within the drop. This is the main reason for the poor prediction of these models in many cases for which internal convection has an important effect on mass transfer rate. In this paper an attempt was made to define a parameter related to the extent of the convective mixing within the growing... 

In this study, in order to investigate the effect of the underlying pore-scale processes on continuum scale simulations of porous media dissolution, we improve the standard Lattice Boltzmann method using Quadtree grid refinement approach to simulate fluid flow and reactive transport through large domain sizes. Our results have shown considerable computational improvements up to 80% in simulation time together with increased numerical accuracy. The results and the added value of the new approach are discussed using comparison of our model with the conventional LBM. Moreover, we have applied a systematic analysis by increasing complexity levels and starting from fluid flow and continuing with... 

In this survey, the reactive mass transfer data are determined for extraction technique in the modified rotating disc column. Mathematical models are investigated to compute the mass transfer coefficients of the dispersed phase. An increase in the dispersed phase holdup from 0.85 to 0.12 and a decrease in droplet diameter from 2.24 to 0.74 mm are observed with increasing rotation speed from 170 to 410 rpm in the optimized system. The experiments showed that the optimum transport efficiency in rotor speed of 410 rpm in this column is equal to 98.85% and 99.45% for extraction and stripping stages, respectively. The model's achievement is compared with the solvent extraction data and a...