Sharif Digital Repository

Injecting low salinity brines is regarded as an enhanced oil recovery (EOR) process through IFT reduction. However, the exact mechanism behind this process is an unsettled and complex issue that has not been well understood yet, especially for heavy crude oil system. Besides, limited information is available regarding the key heavy oil/brine interfacial tension (IFT). The present study aims to investigate the sensitivity of dead heavy crude oil/brine IFT to a wide range of properties/conditions and to reveal the underlying physicochemical mechanisms involved in enhanced oil recovery and IFT reduction by low salinity water injection into heavy oil reservoir. IFT was measured as a function of... 

In this work, a new model based on multilayer kinetic adsorption mechanism has been proposed to account asphaltene adsorption in porous media under dynamic condition and the model was verified using experimental data obtained in this work and also with those reported in the literature. In the proposed model two steps are considered for asphaltene adsorption. The first step is taken as adsorption of asphaltenes on the surface of the porous media and the second step is taken as adsorption of asphaltenes on the asphaltenes already adsorbed on the porous media. The Crank-Nicholson method, central difference in space and trapezoidal rule in time, giving second order convergence in time was... 

Discrete ordinates method relies on approximating the integral term of the transport equation with the aid of quadrature summation rules. These quadratures are usually based on certain assumptions which assure specific symmetry rules and transport/diffusion limits. Generally, these assumptions are not problem-dependent which results in inaccuracies in some instances. Here, various methods have been developed for more accurate estimation of the independent angle in S2 approximation, as it is tightly related to valid estimation of the diffusion coefficient/length. We proposed and examined a method to reduce a complicated problem that usually is consisting many energy groups and discrete... 

Among various chemical methods, alkaline flooding has a great potential for enhancing heavy oil recovery, especially for reservoirs which contain acidic crude oil. However, fundamental understanding about microscopic displacement mechanisms and macroscopic behavior during alkaline floods at different wettabilities is not well understood, especially in five-spot shaly models. In this work several alkaline floods are performed on a glass micromodel containing randomly distributed shale streaks at different wettability conditions. Various mechanisms responsible for enhancing heavy oil recovery during alkaline flooding are investigated at different wettability conditions. These mechanisms... 

Microstructural characteristics and mechanical properties of a friction stir welded cast aluminum bronze (Cu-9Al-1Fe), produced by a sand casting method, have been investigated at tool rotation of 850-1500 rpm and traverse speed of 50-100 mm/min. Refinement of the primary coarse cast microstructure in the base metal was seen after friction stir welding. Microstructure of the stir zone was characterized in four distinct areas of non-isometric fine grains while a significant grain growth was noticed in some of the areas. Conditions of grain growth are defined with high heat input intensity and low heat transfer capability. The grain size was observed to decrease after FSW, resulting in a... 

The classical continuum theory not only underestimates the stiffness of microscale structures such as microbeams but is also unable to capture the size dependency, a phenomenon observed in these structures. Hence, the non-classical continuum theories such as the strain gradient elasticity have been developed. In this paper, a Timoshenko beam finite element is developed based on the strain gradient theory and employed to evaluate the mechanical behavior of microbeams used in microelectromechanical systems. The new beam element is a comprehensive beam element that recovers the formulations of strain gradient Euler–Bernoulli beam element, modified couple stress (another non-classical theory)... 

We investigate the effect of wall roughness on water electrolyte transport characteristics at different temperatures through carbon nanotubes by using nonequilibrium molecular dynamics simulations. Our results reveal that shearing stress and the nominal viscosity increase with ion concentration in corrugated carbon nanotubes (CNTs), in contrast to cases in smooth CNTs. Also, the temperature increase leads to the reduction of shearing stress and the nominal viscosity at moderate degrees of wall roughness. At high degrees of wall roughness, the temperature increase will enhance radial movements and increases resistance against fluid motion. As the fluid velocity increases, the particles do not... 

In order to simulate the performance of pure methane in chemical looping using iron-based oxygen carrier, simultaneously production of three pure streams of hydrogen, nitrogen and carbon dioxide has been investigated. For this purpose, proper operating conditions have been discussed for maximum production of hydrogen, complete consumption of oxygen of inlet air and complete combustion of methane. Professional software is used to simulate the chemical looping reactors and optimize their output streams. Results show that in this process each mole of methane fuel can produce 2.533, 2.65 and 0.99 mol of pure N 2, H2 and CO2, respectively which contributes 80.2% energy conversion of CH4 to H2.... 

In this paper, a new mechanism of heat transfer is introduced. It is shown that, without emission and absorption of photons, light can operate as a channel of heat transfer between nano- or micro-mechanical oscillators. We consider the dynamics of two vibrating mirrors coupled through one optical cavity mode in an optomechanical system. It is shown that light mediates heat transfer between two micro-mirrors. When the detuning frequency of the mechanical resonators is low, fluctuations flow through the light channel from the high temperature vibrating mirror toward the low temperature one. This behavior is named the resonance heat transfer effect. The rate of heat flow between the mechanical... 

In this work, examinations on the microstructure and mechanical properties of plain carbon steel and AISI 430 ferritic stainless steel dissimilar welds are carried out. Welding is conducted in both autogenous and using ER309L austenitic filler rod conditions through gas tungsten arc welding process. The results indicate that fully-ferritic and duplex ferritic-martensitic microstructures are formed for autogenous and filler-added welds, respectively. Carbide precipitation and formation of martensite at ferrite grain boundaries (intergranular martensite) as well as grain growth occur in the heat affected zone (HAZ) of AISI 430 steel. It is found that weld heat input can strongly affect grain... 

The so-called enriched weight functions (EWFs) are utilized in mesh-free methods (MMs) to solve linear elastic fracture mechanics (LEFM) problems; the following issues are of concern: convergence behavior; sufficiency of EWFs to capture singular fields around the crack-tip; and the preservation of the J-integral path-independency. EWFs prove useful in conjunction with the moving least square reproducing kernel method (MLSRKM); for this purpose, both EWFs and MLSRKM are modified. Since EWFs are not truly representative of the near-tip solution, fully EWFs (FEWFs) are introduced. Finally, some descriptive examples address the aforementioned concerns and the accuracy and efficacy of the... 

The nonlinear free and forced bending vibration of sandwich plates with incompressible viscoelastic core is investigated under the effects of different source of nonlinearities. For the core constrained between stiffer layers, the transverse shear strains, as well as the rotations are assumed to be moderate. The linear and quadratic displacement fields are also adopted for the in-plane and out-of-plane displacements of the core, respectively. The assumption of moderate transverse strains requires a nonlinear constitutive equation which is obtained from a single-integral nonlinear viscoelastic model using the assumed order of magnitudes for linear strains and rotations. The 5th-order method... 

Compound 3-benzyl-2H-pyrano[3,2-c]chromene-2,5(6H)-dione(3), was prepared and fully characterized. The vibrational modes (FT-IR) and NMR data ( 1H and 13C chemical shifts) were compared with the results of Density Functional Theory (DFT) method at the B3LYP/cc-PVTZ level. The calculated vibrational frequencies and NMR chemical shifts are in good agreement with the experimental results. The electronic (UV-Vis) spectrum was calculated using the TD-DFT method in CH2Cl2 with the Polarizable Continuum Model using the integral equation formalism variant (IEFPCM) and was correlated to the experimental spectra. The assignment and analysis of the frontier HOMO and LUMO orbitals indicate that... 

Hydroxyapatite (HA) coatings in and onto anodized TiO2 nanotube arrays were presented and prepared by electrophoretic deposition technique (EPD). Coatings were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). EPD proved to be an innovative and versatile technique to coat HA on and into nanotubular structures of TiO2 with enhanced adhesion between nanotubes and HA particles provided by mechanical interlocking. After EPD of HA on TiO2 layer, samples were sintered at 400 °C, 600 °C and 800 °C for 2 h in an Ar atmosphere. Effect of EPD processing parameters on thickness of the deposits and rate of deposition was elucidated for HA coatings on the nanotubular TiO2... 

Knowledge of process parameters during and after hot rolling is a significant requirement in order to produce a material with the desired microstructures and mechanical properties. In continuous hot rolling mills, different stages may exist, including water descaling, rolling stands, interstand sections, and run-out table. In each of these sections, various thermal and/or mechanical conditions are applied on the rolling metal that would affect material response in successive stages. In other words, an integrated model should be employed in hot rolling operations to evaluate metal behavior and microstructural events at the same time. Therefore, the thermal-mechanical response as well as... 

Self compacting concrete (SCC), as an innovative construction material in concrete industry, offers a safer and more productive construction process due to favorable rheological performance which is caused by SCC's different mixture composition. This difference may have remarkable influence on the mechanical behavior of SCC as compared to normal vibrated concrete (NVC) in hardened state. Therefore, it is vital to know whether the use of all assumptions and relations that have been formulated for NVC in current design codes are also valid for SCC. Furthermore, this study presents an extensive evaluation and comparison between mechanical properties of SCC using current international codes and... 

The 1050 aluminum sheets are severely deformed by two passes of the constrained groove pressing (CGP) process to obtain the strain of 2.32. Friction stir processing (FSP) is then performed on these specimens at two conditions of with and without SiC nanoparticles. Microhardness measurements indicate that in the state of FSP without any particle, the microhardness of stir zone is decreased due to the recrystallization and grain growth occurrence because of high stored strain energy in the CGPed specimens. In order to enhance the mechanical properties of the stir zone, SiC nanoparticles are used during FSP. Also, the effect of FSP pass number on the distribution of nanoparticles is... 

In this study, different concentrations of ascorbic acid (50, 100 and 200 μg/mL) were added to the liquid phase of a calcium phosphate cement (CPC). The cements were immersed in simulated body fluid (SBF) for different intervals and physical, physicochemical and mechanical properties of them were evaluated. The release of added ascorbic acid from CPCs into the SBF solution was also studied. From the results, both setting time and injectability of CPC decreased by adding ascorbic acid, however the compressive strength was sharply increased before soaking in SBF solution. But, the compressive strength values of all cements (with or without ascorbic acid) soaked in SBF solution for more than 7... 

Metropolitan areas consist of complicated systems of interconnected infrastructures that are highly interdependent. Disruption of one infrastructure may induce disruption in other interconnected ones. The results from analysis of one infrastructure as an independent system are not realistic without considering the behavior of other interconnected infrastructures. Consequently, the study of the interdependencies among critical infrastructures is important for addressing the cascading effects of a failed infrastructure on the entire network to properly model its performance and help the disaster management team in decision making. In this study, the extended Petri net and Markov chain have... 

This paper presents and discusses the effect of maximum size of coarse aggregate on fracture characteristics and brittleness of self-compacting concrete (SCC). Based on an experimental program, a series of three point bending tests were carried out on 86 notched beams, as recommended by RILEM. For all mixes, the parameters were analyzed by the work-of-fracture method (WFM) and by the size effect method (SEM) and consequently a correlation between these methods was obtained which is used to calibrate cracking numerical models. Test results showed that with increase of size of coarse aggregate, (a): fracture energies of GF in WFM and Gf in SEM increase which may be explained by the change in...