Sharif Digital Repository

In this project, graphene oxide was produced by chemical method (modified hummers method) because of simplicity and reproductiblity in the manufacuring process. Zinc nanoparticles were produced from pure zinc anode in the graphene oxide solution (anodic dissolution). Nanocomposite coating of reduced graphene oxide – zinc was created by electrochemical reduction with voltage pulse. Optimization of corrosion current density of the coating was done by design of experiments software (central composite design). To achieve this goal, several parameters such as cycles of zinc dissolution, frequency, duty cycle, total time of coating and applied voltage were examined. Using analysis of variance... 

Friction Stir Processing (FSP) was used to fabricate Al1050/Fe3O4 nanocomposite in three different weight percent (2.5%, 4% and 5.3%). The effects of rotational speed (1200-1600 rpm), traverse speed (5-15 cm/min) and the number of FSP passes (1, 2, 3 and 6 passes) on microstructure and mechanical properties were investigated. In order to study microstructure evolution, optical and field emission scanning electron microscopes were used. Micro hardness, longitudinal and transverse tensile and wear test were carried out to investigate mechanical properties of the obtained composites. Results showed that increase of the rotational speed and decrease of the traverse speed in 1 pass processed... 

Many regulations have been introduced over the world to urge the elimination of lead and lead containing solders, due to increasing pressure of the environmental and health concerns associated with lead-containing solders in the electronics industry. Therefore, efforts to develop and promote lead-free soldering have recently intensified. Conventional solder technology may not guarantee the required performance at such pitches due to problems such as higher diffusivity and the softening nature of the solder. To solve these problems, efforts have been made to develop solders with a low melting point, higher strength, better microstructure properties, and high creep resistance. Recently... 

In this study, copper-alumina composite specimens with different reinforcement content were produced in two routes, i.e. in-situ and ex-situ; one specimen as functionally graded material (FGM) was also produced. In first method, copper and aluminum powders were initially alloyed by mechanical alloying route and then the copper oxide powder was added as oxidizer. For the fabrication of Cu-Al2O3 composites using ex-situ method, alumina nano particles powder was added to elemental copper powder. FGM specimen consists of five layers, i.e. pure copper, copper matrix composite having 2, 3, 4, and 5 volume percent alumina. To reduce the particles agglomeration and homogeneous distribution of... 

Electrocodeposition of Ni-TiO2 nanocomposite single layers and Ni-TiO2/TiO2 multilayers from Watts bath containing TiO2 sol has been carried out on copper substrate. Cyclic voltammetry and chronoamperometry techniques were applied to study the influence of nickel sulfate and TiO2 sol concentrations on the electrochemical behavior of Ni-TiO2 deposition by direct current. The results clearly showed that at lower sulfate concentrations, the electrodepostion is a diffusion controlled process. Besides, the nucleation mechanism of the nanocomposites at low overpotentials followed the progressive system while at higher overpotentials, it was found to be instantaneous with three-dimensional growth... 

Hot deformation behavior of Al-SiC nanocomposites was investigated in this study. Aluminum powders with mean size of 60 micron and SiC nanopowders (mean size of 45nm) in amounts of 1 and 2 volume percents, as reinforced part, were mixed and milled for 40 hours by planetary ball mill. After degassing at 450 oC for 1 hour, milled powders were pressed into Aluminum cans (in Argon atmosphere) and then hot extruded. Extrusion ratio was 1:14. High density billets (with 98% of theoretical density) were produced because of that high extrusion ratio. TEM microstructure studies showed that fine distribution of reinforcements and Aluminum Oxides obtained via this procedure. Hardness and Uniaxial... 

Recently, due to the increase of environmental concerns, a significant raise in applying films and packaging containers, pollution produced from petroleum-based plastics packaging and problems arising from the various methods of waste disposal, the researchers have concentrate to replace these materials with biodegradable ones. In this study, a nanocomposite based on alloy matrix of thermoplastic starch and polyethylene which is reinforced with different amounts of Montmorillonitenanoclay has been constructed by the extrusion process. Furthermore, in order to increase the compatibility between the polar and non-polar components in the group of samples, compatibilizer was used and its... 

In this research a copper- Tungsten carbided nanocomposite coating prepared by electrodeposition from a sulfate bath in order to increase the hardness and erosion resistance of cooper without loosing cooper's specific physical properties as like as electrical and thermal conductivity. Various parameters were evaluated for finding significant factors in electrodeposition of Cu-Co/WC composite. Current density and concentration of WC and SDS were selected as affective factors. The morphology and structure were characterized by XRD and SEM. The mechanical properties of the coatings, such as hardness, wear resistance and surface roughness were studied with Vickers hardness indentation; pin on... 

In this study, the ultrafine-nanometric yttria stabilized zirconia (YSZ) particles were used for reinforcing of copper metal powder. To producing of bulk nanocomposite specimens, the copper powder and the proper volume percent of reinforcement powders (i.e. 2, 3 and 5) were mixed using Turbula mixer for one hour. Before the mixing of two metallic powders and ceramic nanoparticles, for separation of agglomerated zirconium oxide nanoparticles that witch leads to producing of nanocomposite specimens with satisfactorily distributed secondary phase, the ultrasonic devise with enough quantity of ethanol as neutral liquid have been used for 15 minutes. The powders mixture have been placed under... 

Due to the negative effects of conventional plastics on the environment, especially in the packaging sector, extensive efforts have been put to replace these polymers with biodegradable polymers. Starch is one of the biodegradable polymers which has attracted a lot of attentions because of low cost and good process ability. Native starch has the form of granule and can be processed to a continuous phase after gelatinization in the presence of a plasticizer. The resulting material is a biodegradable plastic-like material called thermoplastic starch (TPS) which is processed using conventional technologies, but suffers from low mechanical properties and high hydrophilicity. Addition of... 

Ultrafine- and fine-grained aluminum matrix nanocomposites were fabricated by friction stir processing (FSP) of 5052 Al alloy sheets containing different volume fractions of pre-inserted TiO2 nanoparticles (2, 3, 5 and 6 vol%). Annealed and wrought (H32) sheets were processed at different rotational (w=800-1400 rpm) and traverse speeds (v=50-200 mm/min). A special design tool (concave shoulder and cylindrical pin with regular threads) without changing the rotation and traveling directions was utilized. It is shown that a homogenous distribution of the reinforcement particles throughout the metal matrix is attained at w=1200 rpm and v =50 mm/min after 4 cumulative FSP passes. Transmission... 

Hydroxyapatite is the most substantial inorganic constituent of bone tissue which displays splendid biocompability and bioactivity. Nevertheless, its mechanical properties is not utmost appropriate for a bone substitutes. Therefore, it is used to improve the mechanical properties of polymer matrix composite scaffolds. In the present work polycaprolactone as a polymeric matrix was employed to fabricate hydroxyapatite-polycaprolactone biocomposite scaffolds via in situ route. Solvothermal method was employed to synthesize in situ hydroxyapatite in polymer matrix. Porous scaffolds were fabricated via freeze-drying/porogen leaching. Physical, mechanical (compressive module and compressive... 

The use of dental implants has grown considerably in recent years in Iran but this piece is the industrial imported parts that are not yet produced in Iran. So the main purpose of this research was to fabricate a dental implant from Ti-6Al-4V alloy by CNC machining techniques. On the other hand, the poor bonding strength of bioactive coatings and low cell growth on the surface of uncoated implants are the common problems in the use of dental implants. So another aim of this study was to investigate the effect of Nanoscale surface topography and nanostructured coatings on the surface modification of titanium implant in order to improve Osseointegration and the bonding strength of bioactive... 

This project aimed to fabricate the bone scaffolds with applying thermoplastic starch-based nano-biocomposites. The starting materials for this scaffold are as follows: thermoplastic starch, ethylene vinyl alcohol as the polymer matrix and nanoforsterite as the ceramic reinforcing phase. Furthermore, vitamin E was used as antioxidant for preserving starch against thermo-mechanical degradations. Likewise, 3D pore structure was developed using azo-dicarbonamide and water in injection moulding process. With blending thermoplastic starch and ethylene vinyl alcohol, some thermoplastic starch’s properties including degradation rate and water absorption were modified. In addition, having... 

In this study, Aluminium based nanocomposite with Al3Ti and Al2O3 nanoparticles have been elaborated by mechanical alloying. For this purpose, Al and TiO2 powders have been blended with weight ratios of 10, 20 and 30 percents and were milled using a planetary mill. Morphological variations in different timing periods of mechanical milling process was investigated by Scaning Electron Microscopy (SEM) and The optimal times for alloying were determined for each combination. The pure Aluminium and the powder with 10, 20 and 30%wt reinforcement had coax morphology after respectively for 44, 30, 24 and 14 hours. after studing phase transformations by XRD analysis, the final powders were cold... 

In this study, Cu-TiC nanocomposites were produced by high energy ball milling of elemental powders and in situ formation of TiC in the copper base. Cu and 5,10,20 and 40 wt% Ti powder blend were milled for 60 h, then graphite powders were added and milling was continued for 10 h again and Finally Cu-TiC composite powders with 10.68, 20.16, 36.24 and 60.25 vol% of reinforcements (6.18, 12.2, 23.82 and 45.47 wt%) were produced. The effect of time on the solution of titanium in the copper was studied by X-Ray diffraction analysis (XRD). crystallite size and lattice strain of copper were determined 12nm and 1.04% subsequently for Cu-40wt%TiC after 60 h milling. to ensure the formation of... 

In this study, Al-TiO2 composites layer were produced on Al 1100 substrate using friction stir processing technique. The variation of process parameters such as tool rotational and substrate advancing speed as well as number of FSP passes were adjusted to achieve quite uniform dispersion of Nano-particles in the Al matrix of the fabricated surface layer. Microstructural observations were carried out using optical and scanning electron microscopes. By increasing the FSP passes, uniform distribution of TiO2 particles in the matrix improved. Surface composition layer exhibited a micro-hardness value of 49 HV which was around twice of the as-received substrate. In addition wear resistance of... 

Chitosan (CS) is a natural polysaccharide, which is widely used for various biomedical applications due to its excellent properties such as biocompatibility, biodegradability, bioadhesivity, and bactericidal capacity. Nevertheless, the poor mechanical strength and the loss of structural integrity limit the applications of chitosan. Graphene oxide (GO) has been recognized as an ideal filler for reinforcement of a polymer matrix and its excellent water solubility makes it as a promising candidate for biopolymers. In this work, biocompatible chitosan-graphene oxide nanocomposites were synthesized. First, graphene oxide was prepared using modified Hummer’s method from graphite powder. Solvent... 

The aim of the present thesis was a synthesis of carbon nanofibers (CNFs) derived from electrospun poly vinyl alcohol (PVA) by means of various stabilizers and, moreover, improvement of synthetic CNFs with the incorporation of carbon nanotubes (CNTs). In order to do so, PVA solutions were prepared and electrospun with and without the cadmium salt. In order to do so, PVA solutions were prepared and electrospun with and without the presence of cadmium salt. The resultant polymeric nanofibers were carbonized directly and indirectly. In the case of indirectly carbonization, they were iodinated before the carbonization process. In the case of CNF-CNT composites, after having oxidized by nitric... 

For application such as electrical contacts and spot welding electrodes, both high electrical conductivity and wear resistance are required. Additionally, such parts should have structural stability at evaluated temperature. Copper based composites containing carbides or oxides reinforcement can be the good choice for production of such parts. In present work, in-situ Cu/NbC composite via mechanical alloying with homogenous distribution of nano reinforcement particle has been produced. For this purpose, in first stage, copper powder was milled with 5, 8, 10 and 12 wt. % of niobium powder in two types of mills, i. e. vibratory dicky mill and planetary ball mill for 5 and 32 h respectively. At...