Sharif Digital Repository

High performance Fe-Gd-P tri-doped TiO2 nanoparticles (1 at% for each dopant) were successfully synthesized by a modified sol–gel method. Various analytical and spectroscopic techniques were carried out to determine the physicochemical properties of the prepared samples, including XRD, EDX, FESEM, BET, FTIR, XPS, PL, EIS and UV–Vis diffuse reflectance spectroscopy. The photocatalytic activities of prepared samples were evaluated by photo degradation of methyl orange (MO) and 4-chlorophenol (4-CP) as model pollutants under visible light irradiation. Effects of each dopant on different properties of TiO2 nanoparticles were investigated. Results show that Gd and P doping enhances TiO2 surface... 

Developments of sensitive, rapid, and cheap systems for identification of a wide range of biomolecules have been recognized as a critical need in the biology field. Here, we introduce a simple colorimetric sensor array for detection of biological thiols, based on aggregation of three types of surface engineered gold nanoparticles (AuNPs). The low-molecular-weight biological thiols show high affinity to the surface of AuNPs; this causes replacement of AuNPs' shells with thiol containing target molecules leading to the aggregation of the AuNPs through intermolecular electrostatic interaction or hydrogen-bonding. As a result of the predetermined aggregation, color and UV-vis spectra of AuNPs... 

We report herein the development of a highly sensitive colorimetric method for detection of d-Penicillamine using citrate-capped gold nanoparticles (AuNPs). This assay relies upon the distance-dependent of gold nanoparticles surface plasmon resonance band of gold nanoparticles. By replacing the thiol-containing chelator drug, d-Penicillamine, with citrate on the gold nanoparticles surface, a new peak appearing at a longer wavelength intensifies and shifts further to the red from the original peak position due to aggregation of gold nanoparticles which depends on ionic strength, gold nanoparticles and d-Penicillamine concentration. During this process, the plasmon band at 521 nm decreases... 

An extracting medium based on chitosan-polypyrrole (CS-PPy) magnetic nanocomposite was synthesized by chemical polymerization of pyrrole at the presence of chitosan magnetic nanoparticles (CS-MNPs) for micro-solid phase extraction. In this work, magnetic nanoparticles, the modified CS-MNPs and different types of CS-PPy magnetic nanocomposites were synthesized. Extraction efficiency of the CS-PPy magnetic nanocomposite was compared with the CS-MNPs and Fe3O4 nanoparticles for the determination of naproxen in aqueous samples, via quantification by spectrofluorimetry. The scanning electron microscopy images obtained from all the prepared nanocomposites revealed that the CS-PPy magnetic... 

A new characteristic-based method is developed and used for solving the mixed and forced convection problems. The nano-fluid flow with heat transfer is simulated with a novel characteristic-based scheme in closed domains with different aspect ratios. For this purpose, a FORTRAN code has been written and developed. Water as a pure fluid and water-titanium dioxide as a nano-fluid were considered. The governing equations are solved by the finite volume utilizing a characteristic-based scheme for the convective fluxes. The simulation is done at Grashof numbers from 100 to 104, Reynolds numbers from 100 to 1000, and volume fractions of nano-particles from 0% to 10%. Streamlines, isotherms,... 

Purpose: The purpose of this paper is to investigate the natural convection behavior of nanofluids in an enclosure. The enclosure is a 3D capsule with curved boundaries filled with TiO2-water nanofluid. Design/methodology/approach: In this paper, a multiple relaxation times lattice Boltzmann method (MRT-LBM) has been used. Two-component LBM has been conducted to consider the interaction forces between nanoparticles and the base fluid. Findings: Results show that the enhanced Nusselt number (Nu*) increases with the increase in volume fraction of nanoparticles (ϕ) and Ra number and decrease of nanoparticle size (λ). Additionally, the findings indicate that increasing volume fraction beyond a...