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    Baseline Design of the Exergy Recovery and Solar Heating System at the Gas Pressure Reduction Station and its Technical, Economical, and Environmental Assessments

    , M.Sc. Thesis Sharif University of Technology Talaei, Mohammad (Author) ; Saboohi, Yadollah (Supervisor)
    Abstract
    As producing and consuming of natural gas has increased in recent years, improving natural gas distribution and transfer network systems has become vital. Pressure reduction station (PRS) is an important part of the natural gas network. Common PRSs are facing two issues: first is the pressure reduction technology, which is throttling valve that destroys the exergy of the high pressure flow. The solution is to utilize turbo-expander instead which can recover the energy. Second is the preheating technology which is boiler and water bath heater in the common systems that cause environmental problems. Using solar collectors is one of the best solution based on the literature. Since the solar... 

    Design and Optimization of Helium Extraction and Liquefaction Cycle from Natural Gas by Direct Method

    , Ph.D. Dissertation Sharif University of Technology Ardeshir Larijani, Morteza (Author) ; Afshin, Hossein (Supervisor)
    Abstract
    Helium is known as a strategic material due to its unique properties and applications in the development of advanced industries. Currently, natural gas is the only source from which helium can be produced economically. The United States, Qatar, Algeria, and Russia have the largest share of helium production, respectively. In this research, the process of helium extraction from natural gas and its liquefaction, independent of LNG production based on helium in South Pars gas of Iran, which is the largest helium reservoir in the world, were designed and simulated.In the helium liquefaction section, the speed and accuracy of the process simulation were improved by developing a home code based on... 

    Forecasting Residential Natural Gas Consumption in Tehran Using Machine Learning Methods

    , M.Sc. Thesis Sharif University of Technology Khazaei, Armin (Author) ; Maleki, Abbas (Supervisor)
    Abstract
    According to increasing energy demand in Iran and the world, the role of natural gas as a relatively clean and cost-effective source has received more attention. Given the high share of the residential sector in the country's natural gas consumption, providing a model for forecasting the demand of this sector is of great importance for policy makers and decision makers in this field. In the present study, we employ three popular methods of machine learning, support vector regression, artificial neural network and decision tree to predict the consumption of natural gas in the residential sector in Tehran according to meteorological parameters (including temperature, precipitation and wind... 

    Numerical Investigation of Nitrogen Condensation in a Two-phase Vortex Tube

    , M.Sc. Thesis Sharif University of Technology Mirjalili, Mohamad Reza (Author) ; Ghorbanian, Kaveh (Supervisor)
    Abstract
    The Ranque-Hilsch vortex tube (RHVT) has no moving parts through which a high-pressure fluid gains on rotational velocity by passing radially through the inlet nozzles and then enters the vortex chamber. Subsequently, the high-pressure fluid becomes divided into two relatively distinctive hot and cold axial flows. Today, while RHVT is of great industrial interest due to its simplicity in manufacturing and operation; however, the mechanism of energy dissociation, which is dominated by the complex coupled interaction of the viscous thermo-fluid characteristics and geometrical properties, is not fully understood and no clear theory has been proposed to explain the energy dissociation so far.... 

    Demand Estimation of Natural Gas

    , M.Sc. Thesis Sharif University of Technology Seyedi, Salar (Author) ; Rahmati, Mohammad Hossein (Supervisor) ; Vesal, Mohammad (Supervisor)
    Abstract
    The provision of developmental infrastructure by governments and their various effects on the lives of citizens has always been the subject of discussion among researchers and policymakers. In particular, the infrastructure associated with access to modern energies causes changes in household economic behavior. The effects of pipeline gas connection on household behavior is the main subject of this research. By using micro level data, these effects compare the behavior of beneficiary households and lack of natural gas. The data includes households living in the entire geographical zone of Iran and between 1377 and 1394. First, we show that natural gas is a direct substitute for liquid fuels... 

    Synthesis and Evaluation of a Three-Way Catalyst for CO, Hydrocarbon and Nitrogen Oxide Emission Control in CNG-Fueled Vehicles

    , M.Sc. Thesis Sharif University of Technology Esperi, Melika (Author) ; Hamzehlouyan, Tayebeh (Supervisor)
    Abstract
    According to the reports of the Tehran Air Quality Control Company, mobile sources are responsible for the emission of 70-85% of air pollutant in this metropolis. Over the past decades, compressed natural gas (CNG) is known as a cleaner fuel and a suitable alternative to gasoline and diesel fuels in the transportation section in some countries. However, methane emissions from natural gas vehicles is a significant challenge because it is a potent greenhouse gas and plays important role in global warming. In addition, because of another pollutant emissions from these vehicles, exhaust gas treatment is a crucial issue. Using Three-Way catalysts (TWC) is the conventional method in order to... 

    Design and Optimization of a Novel Power Cycle and Seawater Freeze Desalination System by Utilizing the Cold Energy of Liquefied Natural Gas

    , Ph.D. Dissertation Sharif University of Technology Eghtesad, Amir Saman (Author) ; Afshin, Hossein (Supervisor) ; Kazemzadeh Hanani, Siamak (Supervisor)
    Abstract
    Access to potable water with standard quality is an inevitable component of human’s lives. Seawater desalination is the precedure of removing the impurities and contaminants in water to achieve the suitable quality for human consumption. Freeze desalination, by consuming relatively much lower energy compared to other techniques has shown to be a promising method for desalination. This technique requires the exertion of a cold source to the system which is then accompanied by simultaneous rejection of the impurities from the water. Regarding this, a numerical study on freeze desalination a hollow cylinder is carried out to determine the effects of the design variables such as heat flux,... 

    Multi-Scale Design and Optimization of A High-Nitrogen-Content Natural Gas Processing Plant

    , M.Sc. Thesis Sharif University of Technology Mostafavi, Mahdi (Author) ; Farhadi, Fathollah (Supervisor) ; Eini, Saeed (Supervisor)
    Abstract
    Given the environmental benefits of natural gas (NG) in comparison to other fossil fuels and its potential contribution to the shift towards renewable energy, there is an anticipated rise in the demand for NG as an energy source in the coming years. This surge in demand has sparked a growing interest in the exploration and development of unconventional gas fields with low hydrocarbon content, which were previously considered economically unviable. Among these fields, those rich in nitrogen have garnered significant attention. However, the presence of high nitrogen content in NG poses notable challenges, including a decrease in calorific value and increased costs associated with... 

    Investigating the mechanism of water inflow in gas wells in fractured gas reservoirs and designing a controlling method

    , Article SPE Production and Operations Symposium, Proceedings ; Vol. 1, issue , May , 2012 , p. 323-340 ; ISBN: 9781613992012 Jafari, I ; Jamshidi, S ; Masihi, M ; Sharif University of Technology
    Abstract
    The coning phenomenon usually occurs in water and gas cap drive reservoirs. Water coning in Iranian hydrocarbon reservoirs is one of the most important problems that affects the cumulative production, operation costs and causes environmental problems. Before producing from a reservoir, its fluids are in equilibrium and their contact surfaces remain unchanged, but after starting production from the reservoir, when the viscous force overcome gravitational force in vertical direction, contact surfaces will displace and coning will occur. So, the production rates will be controlled in a range that prevents entering water and gas to the production well. For this reason, investigation and modeling... 

    Scaling, multifractality, and long-range correlations in well log data of large-scale porous media

    , Article Physica A: Statistical Mechanics and its Applications ; Vol. 390, issue. 11 , June , 2011 , p. 2096-2111 ; ISSN: 03784371 Dashtian, H ; Jafari, G. R ; Sahimi, M ; Masihi, M ; Sharif University of Technology
    Abstract
    Three distinct methods, namely, the spectral density, the multifractal random walk approach, and the multifractal detrended fluctuation analysis are utilized to study the properties of four distinct types of well logs from three oil and gas fields, namely, the natural gamma ray emission, neutron porosity, bulk density, and the sonic transient time logs. Such well logs have never been analyzed by the methods that we utilize in the present study. The results indicate that the well logs exhibit multifractal characteristics, and the estimated Hurst exponents by the three methods are close to each other. Using multifractal detrended fluctuation analysis and the shuffled and surrogated data, we... 

    On the isobaric specific heat capacity of natural gas

    , Article Fluid Phase Equilibria ; Vol. 384, issue , 2014 , pp. 16-24 ; ISSN: 03783812 Jarrahian, A ; Karami, H. R ; Heidaryan, E ; Sharif University of Technology
    Abstract
    A colorimeter equipped with a gas booster in conjunction with a PVT cell was used to measure the heat capacity of natural gas with different amounts of impurities. Based on new experimental and literature data, a general investigation of the isobaric specific heat capacity was carried out using the Jarrahian-Heidaryan equation of state (J-H-EOS). A model was obtained that is valid in wide ranges of pressures (0.1-40. MPa) and temperatures (250-414. K). The arithmetic average of the model's absolute error is acceptable in engineering calculations and has superiority over other methods in its class  

    Simultaneous separation of H2S and CO2 from CH4 by a high silica CHA-type zeolite membrane

    , Article Journal of Membrane Science ; Vol. 470, issue , 2014 , pp. 159-165 ; ISSN: 03767388 Maghsoudi, H ; Soltanieh, M ; Sharif University of Technology
    Abstract
    A high silica CHA-type membrane was synthesized by the in-situ crystallization method on a disk like α-alumina porous support to separate both acid (H2S, CO2) gases from methane. The membrane showed a permeance of 3.39×10-8mol/m2sPa for pure CO2with CO2/CH4 ideal selectivity of 21.6 at 303K and 100kPa pressure difference across the membrane. The membrane was also tested with N2 and O2 pure gases indicating a small O2/N2 selectivity of 1.2-1.4, which shows that this type of membrane is not suitable for O2/N2 separation. The membrane performance was also analyzed by binary (CO2-CH4) and ternary (H2S-CO2-CH4) gas mixtures, with compositions near the real sour natural gas (CO2: 2.13mol%, H2S:... 

    A new cubic equation of state for sweet and sour natural gases even when composition is unknown

    , Article Fuel ; Vol. 134, issue , 2014 , pp. 333-342 ; ISSN: 00162361 Jarrahian, A ; Heidaryan, E ; Sharif University of Technology
    Abstract
    In this paper, the Heidaryan and Jarrahian equation of state (Heidaryan and Jarrahian, 2013) has been adapted as a first worldwide cubic EOS to calculate the density of dry natural gases, wet natural gases, and single-phase gas condensates "sweet and sour mixtures" (up to 73.85, 97.63 and 38.37 mol percent of H2S, CO2, and N2 respectively) even when the gas composition is unknown, through new gas specific gravity correlation equations. Correction terms of water content as high as 10 mol percent of H2O and hythane (natural gas + hydrogen) as high as 74.9 mol percent of H2 were obtained. The equation of state was validated with 8985 experimental compressibility factor data points from 308... 

    Catalyst deactivation in industrial combined steam and dry reforming of natural gas

    , Article Fuel Processing Technology ; Vol. 120 , 2014 , pp. 96-105 ; ISSN: 03783820 Banisharifdehkordi, F ; Baghalha, M ; Sharif University of Technology
    Abstract
    The catalyst's performance and deactivation in a Midrex® industrial fixed bed reactor were investigated for the combined steam and dry reforming of natural gas using a one-dimensional heterogeneous model. The results demonstrate that there is a strong tendency for the catalyst's deactivation by carbon formation originating from methane decomposition. However, kinetic modelling of the combined reforming process shows that only a fraction of the catalyst in the industrial reactor is required for the reactions to reach an equilibrium state in the reformer. Hence, as the catalyst is deactivated at the reactor entrance area, the reaction zone gradually moves forward and still allows for... 

    State-of-the-art least square support vector machine application for accurate determination of natural gas viscosity

    , Article Industrial and Engineering Chemistry Research ; Vol. 53, issue. 2 , 2014 , pp. 945-958 ; ISSN: 08885885 Fayazi, A ; Arabloo, M ; Shokrollahi, A ; Zargari, M. H ; Ghazanfari, M. H ; Sharif University of Technology
    Abstract
    Estimation of the viscosity of naturally occurring petroleum gases is essential to provide more accurate analysis of gas reservoir engineering problems. In this study, a new soft computing approach, namely, least square support vector machine (LSSVM) modeling, optimized with a coupled simulated annealing technique was applied for estimation of the natural gas viscosities at different temperature and pressure conditions. This model was developed based on 2485 viscosity data sets of 22 gas mixtures. The model predictions showed an average absolute relative error of 0.26% and a correlation coefficient of 0.99. The results of the proposed model were also compared with the well-known predictive... 

    Real time optimization of a natural gas lift system with a differential evaluation method

    , Article Energy Sources, Part A: Recovery, Utilization and Environmental Effects ; Vol. 36, issue. 3 , 2014 , pp. 309-322 ; ISSN: 15567036 Frooqnia, A ; Pishvaie, M. R ; Aminshahidy, B ; Sharif University of Technology
    Abstract
    This article presents a method for optimizing and controlling an oil production system using a natural gas lift concept. Ever increasing development of Smart Well technology and various applications of down-hole monitoring and controlling instruments along with new methods of data acquisition/transmission make it possible for the natural gas lift system to be controlled and optimized more effectively and faster than before. With this technology it is possible to monitor the down-hole conditions of gas and oil zones and to control the inflow valves in gas and oil zones. In this work, a proportional integral differential feedback controller has been used to smartly control the entrance of gas... 

    Natural gas hydrate promotion capabilities of toluene sulfonic acid isomers

    , Article Polish Journal of Chemical Technology ; Vol. 16, Issue. 1 , 2014 , pp. 97-102 ; ISSN: 1899-4741 Jarrahian, A ; Heidaryan, E ; Sharif University of Technology
    Abstract
    The purpose of this study was to investigate the natural gas hydrate promotion capabilities of the hydrotrope Toluene Sulfonic Acid (TSA) isomers as an additive. The capabilities of TSA isomers were measured with different concentrations. The optimum additive concentration for hydrate formation was determined for the given pressure, temperature, mixing condition, and cooling time. The natural gas hydrate promotability of para-TSA was found to be 20% and 35% more than meta-TSA and ortho-TSA respectively at the optimum concentration. Beyond the optimum TSA concentration, the hydrate formation declined as the ice formation reduced the overall gas-to-water volume ratio in the hydrates  

    Simulation and experimental investigation of performance and emissions of a turbocharged lean-burn natural gas engine considering thermal boundary layer

    , Article Scientia Iranica ; Vol. 21, issue. 4 , 2014 , pp. 1424-1439 ; ISSN: 10263098 Kharazmi, Sh ; Mozafari, A ; Hajilouy-Benisi, A ; Sharif University of Technology
    Abstract
    Emission characteristics of pure natural gas is fairly known, however more experimental investigation of natural gas combustion is necessary. In this research, emission and performance of a turbocharged natural gas SI engine are investigated experimentally at WOT and lean burn conditions. A computer code is also developed in MATLAB environment for predicting engine performance and NO emission and the results are validated with experimental data. Thermal boundary layer, as a novel approach, is considered in the simulation and a better agreement of predicted mass fraction burned was achieved at end part of combustion process when compared with experimental results. Experimental results have... 

    Toward a predictive model for predicting viscosity of natural and hydrocarbon gases

    , Article Journal of Natural Gas Science and Engineering ; Volume 20 , September , 2014 , Pages 147-154 ; ISSN: 18755100 Yousefi, S. H ; Azamifard, A ; Hosseini, S. A ; Shamsoddini, M. J ; Alizadeh, N ; Sharif University of Technology
    Abstract
    Accurate knowledge of pure hydrocarbon and natural gas viscosity is essential for reliable reservoir characterization and simulation as well as economic design of natural gas processing and transport units. The most trustable sources of pure hydrocarbon and natural gas viscosity values are laboratory experiments. When there is no available experimental data for the required composition, pressure, and temperature conditions, the use of predictive methods becomes important. In this communication, a novel approach was proposed to develop for prediction of viscosity of pure hydrocarbons as well as gas mixtures containing heavy hydrocarbon components and impurities such as carbon dioxide,... 

    A simple correlation to estimate natural gas thermal conductivity

    , Article Journal of Natural Gas Science and Engineering ; Volume 18 , May , 2014 , Pages 446-450 ; ISSN: 18755100 Jarrahian, A ; Heidaryan, E ; Sharif University of Technology
    Abstract
    A general investigation of the thermal conductivity of natural gas as a function of temperature, pressure and composition was carried out to develop a generalized correlation. The model obtained was based on 731 data points of 42 binary mixtures in wide ranges of pressures (0.1-300MPa), temperatures (220-425K) and specific gravities (0.626-1.434). Correction terms for non-hydrocarbons of carbon dioxide and nitrogen were up to 87.8 and 82.8 of mole percent, respectively. The arithmetic average of the model's absolute error was found to be 5.69%, which is acceptable in engineering calculations