Sharif Digital Repository

Asphaltene deposition during oil production and transportation causes extensive damage to reservoirs and wellhead equipment. In this study, the effects of native and non-native resins as well as those of their mixtures on the asphaltene deposition process are investigated. A novel pressure, volume, and temperature (PVT) visual cell is used to check the effect of resin on asphaltene deposition at different pressures and reservoir temperatures. Two Iranian crude oil samples with different potentials of asphaltene deposition (low and high) were used in these tests. During depressurizing in the presence of native and non-native resins, the amount of asphaltene deposited was measured. To monitor... 

CO2 gas injection is known as one of the most popular enhanced oil recovery techniques for light and medium oil reservoirs, therefore providing an acceptable mass transfer mechanism for CO2–oil systems seems necessary. In this study, interfacial mass transfer coefficient has been evaluated for CO2–normal heptane and CO2–normal hexadecane systems using equilibrium and dynamic interfacial tension data, which have been measured using the pendant drop method. Interface mass transfer coefficient has been calculated as a function of temperature and pressure in the range of 313–393 K and 1.7–8.6 MPa, respectively. The results showed that the interfacial resistance is a parameter that can control... 

The present study was carried out to evaluate the degradation efficiency of benzene, toluene, and xylene (BTX) by isolated bacteria from various petroleum-hydrocarbons contaminated sites. Five isolated bacteria were selected for testing BTX biodegradation from liquid culture media. Each of these bacteria was able to degrade BTX but with different efficiencies. Maximum biodegradation efficiency for benzene (more than 70 %) was obtained by Gram-positive coccobacillus, Gram-positive coccus and Gram-negative bacillus bacteria, for toluene (60 %) and xylene (70 %) by Gram-positive coccobacillus and Gram-negative coccobacillus. It was found that the presence of xylene in the substrate mixture... 

MEG regeneration and injection unit regenerates aqueous MEG. The main goal of this unit is approaching desired MEG concentration whereas MEG loss via removed water is a big issue. Circulating glycol is polluted with Ca++ and Mg++ which forms carbonate scale and causes plugging of pipe lines, filters, lean/rich exchanger, still column packings and reboiler tube bundle and decreases their efficiency, consequently increases MEG loss via top product. Different alternatives exist according to similar experiences around the world. Using specific criteria and AHP (Analytical Hierarchy Process) method priority of these alternatives has been found. Results are as following: 1. Increasing number of... 

In order to investigate the feasibility and effects of core permeability on capillary imbibition recoverable oil from carbonate cores, some laboratory tests were carried out at the EOR research laboratories of Sharif University, Iran. Outcrop rocks with different permeabilities were taken away from a recognized outcrop and used in these experiments. Special core analysis tests were run on two core samples to find out relative permeability and end point saturations. Wellhead separator oil and gas samples were collected and recombined to a reservoir gas - oil ratio. A core flooding system with a capability of free and forced imbibition testing was designed and installed. A number of free and... 

The knowledge of the conductivity across the reservoir that is based on the swept fraction controls the recoverable rates of the hydrocarbon in the secondary displacement processes. Most of the time, we need a fast estimation of the conductivity for decision making during field development. Percolation theory is a very useful tool to get this goal. According to this fact that the results of this method are universal, they could be used widely. In this study connectivity and conductivity percolation models are developed and the universal exponents for connectivity and conductivity in fractured reservoir as well as their dependency on the correlation length are investigated. For L< ξ the... 

Wax precipitation may occur in production or transportation of crude oil form field which is a serious problem in petroleum industry. Flow assurance issues concerning wax precipitation make it necessary to develop a precise thermodynamic model to predict the wax appearance temperature and amount of precipitation at different conditions. In this work a new procedure has been proposed to characterize crude oil based on the SARA test considering the wax and asphaltene as single pseudo components. Two scenarios have been investigated for the survey of the crude oil characterization, with and without asphaltene pseudo component. Also, in this work, the Perturbed Chain form of the Statistical... 

Streaming potential measurement is one of the electrokinetic techniques used to determine the average zeta potential of porous rock which can provide reliable information on reservoir flow behavior and wettability state of the rock surface. Streaming potential measurement using electrodes has recently been introduced in the oil reservoirs applications and there are still significant uncertainties during the measurements and interpretation of streaming potential results. The primary purpose of this work is to establish a setup to measure the streaming potential of porous media with low scattering and evaluate voltage measurements based on the paired stabilization and pressure ramping methods.... 

In recent years, improving oil recovery (IOR) has become an important subject for the petroleum industry. One IOR method is infill drilling, which improves hydrocarbon recovery from virgin zones of the reservoir. Determining the appropriate location for the infill wells is very challenging and greatly depends on different factors such as the reservoir heterogeneity. This study aims to investigate the effect of reservoir heterogeneity on the location of infill well. In order to characterize the effect of heterogeneity on infill well locations, some geostatistical methods, e.g., sequential gaussian simulation, have been applied to generate various heterogeneity models. In particular, different... 

It is not common to build a geomechanical model for depleted reservoirs as logging and coring are costly and time consuming in such reservoirs. On the other hand, in regular analysis of wellbore stability, the effect of time is completely ignored. As a result, with time there will be some errors in the evaluation of wellbore stability in depleted reservoirs. In order to determine the optimum wellbore trajectory during the reservoir life, it is necessary to have a model which can estimate the rock properties based on the first full logging suite and also consider the depletion effect. In this study, a novel model is proposed which combines a mechanical earth model, borehole circumferential... 

Classic identifiability analysis of flow barriers in incompressible single-phase flow reveals that it is not possible to identify the location and permeability of low-permeability barriers from production data (wellbore pressures and rates), and that only averaged reservoir properties in between wells can be identified. We extend the classic analysis by including compressibility effects. We use two approaches: a twin experiment with synthetic production data for use with a time-domain parameter-estimation technique, and a transfer-function formalism in the form of bilaterally coupled four-ports allowing for an analysis in the frequency domain. We investigate the identifiability, from noisy... 

In the present paper we investigate the problem of water propagation in 2 dimensional (2D) petroleum reservoir in which each site has the probability p of being occupied. We first analyze this propagation pattern described by Darcy equations by focusing on its geometrical features. We find that the domain-walls of this model at p=pc ≃ 0.59 are Schramm-Loewner evolution (SLE) curves with κ=3.05 ∓ 0.1 consistent with the Ising universality class. We also numerically show that the fractal dimension of these domain-walls at p=pc is Df ≃ 1.38 consistent with SLEκ=3. Along with this analysis, we introduce a self-organized critical (SOC) model in which the water movement is modeled by a chain of... 

The impacts of salinity adjustment of displacing fluid have recently gained special attention to enhanced oil recovery (EOR). Different mechanisms have been studied widely in the literature while some of them are still subjugated to more scrutiny. The effects of diluted sea water on the interfacial properties of brine and asphaltenic-acidic crude oil and the wettability alteration of carbonate reservoir rock are investigated in this experimental observational work. The measurements of interfacial tension (IFT) and contact angle (CA) as two main parameters are studied. Besides, the effects of asphaltene and resin in the crude oil on the IFT values between the crude oil and aqueous solution... 

Most investigations showed that the prevalent thermodynamic models are incapable of predicting asphaltene precipitation without extensive data fitting. This is primarily due to lack of knowledge of the asphaltene properties, its complex nature and the large number of parameters affecting precipitation. Hece, several authors tried to generate a simple and universe mathematical model in order to predict the amount of asphaltene precipitation. In spite of these efforts, the authors only considered temperature and type of solvents as the effective parameters in generating their scaling equations. The major disadvantage of these models is their inability in predicting the amount of asphaltene... 

Enhanced oil recovery (EOR) methods assisted by gravity drainage mechanism and application of sophisticated horizontal wells bring new hope for heavy oil extraction. Variety of thermal and non-thermal EOR techniques inject an external source of energy and materials such as steam, solvent vapor, or gas through a horizontal well at the top of the reservoir to reduce in-situ heavy oil viscosity. So, the diluted oil becomes mobile and flows downwards by gravity drainage to a horizontal producer located at the bottom of the reservoir. In this paper, a sector model of an Iranian fractured carbonate heavy oil reservoir was provided to simulate and evaluate capability of some EOR techniques such as... 

Carbonated water injection (CWI) is known as an efficient technique for both CO2 storage and enhanced oil recovery (EOR). During CWI process, CO2 moves from the water phase into the oil phase and results in oil swelling. This mechanism is considered as a reason for EOR. Viscous fingering leading to early breakthrough and leaving a large proportion of reservoir un-swept is known as an unfavorable phenomenon during flooding trials. Generally, instability at the interface due to disturbances in porous medium promotes viscous fingering phenomenon. Connate water makes viscous fingers longer and more irregular consisting of large number of tributaries leading to the ultimate oil recovery... 

Reservoir heterogeneity has a major effect on the characterization of reservoir properties and consequently reservoir forecast. In reality, heterogeneity is observed in a wide range of scales from microns to kilometers. A reasonable approach to study this multi-scale variations is through fractals. Fractal statistics provide a simple way of relating variations on larger scales to those on smaller scales and vice versa. Simple statistical fractal models (fBm and fGn) can be useful to understand the model construction and help the reservoir structure characterization. In this paper, the fractal methods (fGn and fBm) have been applied to characterize and to estimate of reservoir properties.... 

The purpose of this study was the production of copolymers and terpolymers with highly hydrophilic–hydrophobic properties, using inexpensive and available monomers as potential enhancing oil recovery (EOR) and water production control agents for high-temperature and high-salinity (HTHS) oil reservoirs. For this purpose, several copolymers and terpolymers with different molar percentage of acrylamide/styrene, acrylamide/maleic anhydride, and acrylamide/styrene/maleic anhydride were synthesized by the inverse emulsion polymerization technique. The presence of hydrophobic styrene and hydrophilic maleic anhydride monomers in the copolymer and terpolymer structure, provided some unique properties... 

Sulfate anion is well-known for being one of the most active agents to be injected into the oil reservoirs and being capable of not only altering the interfacial properties of crude oil but also enhancing the water solution properties in oil recovery. In the current study, the effects of temperature and pressure were studied on interfacial tension (IFT) as well as the adsorption behavior of two different solutions containing sulfate anion using experimental measurements and modeling approaches. Although it was expected that IFT values of the studied systems might decrease as temperature increased due to the improvement in the molecule mobility and solubility of crude oil in water, which... 

In the present study, we try to numerically simulate the nanofluid flooding method, which is one of the newest methods in this field. For this purpose, the nanofluid is considered as a single phase fluid that enters the porous petroleum reservoir containing oil. Since all porous petroleum reservoirs are heterogeneous, the porous grid is also considered heterogeneous and is solved using the finite element numerical method. The geometry considered in this study is a two-dimensional anticline medium that is heterogeneous. In this study, the effect of using different volume fractions of nanoparticles in nanofluid is studied. Capillary pressure or diffusion are considered in simulation and their...