Sharif Digital Repository

Recently, a renewed interest arises in the application of nanotechnology for the upstream petroleum industry. In particular, adding nanoparticles to fluids may drastically benefit enhanced oil recovery (EOR) and improve well drilling, by changing the properties of the fluid, rocks wettability alteration, advanced drag reduction, strengthening the sand consolidation, reducing the interfacial tension and increasing the mobility of the capillary trapped oil. In this study, we focus on roles of clay nano-particles on polymer viscosity. Polymer-flooding schemes for recovering residual oil have been in general less than satisfactory due to loss of chemical components by adsorption on reservoir... 

A large variety of modifications have been presented for the temperature dependent function (α) existing in the attractive term of cubic equations of state (CEOS). Most of α-functions attempted to modify the vapor pressure prediction of polar components while other modifications have focused on both polar and non-polar compounds and other relations have considered an expansion of polynomials in the acentric factor (ω) and reduced temperature (Tr) to predict vapor pressure more accurately. In most cases such as Soave and Peng-Robinson equations of state, the suggested α-functions do not show a limiting behavior when temperature increases infinitely. In addition, the incompetency of many... 

Zinc oxide nanoparticles were synthesized and modified by a three-stage method. Elemental analysis, Fourier transform infrared spectroscopy, thermogravimetric analysis, scanning and transmission electron microscopy, and Brunauer–Emmett–Teller method were applied to characterize the nanoparticles. These nanoparticles were evaluated for toluene adsorption from aqueous solutions as a representative of petroleum hydrocarbon removal. The optimum adsorption condition achieved at pH of 6 and contact time of 30 min. The adsorption isotherms were fitted to the Langmuir model. The measured adsorption capacity was 12.8 mg g−1. This study demonstrated that these nanoparticles could be used as an... 

The knowledge of the connectivity across the reservoir not only helps to find out the potential oil recovery within a particular well configuration but also affects on the other reservoir engineering decisions such as infill drilling. Connectivity also controls the swept fraction of the hydrocarbon in place in secondary displacement other than the recoverable rates of the hydrocarbon. Most of the time we need a fast estimation of connectivity for decision making during field development. Percolation theory is a very useful tool to get this goal. According to this fact that the results of this method are universal, they could be used widely. During this study a percolation model is developed... 

Using network analysis, we investigate if an industry's complex and integrated knowledge base leads to a higher spatial concentration (or dispersal)of innovative activities. This is important because the extant literature provides competing claims about how knowledge base complexity impacts on the spatial distribution of industrial innovation. To help empirically resolve this issue, we draw on longitudinal data (1970–2010)on the upstream petroleum industry and build indexes of entropy and complexity to render knowledge base dynamics, assess the spatial concentration of innovation, and study industry structural transformations. We first find a correlation – once a crucial distinction between... 

Water injection into petroleum reservoirs is widely performed around the world for enhancing oil recovery. Understanding the underground fluid path is an important factor in improving reservoir performance under waterflooding operation. This may be used to optimize subsequent oil recovery by changing injection patterns, assignment of well priorities in operations, recompletion of wells, targeting infill drilling, and reduce the need for expensive surveillance activities. Most of the hydrocarbon reservoirs are equipped with sensors that measure the flow rate, pressure, and temperature in the wellbores continuously. Valuable and useful information about the interwell connections can be... 

By reducing the exploration of new oil reservoirs, enhanced oil recovery from previous oil reservoirs is a solution to supply energy demand. In order to develop the production, various technologies and methods have been proposed such as steaming, direct heating, flooding by nano-fluid, chemical injection, polymer injection and etc. In the present study, nanofluid flooding has been attempted on a rock reservoir with incomplete cone geometry and its performance has been evaluated on oil recovery. The porous media is considered heterogeneous in simulation in accordance with oil reservoirs. The heterogeneous geometry considered in this study is incomplete cone that is heterogeneous in a random... 

In this work, high-pressure microscopy technique was used to measure the size and fractal dimension of asphaltene aggregates formed in different live oil samples at elevated pressures and temperatures. It was found that the asphaltene aggregates in live oil samples are irregular fractal-like structures with pressure−temperature-dependent fractal dimensions. By monitoring the variation of the fractal dimension and size of the asphaltene aggregates with pressure and temperature, the mechanisms responsible for asphaltene aggregation process at elevated pressures and temperatures can be well predicted. The range of fractal dimension of asphaltene aggregates in live oils is similar to that... 

Background: To meet stringent emission standards stipulated by regulatory agencies, the oil industry is required to bring down the sulfur content in fuels. As some compounds cannot be desulfurized by existing desulfurizing processes (such as hydrodesulfurization, HDS) biodesulfurization has become an interesting topic for researchers. Most of the isolated biodesulfurizing microorganisms are capable of desulfurization of refined products whose predominant sulfur species are dibenzothiophenes so biocatalyst development is still needed to desulfurize the spectrum of sulfur-bearing compounds present in whole crude. Results: The first desulfurizing bacterium active at 60 °C has been isolated,... 

To meet stringent emission standards stipulated by regulatory agencies, the oil industry is required to bring down the sulfur content in fuels. Oil supplies 38% of the worldwide energy, and as the light oil is limited and meanwhile the energy demand is increasing, it is a must to use heavy crude oil and therefore desulfurize it to meet environmental standards. As it is not feasible to desulfurize all the sulfur containing compounds of heavy crude oil by the existing methods (such as hydro-desulfurization) we have focused on biodesulfurization of heavy crude oil. We have isolated the first native fungus which has been identified as Stachybotrys sp. and is able to remove sulfur and nitrogen... 

Despite the numerous experimental studies, there is a lack of fundamental understanding about how the local and global heterogeneity control the efficiency of polymer flooding. In this work a series of water and polymer injection processes are performed on five-spot glass micromodels which are initially saturated with the crude oil at varying conditions of flow rate, water salinity, polymer type and concentration. Three different pore structures in combine with different layer orientations are considered for designing of five different micromodel patterns. It has been observed that the oil recovery of water flooding is increasing with the salinity concentration, for the ranges studied here.... 

Microbial enhanced oil recovery (MEOR) is receiving renewed interest worldwide in recent years as a viable method while not damaging the reservoir is proven to be remarkably effective, however to some extent costly. This method is based on microorganisms' activities to reduce residual oil of reservoirs, which is dependent on behavior of inherent microorganisms or injection of bioproduct of external microorganisms. In this work, five bacterial species were taken from MIS crude oil that is one of the aging Persian fractured reservoirs. These microorganisms are substantially strong in increasing oil recovery especially by reducing IFT and other MEOR mechanisms such as change of wettability of... 

Capacitance-Resistive Model (CRM), as a fast yet efficient proxy model, suffers from some limitations in modeling relatively complex reservoirs. Some current improvements on this proxy made it a more powerful simulator with updating parameters over time. However, the model's intrinsic uncertainty arisen from simplifying fluid-flow modeling by some limited number of constant parameters is not addressed yet. In this study, this structural limitation of CRM has been addressed by introducing a time-correlated model error, including stochastic and non-stochastic parameters, embedded into this proxy's formulation. The error term's non-stochastic parameters have been tuned to be used in forecasting... 

Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

A new nanocomposite polymer gel is synthesized for reduction of excess water production in petroleum reservoirs at real operating conditions. This new nanocomposite gel contains SiO2 nanoparticles, partially hydrolyzed polyacrylamide (HPAM) and chromium triacetate. High pressure and high temperature tests using porous carbonate core are carried out to evaluate the effects of nanoparticles on the synthesized polymer gel performance. It is shown that the residual resistance factor ratio of water to oil using the synthesized polymer gel nanocomposite in this work is much higher than that of the ordinary polymer gels. The presented results confirm the high performance of the synthesized... 

Asphaltene deposition is a problematic challenge for oil production. Changes in key parameters like pressure and fluid composition during natural depletion and different gas injection scenarios may result in asphaltene precipitation and deposition. In this work, a model is developed by application of mass balance equations, momentum equation, asphaltene deposition and permeability reduction models. An algorithm is developed to perform iterative procedure to solve the numerical equations that contains highly coupled variables. Indeed, an equation is introduced to calculate the saturation of the precipitated asphaltene phase. Model parameters were determined by genetic algorithm which is a... 

Preformed particle gels (PPGs) in solutions have been widely used to suppress excess water production in mature oil reservoirs and, in turn, to improve the amount of oil recovery in brown oil fields. In this study, PPG solutions were meticulously formulated and synthesized in order to be utilized in harsh environments in terms of pressure, temperature, pH, and salinity from a free radical polymerization process. In this work, nanosilica gel at different weight percentages was added to improve the mechanical and thermal stability properties of the PPG at harsh condition: high pressure, temperature, and strain. Moreover, the effects of nanosilica gel at various concentrations, ranging from 0.0...