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    Flux enhancement of thin-film composite membrane by graphene oxide incorporation

    , Article Journal of Environmental Health Science and Engineering ; Volume 17, Issue 1 , 2019 , Pages 377-382 ; 2052336X (ISSN) Jalali, S ; Rashidi Mehrabadi, A ; Shayegan, J ; Mirabi, M ; Madaeni, S. S ; Sharif University of Technology
    BioMed Central Ltd  2019
    Abstract
    Reverse Osmosis (RO) is a rapid-developing desalination technology; however, it suffers from inefficient energy consumption. To reduce energy consumption, in this study, reverse osmosis thin-film composite membrane (TFC) module was prepared and composed of m-phenylenediamine (MPD), graphene oxide, and 1,3,5-benzenetricarbonyl chloride (TMC) by interfacial polymerization on the surface of a polysulfone substrate. The graphene oxide was embedded in the mentioned thin-film composite by adding it to MPD aqueous solution to enhance permeation flux and, thus, reduce energy consumption. This study assessed the performance of the membrane using a lab-scale RO setup and evaluated permeability and... 

    Conceptual arrangement and basic design of drinking water reverse osmosis desalination plants

    , Article International Journal of Environmental Science and Technology ; Volume 18, Issue 12 , 2021 , Pages 4019-4036 ; 17351472 (ISSN) Khodabandehloo, M ; Farhadi, F ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2021
    Abstract
    To propose a conceptual arrangement of reverse osmosis desalination plants, four comprehensive decision algorithms and a software are developed. Typically, commercial software predict the performance of the reverse osmosis membranes based on their pre-determined configuration; however, the developed decision algorithms and the developed software in this study have the capability of introducing the conceptual arrangement of pretreatment units, reverse osmosis membranes, and energy recovery devices for both seawater and brackish water reverse osmosis plants. To perform a comprehensive study, alongside the developed software and the decision algorithms, both design considerations of the... 

    Preparing an Appropriate UF Membrane from PVC to Use it as Substrate in Sea Water Desalination RO Membranes

    , M.Sc. Thesis Sharif University of Technology Sabzi Dizajeyekan, Behnam (Author) ; Bastani, Daruoosh (Supervisor) ; Musavi, Abbas (Supervisor)
    Abstract
    In this study the main goal is preparing an appropriate UltraFiltration membrane from PolyVinyl Chloride for using as substrate in producing efficient Reverse Osmosis membranes to use in sea water desalination. each membrane should have some specifications to use it as reverse osmosis membrane’s substrate. One of the most important specifications is the appropriate pore sizes. To investigate this subject pure water flux and PolyEthylene glycol rejection of prepared membranes is tested. After investigation of this parameters and proving them, RO membranes are prepared using this membranes.
    Salt rejection of Brackish water (2000ppm) and sea water (Persian gulf,32000ppm) are measured in... 

    Biofouling Reduction in Reverse Osmosis Membrane for the Purification Brackish Water

    , M.Sc. Thesis Sharif University of Technology Niknamfar, Rasool (Author) ; Soltanieh, Mohammad (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    In this project, modification of reverse osmosis membrane was investigated in order to reduce the biofouling in treatment of brackish water. Furthermore, the technique which is used to attain the favorable results is graft polymerization to modify the membrane’s surface with grafting acrylic acid as hydrophilic monomer onto polyamide exploited as last layer in reverse osmosis membrane. This technique is a free radical grafting, andfree radicals which are needed for grafting are provided by the redox system potassium persulfate-sodium metabisulfite which was used as initiator. To figure out the best concentration of acrylic acid, initiator and process time in order to achieve a new membrane... 

    Treatment of Blow-down water to Reuse by Membrane Processes, Nanofiltration and Reverse Osmosis

    , M.Sc. Thesis Sharif University of Technology Davood Abadi Farahani, Mohammad Hossein (Author) ; Borghei, Mehdi (Supervisor)
    Abstract
    Petrochemicals, refineries and power plants are among the biggest water-consuming industries. Of all systems in mentioned complex, most water is consumed in the cooling tower system, of which the feed water of the cooling tower accounts for the largest portion of water demand. Drainage loss (blowdown) which constitutes the biggest portion of the feed water losses, varies greatly with changes in source water quality and cooling water treatment. Scarcity of water, large quantities of cooling tower blowdown water and increasing of water price lead to activities for blowdown water treatment to reuse. In this project two pre-treatment methods and two final membrane treatment methods were... 

    Design, Construction and Experimental Study of Effect of a Pressure Intensifier Device on a Small Scale Reverse Osmosis System

    , M.Sc. Thesis Sharif University of Technology Bolhassani, Mohammad (Author) ; Arghavani Hadi, Jamal (Supervisor)
    Abstract
    Nowadays, water and energy shortage is the main concern of many industries. Every saving that could be done is valuable. In the first step of this project, energy recovery devices that are used in reverse osmosis systems, are reviewed and advantages and disadvantages of each system are investigated. These apparatuses save energy by recovering high-pressure energy from leaving brine and reduce the energy consumption of the device. The main focus of this study is energy consumption of the device that is used for desalination of seawater in reverse osmosis systems and on this basis, different energy recovery devices are compared. According to the investigation, results showed that most of the... 

    Effect of Electromagnetic Field on Membrane Fouling in Filtration Process

    , M.Sc. Thesis Sharif University of Technology Rouina, Mohammad (Author) ; Kariminia, Hamid Reza (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    Current research studies the effect of electromagnetic field on reducing precipitation on membrane surface in reverse osmosis. Reverse osmosis is one of the most widely applied methods for water desalinization. Despite its advantages over other desalinization techniques, suffers from shortcomings such as blockage of membrane surface. Use of magnetic fields for reducing precipitation in process equipment, the so-called magnetic treatment, has been studied and practiced for decades. This research intends to study the effect of electromagnetic field on water and its mineral content, and the possibility of its application as a method for reducing precipitation and blockage in reverse osmosis... 

    Waste Water Purification of the Isfahan Zirconium Production Plant (ZPP) by Membrane Process

    , M.Sc. Thesis Sharif University of Technology Chaichi, Mahdieh (Author) ; Samad Fam, Mohammad (Supervisor) ; Yavari, Ramin (Supervisor) ; Haji Hosseini, Majid (Co-Supervisor)
    Abstract
    Isfahan Zirconium Production Plant (ZPP) is one of the most important plants in the nuclear industry of Islamic Republic of Iran. The wastewater of this plant contains high values of Sodium, Chloride, Nitrate and low values of Calcium, Magnesium, Zinc and Zirconium ions. Its release has been banned by international and national law because of the dangers and toxicity of its ions for the environment and living organisms. Therefore, its refinement as a compensation of Iran’s water resources in agriculture and drinking water has received a major consideration. Among the common methods to removal of these ions, membrane process method is selected due to it's major benefits such as not producing... 

    Improvement of performance and fouling resistance of polyamide reverse osmosis membranes using acrylamide and TiO2 nanoparticles under UV irradiation for water desalination

    , Article Journal of Applied Polymer Science ; Volume 137, Issue 11 , 2020 Asadollahi, M ; Bastani, D ; Mousavi, S. A ; Heydari, H ; Vaghar Mousavi, D ; Sharif University of Technology
    John Wiley and Sons Inc  2020
    Abstract
    The purpose of this research is to explain the surface modification of fabricated polyamide reverse osmosis (RO) membranes using UV-initiated graft polymerization at different irradiation times (15, 30, 60, and 90 s) and various acrylamide concentrations (10, 20, and 30 g L−1). Also, coating of membranes surface with various concentrations of TiO2 nanoparticles (10, 20, 30, and 50 ppm) followed by the same UV irradiation times was investigated. After that, the membranes modification was done by grafting of acrylamide blended with TiO2 nanoparticles via UV irradiation. The characterization of membranes surface properties and their performance were systematically carried out. The results... 

    An investigation on using MDCs for an efficient desalination process as pretreatment of reverse osmosis

    , Article Journal of Water Supply: Research and Technology - AQUA ; Volume 69, Issue 4 , 1 June , 2020 , Pages 322-331 Habibi, A ; Abbaspour, M ; Javid, A. H ; Hassani, A. H ; Sharif University of Technology
    IWA Publishing  2020
    Abstract
    Microbial desalination cell (MDC) is a new bio-electrochemical technique which converts chemical energy into electrical energy, and at the same time desalinates water and treats wastewater. In this study, MDC performance and water biofouling conditions were tested as an efficient pretreatment desalination process of reverse osmosis (RO). The experiments were designed in a three-chamber reactor to compare the performance of batch and continuous fed modes, using bio-cathode and synthetic wastewater in four different hydraulic retention times and 17 and 35 g/L NaCl concentrations. According to the results, maximum salt removal of about 52.3% was obtained in the continuously fed MDC at 35 g/L... 

    Modeling and techno-economic study of a solar reverse osmosis desalination plant

    , Article International Journal of Environmental Science and Technology ; Volume 19, Issue 9 , 2022 , Pages 8727-8742 ; 17351472 (ISSN) Ebrahimpour, B ; Hajialigol, P ; Boroushaki, M ; Shafii, M. B ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2022
    Abstract
    In this research, the design of a solar reverse osmosis desalination plant was investigated by integrating various components using TRNSYS and ROSA software. To this goal, a two-stage reverse osmosis system with 50% recovery in the city of Chabahar was modeled. The calculations were performed in three different case studies, i.e., a photovoltaic power plant, a solar collector power plant with Organic Rankine Cycles, and a photovoltaic thermal power plant with Organic Rankine Cycles, with the reverse osmosis desalination plant being a novel investigation. Water production and electrical energy generation of each case study were evaluated both on a daily and yearly bases. The simulation... 

    Monitoring & Optimizing of the Returned Condensated Water as Boiler Make up Water at the Agro-Industry Hakim Farabi Boilers

    , M.Sc. Thesis Sharif University of Technology Askary Bozayeh, Hossein (Author) ; Alamolhoda, Ali Asghar (Supervisor) ; Pourjavadi, Ali (Co-Advisor)
    Abstract
    Vapor in agro-industry hakim farabi production electricity, Turbines force and thermal energy for Yellow and white sugar in sugar production. In the utilization to supply water for the boiler , condensate water return use Until plant be able to do its work ¬good quality of condensate water decrease cost of destruction energy in blow down and can save energy, reduce cost of chemical operation for optimum boiler water and costs associated with wastewater treatment. unclean condensate water consist of sugar and Electrical conductivity more than permissive is not suitable for use in The boiler because Increase the total dissolved solids and decreasing pH lower than the Extent permitted. The... 

    Water Recycling from Output Residual Flow of Reverse Osmosis Membranous Units

    , M.Sc. Thesis Sharif University of Technology Ghashghaei Nezhad, Hossein (Author) ; Moosavi, Abbas (Supervisor)
    Abstract
    In this research, we focus on reduction of solutes in left out water from reverse osmosis membranous units (brine) with reduction of scaling factors of membrane. This research is important from that perspective that the out put brine from reverse osmosis membranous unit After purification by this method, enter into membranous system in order to increase in recovered water volume and also minimization of out put waste from membranous system and decrease the environmental damages. The method used in this research, is three processes of cooling, chemical desalination and seeding by crystal material. In this research is investigated the type and amount of matter for chemical desalination and... 

    Study of Surface Properties and Performance of Reverse Osmosis Membranes after Surface Modification via Irradiation

    , Ph.D. Dissertation Sharif University of Technology Asadollahi, Mahdieh (Author) ; Bastani, Dariush (Supervisor) ; Mousavi, Abbas (Supervisor)
    Abstract
    Today reverse osmosis (RO) is the dominant technology for desalination. Most of commercially available RO membranes are polyamide thin film composite (TFC) types which exhibit good performance. However, the major obstacle for application of polyamide TFC RO membranes is fouling which can be mitigate by surface modification.In this research, surface modification of fabricated aromatic polyamide TFC RO membranes was carried out using UV-initiated graft polymerization at different irradiation times (15, 30, 60, and 90 s) and various acrylamide concentrations (10, 20, and 30 g/L). Also, coating of membranes surface with various concentrations of TiO2 nanoparticles (10, 20, 30, and 50 ppm)... 

    Preparation a Polymeric Membrane for Dehydration of Acetic Acid

    , M.Sc. Thesis Sharif University of Technology Mirfarah, Hesam (Author) ; Mousavi, Abbas (Supervisor) ; Bastani, Dariush (Supervisor)
    Abstract
    The separation ofacetic acids in binary water solutions hasbeenstudied using a reverse osmosis (RO) membrane. Thin film composite polyamide membrane is used in this study.Thin-film composite (TFC) membrane was prepared through the interfacial polymerization between m-phenylenediamine (MPD) and trimesoyl chloride (TMC) on the polysulphone support membrane.The solute permeation was carried out under applied pressure of 5 bar at 25°C. In this work the effect of various synthesis conditions on the membrane performance was investigated. Parametric studies were conducted by varyingconcentration of reactants, reaction time, curing time and curing temperature. By suitable combination of these... 

    Hydrodynamic Simulation of Flow in Reverse Osmosis Membranes for Seawater Disalination

    , M.Sc. Thesis Sharif University of Technology Yarmohammadi, Amir Mohmamad (Author) ; Seif, Mohamad Saeed (Supervisor) ; Mehdigholi, Hamid (Supervisor)
    Abstract
    Water is the most essential human need and the lack of fresh water soon is one of the biggest problems of mankind. One way to deal with the lack of fresh water is desalination of seawater. Seawater desalination is done by different thermal and membrane methods. In this research, the methods and history of freshwater supply methods and the role of chains in the progress of seawater desalination, and the measures taken in the field of seawater desalination have been investigated. Among the various methods discussed and proposed in this research, it was concluded that reverse osmosis membrane is available and has an acceptable economic efficiency compared to other methods. After choosing the... 

    Designing and Modeling of a Hybrid System Based on Electrodialysis for Desalinating Brine

    , M.Sc. Thesis Sharif University of Technology Doostmohammadi, Mohammad Reza (Author) ; Moosavi, Ali (Supervisor) ; Hoseini, Vahid (Supervisor)
    Abstract
    The world's freshwater resources are rapidly decreasing due to population growth, industrial and technological progress, successive droughts, climate changes, increased food demand, and poor management of water resources. Using desalination methods is one of the ways to produce the required freshwater. Several methods have been developed for desalination. The most widely used method is reverse osmosis (RO). In this thesis, an electrodialysis (ED) desalination system was designed and modeled using up-to-date and reliable articles. This modeling was done in EES software and after validating that, the effect of considering Donnan's potential was investigated. At the 60 ppt concentration of the... 

    Numerical Simulation and Optimization of Sea Water Desalination by Reverse Osmosis Membrane

    , M.Sc. Thesis Sharif University of Technology Fouladi Moghaddam, Farshad (Author) ; Mousavi, Ali (Supervisor)
    Abstract
    Reverse osmosis (RO) is by far the most widely used membrane desalination process worldwide. The RO process depends on the properties of semi-permeable membranes which allow the separation of water from a salt solution by applying external pressure higher than the osmotic pressure on the seawater. The main problem in membrane separation process is the fouling of the membrane walls, which decreases the permeate flux. Having spacer filaments in the feed channel has been proven to dynamically change the concentration boundary layer and preventing fouling. The impact of spacer configurations (cavity, zigzag and submerged) on the alleviation of concentration polarization and the enhancement of... 

    Ion Separation through a Y-Shaped CNT Membrane- A Molecular Dynamics Simulation

    , M.Sc. Thesis Sharif University of Technology Karimi, Sajjad (Author) ; Mousavi, Ali (Supervisor) ; Sadrhosseini, Hani (Supervisor)
    Abstract
    Nowadays, water desalination is a widely-used method for producing clean and fresh water. Recent researches in this area have mostly focused on Reverse Osmosis technology which is one of the most efficient technologies in water desalination. A new idea to increase the efficiency of a recently-designed reverse osmosis membrane called “Honeycomb Carbon Nanotube Membrane” is presented through molecular dynamics simulation. Although in this study only the inlet area of the honeycomb structure which is a Y-shaped entrance, is modeled and studied, but obviously, any improvement in the membrane inlet, equals better results at outlet which means a more efficient desalination process. Present thesis... 

    Design and Modification of Side Stream Filters of Blow-Down Water in Cooling Water System

    , M.Sc. Thesis Sharif University of Technology Beigi, Amir Hossein (Author) ; Mousavi, Ali (Supervisor) ; Sadr Hosseini, Hani (Supervisor)
    Abstract
    The use of superhydrophobic surfaces is one the most promising methods for reducing the friction and increasing the flow rate in fluid transfer systems. Since in such systems the surface structure plays a key role, in the first part of this study, the performance of the hierarchical nanostructures is explored. These nanostructures are inspired by the superhydrophobic surface of the lotus leaf. The flow is considered between two walls with hierarchical nanostructures and simulate the system via the molecular dynamics (MD) method. The size of the nanostructures and the distance between them have been studied to find whether a design with maximum flow rate exists. The nanostructures have two...