Sharif Digital Repository

An on-line extraction/determination set up was designed for micro solid-phase extraction of clodinafop propargyl from water, soil and wheat samples using electrospun polyamide nanofiber mats. The prepared mats were packed in a stainless steel tube which conveniently acted as a high-performance liquid chromatography injection loop. Influential parameters affecting the extraction efficiency were optimized using a distilled water sample fortified with 25 μg L-1 of clodinafop propargyl. An enrichment factor of 440 was achieved for clodinafop propargyl indicating the ability of the whole procedure. Under the optimum conditions, the linearity for the analyte was in the range of 6-700 μg L-1, while... 

This paper addresses the impacts of climate change on hydrology and water resources in the Karkheh River Basin (KRB), which is the third most productive basin in Iran and has great potential for hydropower generation. The total potential capacity of reservoirs in this basin is more than 15 ×109 Mm3, of which 40% has been built. The sensitivity of the KRB to potential climate change is investigated by simulating basin streamflow response under different climate change scenarios. A conceptual rainfall-runoff model (IHACRES) was first calibrated by using hydrological and streamflow observations. The model was then applied by downscaling two general circulation model outputs (CGCM3 and HadCM3)... 

Accurate estimation of scour depth is needed for economic and safe determination of bridge pier foundation depth. Most design criteria are based on maximum scour depth due to the steady design discharge without flow time limit. In this paper, the results are presented of an experimental investigation on local scouring around a single bridge pier under steady and unsteady flow regimes. For unsteady flow, triangular shape hydrographs with repeatable peaks have been chosen. Results show that both sharp and flat increases to the peak of hydrographs have a negligible effect on scour depth for the same base time. An equation is obtained to compute the scour depth due to a specific triangular... 

The inherent complexities of multi-reservoir flood control systems and their operation conditions along with the improvements of optimization methods have led to a positive trend on better development of these models. This trend tends to provide the operators of these systems with more practical solutions. Although optimization models can provide appropriate solutions for operation of multi-reservoir systems, the exact implementation of these solutions in real world is not guaranteed. This arises mainly due to high level risk of flood situation, real time operation constraints, high level uncertainties of inflows that usually are overlooked in optimization models, and so on. These problems... 

Background & objectives: Malaria is the most important mosquito-borne disease in Iran. It is endemic in south to southeastern part of the country. Knowledge about bio-ecology of vectors will support authorities for appropriate management of the disease. Bashagard district is one of the main endemic areas for malaria in south of Iran. This study was conducted to determine anopheline fauna, diversity and affinity in the area, characterization of larval habitats, and mapping their potential distribution across the district. Methods: The potential aquatic habitats for Anopheles larvae were extracted from Indian Remote Sensing Satellite (IRS) image and digital elevation model of the area using... 

In the present paper, the seismic response of an arch dam subjected to spatial variation of ground motions along the interface with its foundations is investigated. Recorded ground accelerations at the dam foundation interface of an arch dam were used for the purpose of this investigation. Topographic amplification between various points of the interface was studied by obtaining ratios of the response spectral displacement and spectral pseudo acceleration. Time shift and amplification between stations show the nonuniform nature of ground motions for large structures like dams. Recorded ground accelerations were interpolated for different nodes of the finite element model. The seismic... 

A new facile, rapid, inexpensive, and sensitive method based on magnetic micro-solid phase extraction (M-μ-SPE) coupled to gas chromatography-mass spectrometry (GC-MS) was developed for determination of the herbicide oxadiargyl in environmental water samples. The feasibility of employing non-modified magnetic nanoparticles (MNPs) as sorbent was examined and applied to perform the extraction process. Influential parameters affecting the extraction efficiency along with desorption conditions were investigated and optimized. The limit of detection (LOD, S/N = 3) and limit of quantification (LOQ, S/N = 10) of the method under optimized conditions were 0.005 and 0.030 ng mL-1, respectively. The... 

Flood control as an important purpose of reservoir systems faces a wide range of natural, social and political challenges, mainly due to different uncertainties. Over the time, these uncertainties call for necessary changes in the original plan of the systems. Therefore, construction of new flood control systems as well as the storage reallocation and reservoir reoperation of existing ones are essential for adapting the systems to new information, conditions and policies. Furthermore, multipurpose nature of the multi-reservoir systems requires considering conflicts among various purposes. In this paper, a multiobjective optimization model is developed for analyzing such conflicts in a... 

Changes of morphological parameters of oil shale under thermal conditions are investigated. Analyses are based on 26 micro-computed tomography (micro-CT) images of Green River immature shale rock available under creative commons license. Several image processing and characterization algorithms are applied to sequential high-resolution micro-CT images of oil shale samples undergoing pyrolysis. Pore-scale morphology is extracted and quantified, providing results for pore size, throat size, grain size, specific surface, coordination number, and fracture aperture. The results demonstrate critical increases of porosity, coordination number and fracture aperture in the temperature range from 390... 

Understanding controls of P movement through watersheds are essential for improved landscape management in intensively managed regions. Here, we analyze observational data from 104 gaged river sites and 176 nongaged river sites within agriculturally dominated watersheds of Minnesota, USA, to understand the role of landscape features, land use practices, climate variability, and biogeochemical processes in total, dissolved and particulate P dynamics at daily to annual scales. Our analyses demonstrate that factors mediating P concentration-discharge relationships varied greatly across watersheds and included near-channel sediment sources, lake and wetland interception, assimilation by algal P,... 

Dam construction in arid and semiarid regions is generally related to the risk of increased salinity, due to water passage in contact with salty formations. Hence, it is important to take reservoir thermal and salinity stratification into account in operational rules. In the present study, a simulation–optimization model was developed to determine the amount of water release from various outlets to discharge the brine from hypolimnion layer considering the downstream water quality limitations. The most appropriate time, rate, and concentration to release brine were determined based on water consumption conditions and downstream water demand and river ecology characteristics. The proposed... 

The global demand for renewable energy sources has arisen significant research interests in marine hydrokinetic energy harvesting from flow induced vibrations. The current study deals with the hydrokinetic energy harvesting potentials of diamond and square oscillators at various inline configurations. Both the sharp edge sections and the wake induced vibrations in tandem arrangement can lead to galloping type of instability with high energy efficiency ratios. The present in-water towing tank experiments comprise 1DoF vibrating systems at Re ranging from 2 × 103 to 4.8 × 104. The results show that the upstream wake generally enhances the system efficiency and the mechanical work done by the... 

The Shadegan Wetland is a Ramsar-listed wetland in the south-west of Iran at the head of the Persian Gulf. It is the largest wetland of Iran covering about 400,000 hectares. The wetland plays a significant hydrological and ecological role in the natural functioning of the northern Gulf. It also supports a very diverse flora and fauna and is the most important site in the world for Marbled Teal. The water regime is threatened by upstream abstraction of water for irrigation and the saline discharge from sugar cane industries and irrigation schemes. This will result in an overall reduction in wetland water quantity and quality, leading to a change in plant community composition. This paper... 

The on-fiber standardization technique for solid-coated solid-phase microextraction (SPME) was studied, and a theoretical model is proposed for the isotropic behavior of adsorption and desorption, based on Fick's law of diffusion and the Langmuir model. The isotropy of the adsorption and desorption of analytes onto and from the surface of porous solid SPME fiber was validated with the use of a commercially available fiber, a 50-μm Carbowax/ templated resin for carbamate pesticide analysis in various sample matrixes, and a self-made polypyrrole fiber for diazepam analysis in blood samples. Time constants were comparable for the adsorption and desorption processes. Equilibrium constants and... 

An immersed solvent microextraction (SME) method was successfully developed for the trace enrichment of s-triazine herbicides from aquatic media. A microdrop of butyl acetate was applied as the extraction solvent. After extraction, the microdrop was introduced directly into a gas chromatography-mass spectrometry (GC-MS) injection port. Some important extraction parameters such as type of solvent, extraction time, stirring rate, and temperature were investigated and optimized. The highest possible microdrop volume of 3 μl, a sampling temperature of 60°C, and use of butyl acetate are major parameters to obtain high enrichment factors. The enrichment factor and linearity was studied by... 

A three-dimensio111nal boundary element solution for the seepage analysis in multi-domain general anisotropic media has been developed based on the transformation approach. Using analytical eigenvalues and eigenvectors of the hydraulic conductivity tensor, a closed-form coordinate transformation matrix has been provided to transform the quadratic form of governing equation of seepage for the general anisotropic media to the Laplace equation. This transformation allows the analysis to be carried out using any standard BEM codes for the potential theory on the transformed space by adding small pre- and post-processing routines. With this transformation, any physical quantity like the total... 

In this research, an attempt was made to investigate the potential of nanophotocatalysts for treatment of hazardous wastewater streams. Titanium dioxide nanoparticles (as photocatalyst) were immobilized on a porous and low-density support called "perlite" using a very simple and inexpensive method. TiO2-coated perlite granules were used in a "Floating-bed photoreactor" to study the photocatalytic purification process of a typical wastewater polluted by furfural. The effects of initial concentration, catalyst mass/solution volume ratio, oxidant molar flow, residence time, and light intensity on process removal efficiency, and kinetics of the reactions were studied. SEM analyses showed a... 

This study presents a comprehensive review of the Land subsidence (LS) cases, as a worldwide environmental, geological, and global geohazard concern. Here, 290 case studies around the world mostly conducted in large metropolitan cities (e.g. Bangkok, Beijing, California, Houston, Mexico City, Shanghai, Jakarta, and Tokyo) in 41 countries were collected. The spatial distribution of LS characteristics (e.g. intensity, magnitude, and affected area), impacts, and influential factors are scrutinized. Worldwide attempts to remedy the crisis of LS were also investigated in this review. It is shown that the coastal plains and river deltaic regions are of high-frequent subsided areas around the world... 

Reinforced polydiphenylamine (PDPA) nanocomposite was synthesized by oxidation of diphenylamine in 4molL-1 sulfuric acid solution containing a fixed amount of carbon nanotubes (CNTs) in the presence of cetyltrimethylammonium bromide (CTAB). The surface characteristic of PDPA and PDPA/CNT nanocomposites was investigated using scanning electron microscopy (SEM). The prepared PDPA/CNT nanocomposite was used as an extraction medium for microextraction in packed syringe (MEPS) of selected pesticides from aquatic environment. The effect of CNT doping level and the presence of surfactant on the extraction capability of nanocomposite was investigated and it was revealed that when 4% (w/w) of CNT in...