Sharif Digital Repository

Dam construction in arid and semiarid regions is generally related to the risk of increased salinity, due to water passage in contact with salty formations. Hence, it is important to take reservoir thermal and salinity stratification into account in operational rules. In the present study, a simulation–optimization model was developed to determine the amount of water release from various outlets to discharge the brine from hypolimnion layer considering the downstream water quality limitations. The most appropriate time, rate, and concentration to release brine were determined based on water consumption conditions and downstream water demand and river ecology characteristics. The proposed... 

Enhanced Oil Recovery (EOR) methods have been widely used around the world to improve oil production from petroleum reservoirs. Recently, the injection of the low salinity/smart water has gained popularity among the EOR methods. Different mechanisms are believed to exist during low salinity/smart water injection, including dissolution, precipitation, and ion exchange at the rock surface. In this study, a coupled geochemical-transport model is presented for the detailed analysis and investigation of the interactions between brine, sandstone and carbonate rocks. The proposed model presents the coupling of a geochemical software (PHREEQC) and a species transport model. This coupled method makes... 

Low salinity water flooding (LSWF) has the potential to enhance the oil recovery by affecting the fluid-fluid and rock-fluid interactions. Therefore, a systematic investigation on the effect of initial wetting state (water-wet or oil-wet) of pure calcite is conducted to study the importance of these interactions on the effectiveness of LSWF. In the case of initially water-wet cores, more oil recovery efficiency is observed for more saline water cases. To shed light on the possible involved mechanisms, dynamic IFT, dynamic contact angle (CA), oil/brine and rock/brine surfaces zeta potentials, and effluent pH are measured. It is shown that the short-term effect of IFT reduction and long-term... 

Photothermally heated and mesh-gridded membrane distillation (PHMD) system is proposed for desalination of high saline aqueous solutions. A triple-layered membrane, composed of a photothermal top nanofibrous layer containing polyacrylonitrile and dispersed carbon black nanoparticles and a polyvinylidene fluoride porous membrane supported on a nonwoven polyester, was prepared. A polypropylene mesh was used to hold the membrane. A 3D numerical simulation of the PHMD system was carried out by COMSOL and the appropriate length of the membrane module was determined. The effects of various operating parameters including solar radiation intensity on the permeate flux and thermal efficiency were... 

Oil polarity is an important property impacting the efficiency of low salinity waterflooding (LSWF). It directly affects fluid/fluid and rock/fluid interactions, controlling the interfacial properties and forces. However, the current findings in the literature on the effect of concentration of polar components on oil recovery by LSWF are contradictory. Therefore, the main objective of this paper is to investigate how the type of non-polar fractions and the concentration of acidic polar oil constituents change the trapped oil saturation at the pore-scale during LSWF. In this regard, we conducted a series of microfluidics LSWF experiments in both secondary and tertiary modes, using clay-free... 

Clay liners are widely used as porous membrane barriers to control solute transport and to prevent the leakage of leachate both in horizontal and vertical flow scenarios, such as the isolated base and ramps of sanitary landfills. Despite the primary importance of saturated hydraulic conductivity in a reliable simulation of fluid flow through clay barriers, there is no model to predict hydraulic conductivity of clayey soils permeated with saline aqueous solutions because most of the current models were developed for pure water. Therefore, the main motivation behind this study is to derive semi-empirical models for simulating the hydraulic conductivity of clayey soils in the presence of... 

In this study a membrane bioreactor (MBR) has been studied experimentally for the treatment of oil field wastewater (produced water). This type of wastewater is characterised with relativity moderate to high amount of salt and oil. The normal bacteria which are growing in conventional activated sludge and MBR cannot withstand at these adverse conditions, therefore it is necessary to be adapted. In this study, different samples from sea sediment in Bushehr (south of Iran) were analysed and different groups of bacteria were isolated and adapted for surveying under high salinity conditions. The performance and efficiency of these bacteria in the degradation of model oil has been studied. The... 

This study aims to investigate the role of fluid-fluid interactions during low salinity water flooding, using crude oil from an Iranian oil reservoir. To minimize the effects of mineral heterogeneity and wettability alteration, a synthetic sintered glass core was utilized and all coreflooding experiments were performed at low temperatures without any aging process. The effect of fluid-fluid interactions were investigated in both secondary and tertiary injection modes. pH measurements as well as UV-Vis spectroscopy and interfacial tension (IFT) analysis were performed on the effluent brine samples. Results: show that fluid-fluid interactions, mainly the dissolution of crude oil polar... 

During the low salinity waterflooding (LSWF) of a viscous asphaltic oil reservoir, fluid-fluid interactions have a large influence on the fluid flow, pore-scale events, and thus oil recovery efficiency and behavior. In-situ water-in-oil (W/O) emulsion formation is a consequence of crude oil and brine interfacial activities. Despite the published studies, the pore-scale mechanisms of W/O emulsion formation and the role of injected brine salinity, injection rate, and pore-scale heterogeneity on emulsion formation and stability requires a deeper understanding. To address these, a series of static and dynamic micro-scale experiments were performed. The salinity dependent oil-brine interactions... 

One of the possible fluid-fluid interactions during water-flooding in oil reservoirs, that is still debated, is the effect of injected brine salinity on asphaltene destabilization. If asphaltene precipitation is induced by salinity changes in the oil reservoirs and surface facilities, this could have a massive impact on the economy of a low salinity water-flooding project. Therefore, this study aims to investigate the effect of brine salinity on the amount of asphaltene precipitation and the governing destabilization mechanisms. Direct asphaltene precipitation measurements, along with the analyses of optical microscopy images and ion chromatography (IC), indicate that the asphaltene...