Sharif Digital Repository

Movement and transportation of fine particles in formations leads to clogging the pores and reduction in permeability. This type of formation damage is stronglycontingent upon water salinity and ionic conditions in the formation. The main parameters which control the particle release are the interactions and forces between particles and porous medium surfaces. Changing salinity which leads to pH alteration, affects these interactions and subsequently the fine migration process. Hence, pH and salinity variations should be considered to study and evaluate the portion of fine migration in formation damage. The principal challenge in this research therefore, is to try to change the surface... 

Due to the hopeful potential of nanoparticles in medicine, they have attracted much attention for various applications such as targeted drug/gene delivery, separation or imaging. Interaction of NPs with the biological environment can lead to a wide range of cellular responses. In order to have safe NPs for biomedical applications, the current biocompatibility researches are particularly focused on the severe toxic mechanisms which cause cells death. These mechanisms are apoptosis, autophagy and necrosis, which can also be intricately linked with the cell-life cycle, as there are various check-points and controls in a cell's life cycle to ensure appropriate division processes. Mechanisms by... 

The main objectives of this study are to determine the influence of crude oil type, salinity, temperature and pressure on the dynamic interfacial tension (DIFT) of crude oil based on the experiments and modeling approaches. DIFT is also modeled using dynamic adsorption models, mono-exponential decay model as well as empirical equations. The results showed that when temperature increases, unlike deionized water which inversion phase temperature was observed, the equilibrium IFT of crude oils/sea water increases due to reduction of surface excess concentration of natural surfactants at the fluid/fluid interface as a dominant mechanism  

Calcite is among the most abundant minerals organizing the oil reservoir formation and therefore its surface properties play a central role in the increase of the oil recovery efficiency. The effect of low-salinity water in carbonate rocks reveals that brine composition and salinity can improve the oil recovery in carbonates through wettability alteration. However, the specific mechanism for wettability changes that leads to improved oil recovery in calcite is not well understood. To obtain deeper insights at atomic level into the understanding the characteristics of the calcite-water interface, we performed classical molecular dynamics simulations in the presence of different ions in brine... 

Urmia Lake, located in a closed basin in north-west Iran, is the largest lake (5000-6000 km2) in the Middle East. It is very saline with total dissolved salts reaching 200 g/l compared with a normal seawater salinity of about 35 g/l. The construction of a causeway, which was initiated in 1979 but then abandoned until the early 2000s, is near completion and will provide road access between the western and eastern provinces. The causeway has an opening 1.25 km long and divides Urmia Lake into a northern and southern basin and restricts water exchange. The flow and salinity regimes are affected by the presence of this new causeway, and there are concerns over the well being of the Artemia... 

Lake Urmia is a thalassohaline ecosystem. It is an extremely simple ecological pyramid. This makes it a very sensitive ecosystem. This ecosystem has been facing various threats regarding the amount of water released from the associated basin. To calculate the lake water requirement with an ecological approach, we identified three variables: ecology, water quality, and water quantity indices as environmental indicators. The ecological index represented by Artemia urmiana is considered as an independent variable; while, the water quality index represented by concentration of NaCl, and the water quantity index represented by water elevation are regarded as dependent variables. The salinity... 

The work presented here is a study of the steady withdrawal of water from the lens of freshwater situated above the ocean's salt water and within the island. It is the aim of this paper to investigate the process of withdrawal from the lens of freshwater with a view to establishing the critical flow values for withdrawal and the effects of sink location and density differences on these values, and also to determine the effects of relative density differences.Steady solutions are found for the shape of the interface between salt and freshwater beneath a tropical island. A Green_s function approach is used and proves to be much more robust than spectral methods. Computations of the surface... 

The work presented here is a study of the steady withdrawal of water from the lens of freshwater situated above the ocean's salt water and within the island. It is the aim of this paper to investigate the process of withdrawal from the lens of freshwater with a view to establishing the critical flow values for withdrawal and the effects of sink location and density differences on these values, and also to determine the effects of relative density differences. Steady solutions are found for the shape of the interface between salt and freshwater beneath a tropical island. A Green_s function approach is used and proves to be much more robust than spectral methods. Computations of the surface... 

The slow kinetics of wettability alteration toward a more water-wetting state by low-salinity waterflooding (LSWF) in oil-brine-rock (OBR) systems is conjectured to be pertinent to the electrokinetic phenomena in the thin brine film. We hypothesize that the nanoscale physicochemical heterogeneities such as surface roughness and surface charge heterogeneity at the rock/brine interface control further the dynamics of electrodiffusion and electrostatic disjoining pressure (Πel), thus the time-scale and the magnitude of the low salinity effect (LSE). In this regard, film-scale computational fluid dynamics (CFD) simulations were performed. The coupled Poisson-Nernst-Planck (PNP) equations were... 

Understanding the fresh groundwater lens (FGL) behavior and potential threat of climatic-induced seawater intrusion (SWI) are significant for the future water resources management of many small islands. In this paper, the FGL of Kish Island, an arid-region case in the Persian Gulf, Iran, is modeled using two-dimensional (2D) and three-dimensional (3D) simulations. These simulations are based on the application of SUTRA, a density-dependent groundwater numerical model. Also, the numerical model parameters are calibrated using PEST, an automated parameter estimation code. Firstly a detailed conceptualization of the FGL model is completed to understand the sensitivity of the FGL to some... 

The effect of an efficient biosurfactant produced from Pseudomonas aeroginosa MR01, a bacterial strain isolated from oil excavation areas in southern Iran, on the recovery of residual oil trapped within carbonate rocks, was investigated. In a core holder set-up, bearing a number of limestone-and dolomite-containing core samples, biosurfactant flooding resulted in oil recoveries as large as 20% to 28% Residual Oil (R.O). Biosurfactant injection in less permeable rocks in a range of 0.5 to 32 md was more successful, in terms of oil production. In the case of the least oil recovery via biosurfactant flooding, incubation of the core with a biosurfactant solution at reservoir conditions,... 

Recently, microalgae has received a high attention for application in bioelectrochemical systems due to its potential to be used for oxygen generation and biodiesel production. In this study performance of algal biocathode in a microbial desalination cell (MDC) was evaluated against air cathode and biocathode microbial fuel cell (MFC). Effluent of a dairy wastewater treatment plant with COD of 1000 mg l-1 was utilized as substrate in the anode and the microalgae Chlorella vulgaris was inoculated in the cathode using a synthetic culture media. Experiments were conducted using two different saline water concentrations including 15 g l-1 (MDC-1) and 35 g l-1 (MDC-2) in a desalination cell and... 

Low salinity (LS) and smart water (SW) flooding processes which receive a great interest as cost-effective and environmental friendly techniques are relatively new enhanced oil recovery methods. Although shifting carbonate surfaces towards a water-wet state is the main mechanism behind these methods, effects of controlling factors (for instance: ion type or salinity) are already remained unsettled. In this regard, the effects of sulfate ion types (i.e. Na2SO4, MgSO4 and CaSO4) and their concentrations (i.e. 0–45,000 ppm) on wettability alteration are investigated using contact angle (CA) measurement technique. In addition, work of cohesion, work of adhesion and spreading coefficient of all... 

Smart water flooding as a developing technique utilizes modified water chemistry in terms of salinity and composition to prepare the best-suited brine composition for a specific brine/oil/rock system to obtain higher oil recovery efficiency. Huge amount of unrecovered oil is expected to be remained in carbonate reservoirs; however, few research works on incremental oil recovery during smart water injection in carbonate cores at reservoir condition are reported. Several core flooding tests using one of the Iranian carbonate reservoir rock are conducted to check the effectiveness of smart water injection for more oil recovery efficiency. The results reaffirm the positive effect of sulfate ions... 

Access to potable water with standard quality is an inevitable component of human's lives. Freeze desalination, by consuming lower energy compared to other techniques, relies on the exertion of a cold source which is then accompanied by simultaneous rejection of impurities from water. Regarding this, a numerical study on freeze desalination in a hollow cylinder is carried out to determine the effects of the design variables such as heat flux, hydraulic diameter, initial salt concentration, and freezing time on the ice mass, ice salinity, ice generation speed, and Nusselt number on the cold surface of the inner tube. Results show that increasing the value of heat flux from −250 [Formula... 

One of the key open questions in the area of low or controlled salinity water flooding (LSWF or CSWF) is how the observed oil recovery at macro-scale (e.g. Darcy or core-scale) can the explained and what underlying microscopic mechanisms drive it. Thus far, the micromodel investigation of LSWF has been limited to sandstones, remaining challenging to apply to carbonates. In this paper we aim to i) extend the capability to fabricate a novel calcite micromodel using Iceland spar calcite crystal, ii) investigate the pore-scale mechanisms leading to oil recovery from carbonates. A target crude oil-brine-rock (COBR) system was first selected. To screen potential brines which can produce...