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    Pore scale visualization of fluid-fluid and rock-fluid interactions during low-salinity waterflooding in carbonate and sandstone representing micromodels

    , Article Journal of Petroleum Science and Engineering ; 2020 Siadatifar, S. E ; Fatemi, M ; Masihi, M ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    Low Salinity Waterflooding (LSWF) has become a popular tertiary injection EOR method recently. Both fluid-fluid and fluid-rock interactions are suggested as the contributing mechanisms on the effectiveness of LSWF. Considering the contradictory remarks in the literature, the dominating mechanisms and necessary conditions for Low Salinity Effect (LSE) varies for different crude oil-brine-rock (CBR) systems. The aim of the present study is to investigate LSE for an oil field in the Middle East that is composed of separate sandstone and limestone layers. Contact angles and Interfacial Tension (IFT) are measured to have more insight on the CBR under investigation. Visual experiments were... 

    Effect of heterogeneity of layered reservoirs on polymer flooding: An experimental approach using five-spot glass micromodel

    , Article 70th European Association of Geoscientists and Engineers Conference and Exhibition - Incorporating SPE EUROPEC 2008, Rome, 9 June 2008 through 12 June 2008 ; Volume 3 , 2008 , Pages 1445-1454 ; 9781605604749 (ISBN) Meybodi, H. E ; Kharrat, R ; Ghazanfari, M. H ; Sharif University of Technology
    Society of Petroleum Engineers  2008
    Abstract
    Despite the numerous experimental studies, there is a lack of fundamental understanding about how the local and global heterogeneity control the efficiency of polymer flooding. In this work a series of water and polymer injection processes are performed on five-spot glass micromodels which are initially saturated with the crude oil at varying conditions of flow rate, water salinity, polymer type and concentration. Three different pore structures in combine with different layer orientations are considered for designing of five different micromodel patterns. It has been observed that the oil recovery of water flooding is increasing with the salinity concentration, for the ranges studied here.... 

    A novel energy storage system for latent heat recovery in solar still using phase change material and pulsating heat pipe

    , Article Renewable Energy ; Volume 163 , 2021 , Pages 2115-2127 ; 09601481 (ISSN) Khalilmoghadam, P ; Rajabi Ghahnavieh, A ; Shafii, M. B ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    In this study, a latent heat storage unit and built-in condenser were integrated with a solar still. Storage of dissipated latent heat of vapor during the day and using it after sunset prolongs system operation. During the day, the entire solar radiation was consumed to heat the saline water and only the heat coming from the condensation of vapor was stored in the phase change material (PCM). The dissipated heat from the condenser body was transferred to the PCM and stored. Additionally, the existence of PCM on the outer surfaces of the condenser prevented the rise of condenser wall temperature during the day and kept the condenser temperature low. After sunset, the heat stored in the PCM... 

    Experimental investigation on synergic effect of salinity and pH during low salinity water injection into carbonate oil reservoirs

    , Article Journal of Petroleum Science and Engineering ; Volume 202 , 2021 ; 09204105 (ISSN) Mehraban, M. F ; Ayatollahi, S ; Sharifi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Interaction between rock-fluid and fluid-fluid can have a significant effect on oil recovery. Changing the wettability of reservoir rock toward more water-wet or less oil-wet state is one of the expected mechanisms during low salinity water injection (LSWI). pH and salinity are of the most eminent factors of injection water controlling the wettability state of a crude oil/brine/rock system during any waterflooding operation. A small change in pH can affect the surface charges at the rock/water and oil/water interfaces leading to wettability alteration in a porous medium. In this study, the synergic effect of salinity and pH on the wettability state of carbonate rocks is evaluated through... 

    Direct numerical simulation of the effects of fluid/fluid and fluid/rock interactions on the oil displacement by low salinity and high salinity water: Pore-scale occupancy and displacement mechanisms

    , Article Journal of Petroleum Science and Engineering ; Volume 196 , 2021 ; 09204105 (ISSN) Alizadeh, M ; Fatemi, M ; Mousavi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

    Direct numerical simulation of the effects of fluid/fluid and fluid/rock interactions on the oil displacement by low salinity and high salinity water: pore-scale occupancy and displacement mechanisms

    , Article Journal of Petroleum Science and Engineering ; Volume 196 , 2021 ; 09204105 (ISSN) Alizadeh, M ; Fatemi, M ; Mousavi, M ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Laboratory experiments have shown that performance of waterflooding in oil reservoirs could be significantly increased by lowering the ionic strength and/or manipulation of its composition, which is generally known as low salinity waterflooding (LSWF). The involved mechanisms in additional oil production can be generally categorized in two categories, fluid/fluid and fluid/rock interactions. The distribution of the phases and the involved displacement mechanisms would be strongly affected by the inter-relations between capillary and viscous forces. Although there have been recent advances in the simulation of the LSWF at core scale and beyond and some models are included in commercial... 

    Impact of rock morphology on the dominating enhanced oil recovery mechanisms by low salinity water flooding in carbonate rocks

    , Article Fuel ; Volume 324 , 2022 ; 00162361 (ISSN) Farhadi, H ; Ayatollahi, S ; Fatemi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Because of the complex nature of carbonate reservoirs, the required conditions for effective Low Salinity Water Flooding (LSWF) in these reservoirs need further and in depth investigation. In the present study, three calcite cores, i.e. Cal-1, Cal-2, and IL, with the same chemical composition are subjected to tertiary low salinity water flooding (LSWF), while the crude oil and composition of flooding brine kept the same. The experimental results show significant difference in the amount of enhanced oil recovery, as IL had the most additional oil recovery (20.8 % of IOIP), followed by Cal-2 (10.5 % of IOIP) and Cal-1 (3.9 % of IOIP). The results of contact angle, zeta potential, and effluent... 

    Effect of permeability heterogeneity on the dissolution process during carbon dioxide sequestration in saline aquifers: two-and three-dimensional structures

    , Article Geomechanics and Geophysics for Geo-Energy and Geo-Resources ; Volume 8, Issue 2 , 2022 ; 23638419 (ISSN) Mahyapour, R ; Mahmoodpour, S ; Singh, M ; Omrani, S ; Sharif University of Technology
    Springer Science and Business Media Deutschland GmbH  2022
    Abstract
    Abstract: The convection–diffusion process of carbon dioxide (CO2) dissolution in a saline reservoir is investigated to shed light on the effects of the permeability heterogeneity. Using sequential Gaussian simulation method, random permeability fields in two and three-dimension (2D and 3D) structures are generated. Quantitative (average amount of the dissolved CO2 and dissolution flux) and qualitative (pattern of the dissolved CO2 and velocity streamlines) measurements are used to investigate the results. A 3D structure shows a slightly higher dissolution flux than a 2D structure in the homogeneous condition. Results in the random permeability fields in 2D indicates an increase in the... 

    Microfluidics experimental investigation of the mechanisms of enhanced oil recovery by low salinity water flooding in fractured porous media

    , Article Fuel ; Volume 314 , 2022 ; 00162361 (ISSN) Mahmoudzadeh, A ; Fatemi, M ; Masihi, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Spontaneous imbibition of water from fracture into the matrix is considered as one of the most important recovery mechanisms in the fractured porous media. However, water cannot spontaneously imbibe into the oil-wet rocks and as a result oil won't be produced, unless the capillary pressure barrier between fracture conduits and matrix is overcome. Wettability alteration is known as the main affecting mechanism for low salinity water flooding (LSWF), however, its effectiveness in fractured porous media has been less investigated, especially in the case of possible pore scale displacement mechanisms. In this study, the effectiveness of LSWF (diluted seawater) on oil recovery is compared to the... 

    Pore network-scale visualization of the effect of brine composition on sweep efficiency and speed of oil recovery from carbonates using a photolithography-based calcite microfluidic model

    , Article Journal of Petroleum Science and Engineering ; Volume 208 , 2022 ; 09204105 (ISSN) Mohammadi, M ; Nikbin Fashkacheh, H ; Mahani, H ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    A novel photolithography-based technique was developed to fabricate a quasi-2D heterogeneous calcite micromodel of representative elementary volume size. The effect of brine-chemistry on the mobilization of capillarity and heterogeneity trapped oil after high salinity water injection was evaluated by using diluted seawater, and seawater modified with calcium, sulphate, and silica nanoparticles. Preliminary brine screening was performed based on modified contact angle experiments under dynamic salinity alteration. The main findings are that the chemical composition of brine impacts both the ultimate oil recovery and its speed. The highest and fastest oil recovery was obtained with diluted... 

    Effect of Salinity on MLE Process Function

    , M.Sc. Thesis Sharif University of Technology Salahshoor, Zahra (Author) ; Borghei, Mehdi (Supervisor) ; Kariminia Hamedani, Hamidreza (Supervisor)
    Abstract
    Removing nitrogen, as one of the most important contaminants of surface and ground water, needs to be considered. Since this material minimizes water quality and makes it useless. On the other hand, many industries as refineries have saline wastewater which their salinity removal is not economical by physical and chemical methods and is often impossible. Although biological treatment of saline wastewater has its problems, biological nitrification and denitrification are efficient and economical methods for nitrogen removal from industries saline wastewater. In this research, moving bed biofilm reactor (MBBR) adopted from Modified LUDZACK – ETTINGER (MLE) method has been used in order to... 

    Coupling Flow and Geochemistry for Numerical Simulation of Low Salinity/Smart Waterflooding in Carbonates

    , M.Sc. Thesis Sharif University of Technology Alipour, Sina (Author) ; Ayatollahi, Shahab (Supervisor) ; Mahani, Hassan (Supervisor)
    Abstract
    Due to the decrease in oil reserves in the world, increasing population and the growing demands for oil consumption in the world, increasing the oil recovery from oil reservoirs has become more important. Increasing the amount of oil production efficiency by using low salinity water/modified salinity water has been highly appreciated during the last two decades. Low-salt water is a new method, due to its advantages such as low cost, simplicity of operation and low environmental hazards. It is believed that low salinity water can alter the rock wettability from a more oil-wetting state to a more water-wetting state. In order to be able to predict the performance of low salinity water... 

    Application of Sulfur Degrading Bacteria in Bioremediation

    , M.Sc. Thesis Sharif University of Technology Ghaffari, Leila (Author) ; Kariminia, Hamid Reza (Supervisor)
    Abstract
    The main objective of this research was to evaluate the application of a new strain of Brevundimonas naejangsanensis which is newly identified sulfate-reducing bacteria (SRB), in bioremediation. A laboratory scale packed bed reactor (PBR) was fabricated and operated to study the new bacteria’s feasibility on SO_4^(2-) reduction. The reactor was packed with polyurethane foam cubes and operated under different feeding and operating conditions of HRT, COD/SO_4^(2-) ratio and salinity. A maximum SO_4^(2-) reduction of 73.6% was achieved in the PBR when operated at an HRT of 12 h with SO_4^(2-) concentration of 670 mg/L, COD/SO_4^(2-) ratio of 1 and salinity of 3%. The results show that this... 

    Experimental Analysis of the Effect of Fluid/Fluid and Fluid/Rock Interactions on the Pore Scale Displacement Mechanisms of Oil by Lswi

    , M.Sc. Thesis Sharif University of Technology Siadatifar, Emad (Author) ; Fatemi, Mobeen (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Visual investigation of the low salinity water injection into micromodel is the goal of this research. Although many researches have been performed to realize the dominating mechanism behind the increased oil recovery after low salinity water injection, many contradictions exist among the studies. Mechanisms are generally divided into two classes. One class is due to fluid/fluid interactions and the other one is due to fluid/rock interactions. A comprehensive set of experiments are conducted in this study to find out the dominating mechanism behind low salinity water injection under the existing conditions of the experiments. Effect of different wettability condition and presence and absence... 

    Experimental Investigation and Modeling of Nonorganic Scale Formation in Porous Media at Microscopic Scale

    , M.Sc. Thesis Sharif University of Technology Mirzaalian Dastjerdi, Ali (Author) ; Ayatollahi, Shahabodin (Supervisor) ; Taghikhani, Vahid (Supervisor)
    Abstract
    Inorganic scale deposition has been found to affect many industrial processes,including water injection into the oil reservoirs. Major formation damage because of incompatibility of high sulfate ion content of seawater with formation water containing calcium ion results in formation damage and production decline.In this study, several simultaneous techniques are utilized for qualitative and quantitative analysis of calcium sulfate scale to get more insight into the damage of formation during smart water flooding at micro and Nano scales. In the experimental section, calcium sulfate deposition due to the mixing of the formation water and seawater samples was investigated using the dynamic... 

    Mechanistically Investigation of Residual Oil Saturation in Heterogeneous Glass Micromodel during Low Salinity Water Injection

    , M.Sc. Thesis Sharif University of Technology Safdari, Mojtaba (Author) ; Ayatollahi, Shahaboddin (Supervisor) ; Masihi, Mohsen (Supervisor)
    Abstract
    Oil and gas reservoirs in various parts of the world have declined over time, despite a high percentage of oil. Due to the increasing need for hydrocarbon resources, the need for more cost-efficient harvesting methods and less environmental damage is felt. Injection of saline water is one of the most cost-effective ways of harvesting due to the need for no expensive additives. On the other hand, microscopic glass modeling can be used to better understand and understand the performance of saline water at the microscopic scale. In this study we have been able to visualize the effective factors in infusion of saline water. Improved interfacial tensile and particle migration in kaolin-coated... 

    Experimental Study of LSW Injection in Fractured Porous Media: Fracture Geometrical Properties at Pore Scale

    , M.Sc. Thesis Sharif University of Technology Mahmoudzadeh Zarandi, Atena (Author) ; Masihi, Mohsen (Supervisor) ; Fatemi, Mobeen (Supervisor)
    Abstract
    Enhancing oil production from fractured reservoirs is challenging. The flow characteristics observed in naturally fractured reservoirs are complicated due to interaction between the two different flow domains: fracture and matrix. Spontaneous imbibition is one of the most important recovery processes in water-wet fractured reservoirs. Oil cannot be spontaneously produced from oil-wet rocks, unless the capillary pressure barrier between fracture conduits and matrix is overcome. The flow characteristics in fractured systems thus relate to the wettability of the rocks. Low salinity water injection has been widely studied as a method of enhancing oil recovery in recent years. However, its impact... 

    Pore-scale Modeling and Simulation of Low Salinity Waterflooding (LSWF) with OpenPNM

    , M.Sc. Thesis Sharif University of Technology Abdollahi, Saeed (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahabodin (Supervisor) ; Sadegh Nejad, Saeid (Co-Supervisor)
    Abstract
    The Low salinity water flooding is one of the important methods of secondary and tertiary oil production in which many expert petroleum-production engineering working on it in recent two decades. There are some basis mechanisms for low salinity method presented in the literatures including fine migrations, alkaline flooding, multicomponent ionic exchange, electrical double-layer expansion and pH-driven wettability alteration. The main approach is generating low salinity mechanism especially wettability alteration in OpenPNM framework. OpenPNM is a python base framework developed by Jeff Gostick for porous media modeling. OpenPNM has paved the way for extracting pore network models (PNM) from... 

    Investigation of Low Salinity Waterflooding Predictive Capability and the Development of a Tool for Screening Candidates

    , M.Sc. Thesis Sharif University of Technology Golmohammadi, Meysam (Author) ; Mahani, Hassan (Supervisor) ; Ayatollahi, Shahab (Supervisor)
    Abstract
    Among different enhanced oil recovery (EOR) methods, low salinity waterflooding (LSWF) has been attractive to researchers because of its relative simplicity and lower environmental problems compared to other conventional EOR methods. Numerous researchers have attempted to find the main cause of the low salinity effect (LSE). According to previous studies, several experimental techniques have been proposed for predicting LSE and screening potential field candidates. However, there is a lack of a systematic investigation of all (or even some of) the methods to compare and determine their LSE predictive capability. Predictive capability development is essential because it saves costs and time... 

    Micromodel Investigation of the Non-Monotonic Effect of Injection Water Salinity on Wettability and Oil Recovery

    , M.Sc. Thesis Sharif University of Technology Karimpour Khamaneh, Mehran (Author) ; Mahani, Hassan (Supervisor)
    Abstract
    Based on numerous laboratory and field evidence, low-salinity waterflooding or engineered salinity waterflooding can lead to enhanced oil production. According to the literature, the mechanisms involved in this process can be divided into two general categories: fluid-fluid interactions and solid-liquid interactions. These mechanisms are caused by intermolecular and electrostatic forces at the rock and fluid interfaces. The most important controlling factor of the electrostatic forces is the concentration of ions at/near fluids-rock interface. Therefore, improving the concentration of ions causes a shift in wettability toward a more water-wetting state, eventually leading to increased oil...