Sharif Digital Repository

The present study is aimed at the synthesis of MnFe2O4@SiO2@PMIDA in terms of highly efficient sensing platform for anti-prostate specific membrane antigen (PSMA) immobilization. Superparamagnetic manganese ferrite nanoparticles were synthesized following co-precipitation method and then SiO2 shell was coated on the magnetic core with tetraethyl orthosilicate (TEOS) through a silanization reaction to prevent oxidation, agglomeration and, increase the density of OH groups on the surface of MnFe2O4. Subsequently, MnFe2O4@SiO2@PMIDA obtained as a result of the reaction between N-(phosphonomethyl)iminodiacetic acid (PMIDA) and MnFe2O4@SiO2. The reactive carboxyl groups on the surface of magnetic... 

The direct growth of self-supported metal-organic frameworks (MOFs) thin film can be considered as an effective strategy for fabrication of the advanced modified electrodes in sensors and biosensor applications. However, most of the fabricated MOFs-based sensors suffer from some drawbacks such as time consuming for synthesis of MOF and electrode making, need of a binder or an additive layer, need of expensive equipment and use of hazardous solvents. Here, a novel free-standing MOFs-based modified electrode was fabricated by the rapid direct growth of MOFs on the surface of the glassy carbon electrode (GCE). In this method, direct growth of MOFs was occurred by the formation of vertically... 

Denim jeans have consistently been fashionable around the world. This fabric inspired strong opinions from historians, teenagers, and movie stars, and has acquired different styles throughout the years. Most jeans today are stonewashed; this technique first become popular in 1970. Now, in addition to pumice stones, enzymes are used on the cotton fabrics to create the stonewashed look. Nowadays, plasma treatment is a cost-effective and environment-friendly process which is able to modify the properties of the fabric surface in order to achieve this effect. Plasma surface treatment changes the properties of the fabric up to a limited depth (several molecular layers), leaving the bulk... 

To investigate the Ta/Co/Cu/Co/NiO/Si(100) spin valve structure, fabrication and characterization of the Cu/Co/NiO/Si(100) system was studied for further understanding the structure. The system was grown by employing combinative DC sputtering-evaporation technique. Nickel oxide with a thickness of about 30 nm was deposited on Si(100) substrate using thermal evaporation technique.The cobalt film, then, with a thickness of about 3 nm was grown by DC sputtering under various applied negative bias voltages ranging from 0 to - 80 V. The optimum bias voltage (Vb = -60 V) for the growth of Co layer was determined by atomic force microscopy (AFM), four-point probe sheet measurement (Rs) and scanning... 

This work studies the influence of surface modification of silica nanoparticles by mercaptopropyl trimethoxysilane on silica weight percent in Ni coating during electrodeposition. Results showed SiO2(CH2)3SH particles were embedded in the Ni coating up to 11%. Also, modified Guglielmi’s model and mechanicsm of nucleation of Ni-SiO2(CH2)3SH composite were studied. © 2017 The Electrochemical Society. All rights reserved  

Background: This research follows some investigations through neural tissue engineering, including fabrication, surface treatment, and evaluation of novel self-stimuli conductive biocompatible and degradable nanocomposite scaffolds. Methods: Gelatin as a biobased material and polyvinylidene fluoride (PVDF) as a mechanical, electrical, and piezoelectric improvement agent were co-electrospun. In addition, polyaniline/graphene (PAG) nanoparticles were synthesized and added to gelatin solutions in different percentages to induce electrical conductivity. After obtaining optimum PAG percentage, cold atmospheric plasma (CAP) treatment was applied over the best samples by different plasma variable... 

A duplex surface treatment on DIN 1.2210 steel has been developed involving nitriding and followed by chromium thermo-reactive deposition (TRD) techniques. The TRD process was performed in molten salt bath at 550, 625 and 700°C for 1-14h. The process formed a thickness up to 9.5μm of chromium carbonitride coatings on a hardened diffusion zone. Characterization of the coatings by means of scanning electron microscopy (SEM) and X-ray diffraction analysis (XRD) indicates that the compact and dense coatings mainly consist of Cr(C,N) and Cr2(C,N) phase. All the growth processes of the chromium carbonitride obtained by TRD technique followed a parabolic kinetics. Activation energy (Q) for the... 

In order to produce a thick near equi-atomic NiTi intermetallic layer on the surface of titanium plate, layers of nickel with thicknesses of 30 μm and 60 μm were electroplated on commercial pure (Cp) titanium and subsequently were heat treated at 850°C and 900°C. The effects of heat treating temperature and the thickness of electroplated nickel on the evolution of the microstructure and mechanical properties were studied. The results confirm the formation of various intermetallic layers in the coatings that substantially affect their hardness. The optimum condition for the formation of a thick NiTi intermetallic layer on the outer surface of the titanium was diffusion treatment of the sample... 

In this study, the in-vitro bone regeneration ability of commercial pure titanium (CP-Ti) surface modified via electrospun polyvinylidene/hydroxyapatite (PVP/HA) masking and subsequent Nd-YAG pulsed laser treatment was investigated. The ratio of HA to PVP played a significant role in achieving a perfect homogenous mask on the CP-Ti. In the laser treatment process, the parameter of area scanning speed (ASS) had an important influence on the final surface morphology. A favorable range was defined for this parameter where these two conditions were satisfied: no PVP remaining and no severe substrate melting. Within a favorable range of ASS, as decreasing ASS exchanged the surface structure from... 

The effects of nitriding, nitrocarburizing and shot peening on fatigue behavior of AISI D3 cold work tool steel were investigated. Five batches of fatigue specimens were manufactured according to the ASTM E466-96 standard. All specimens were quenched and tempered to a hardness of 50 HRC. One group of specimens was shot peened with an Almen intensity of 16 A, one group was nitrocarburized, one group was gas nitrided by single stage and another group was also nitrided by double stages. Rotating-bending fatigue tests were carried out. Our results showed that nitriding and nitrocarburizing treatments did not have a beneficial effect on the fatigue resistance of D3 tool steel. Fatigue test... 

Herein, we show that surface treatment of PEDOT:PSS films using propionic acid (PA) results in better device performance for the resulting CH3NH3PbI3 perovskite solar cells (PCE > 15%). N2 blow spreading of PA appears critical in enhanced performance. This weak acid treatment leads to no worse roughness, while providing larger perovskite grains  

The influences of cupric oxide layer thickness, cuprous oxide particles, and pores on mechanical properties and microstructure of alumina-copper eutectic bond have been investigated. The furnace atmosphere in the first stage was argon gas with 2 × 10-6 atm oxygen partial pressure. In the second stage, the furnace atmosphere was same as the first stage unless that in cooling between 900-1000 °C, the hydrogen gas was purged in furnace atmosphere. Finally, in the last stage a vacuum furnace with 5 × 10 -8 atm pressure was chosen for bonding procedure. Peel strength of first stage specimens shows that cupric oxide layer with 320 ± 25 nm thick generates the maximum peel strength (13.1 ± 0.3... 

The present paper demonstrates the performance of the radiation grafting technique as a chemically based surface pretreatment method to adhesion modification of polyethylene surfaces toward the metallic layer. Gamma irradiation over a dose range of 4-10 kGy is used for grafting of vinyl monomers including acrylamide (AAm) and 1-vinyl-2-pyrrolidone (NVP) onto the surface of three different polyethylenes including low density polyethylene (LDPE) and two kinds of high density polyethylenes, namely HDPE-1 and HDPE-2. The grafting yield is evaluated based on the weight increase of the samples. It is found that the grafting yield is dominated by the crystallinity of the polyethylene, so that lower... 

Shot peening is one of the most effective surface strengthening treatment technologies in which compressive residual stresses are induced beneath the specimen surface. Effects of various factors on the distribution of residual stress profile induced by shot peening have been investigated by many researchers. However, initial residual stresses are one of the important factors which affect the shot peening residual stress.This study is aimed to present comprehensive numerical and experimental study on the effect of initial residual stresses on the shot peened specimen. Initial residual stresses were induced using a four-point bending rig and grinding. Incremental center hole drilling (ICHD)... 

Control charts are the most popular statistical process control tools used to monitor process changes. When a control chart indicates an out-of-control signal it means that the process has changed. However, control chart signals do not indicate the real time of process changes, which is essential for identifying and removing assignable causes and ultimately improving the process. Identifying the real time of the change is known as the change-point estimation problem. Most of the traditional methods of estimating the process change point are developed based on the assumption that the process follows a normal distribution with known parameters, which is seldom true. In this paper, we propose...