Sharif Digital Repository

Hydroxyapatite (HA) is an attractive biomaterial due to its close chemical composition to bone and teeth. However, HA is brittle and has low strength under bearing loads, resulting in limition for orthopedic and dental applications. Two creative approaches have been developed to overcome this problem, using bioactive HA as coatings on metallic implants or as ceramic/metal composites. Carbon nanotubes (CNT) possess excellent mechanical properties to play the role as reinforcement for imparting strength and toughness to brittle hydroxyapatite (HA) bioceramic coating. Moreover, The addition of TiO2 to HA coatings has attracted considerable attention, since TiO2 is capable of increasing the... 

In recent years, semiconductor photocatalysts have attracted much attention because of cleanliness, no secondary pollution and profound oxidation and reduction reactions at room temperature. TiO2 is recognized as the best semiconductor photocatalyst due to its higher photocatalytic activity, nontoxicity, electronic and optical properties, chemical stability and low cost. There are some problems preventing from wide application of titania such as rapid recombination of photogenerated electrons and holes, the lack of visible-light utilization and difficult recovery of photocatalyst. In this study, to overcome these problems, TiO2/MWCNTs nanocomposite was prepared. Carbon nanotubes are... 

In the recent years, nanophotocatalytic process for E. coli inactivation has become considerable choice for water treatment. Having suitable catalytic characterizations, nanophotocatalysis could be considered as an alternative to current E. coli disinfections methods.
In this study, antibacterial effect of Fe-Cd/TiO2 (TiO2 doped with Fe and Cd) under visible light was reported for the first time. The Results show that by comparing Fe-Cd/TiO2 with commercial TiO2 (P25 Degussa), bactericidal efficiency of this codoped photocatalysis under visible light is high and effective. Indeed, Nanoparticle of Fe-Cd/TiO2 disinfects E. coli (cell density: 107 CFU/ml) almost completely within 55 min... 

Growing demand on energy and limitation and consequence of fossil fuels have caused to utilize the clean and renewable energy sources. Hydrogen is a clean energy carrier which produced just water vapor during combustion. Today, methods which are usually used to produce this fuel are based on using fossil fuel compounds. Therefore, utilizing new production methods is unavoidable. One of these methods is using semiconductors such as TiO2 to spilt water and produce H2 by solar irradiation. Reducing the energy gap of these semiconductors to match the solar spectrum, specially in its visible range, modification of their structures, surfaces and stability are the main challenges in hydrogen... 

Antibacterial coatings are a branch of paints and coatings industry that has a wide application from Clothing and Textiles to Floor and Medical instrument. Different antibacterial agents such as silver, titanium dioxide, zinc oxide, gold, chitosan, Silicon dioxide, Magnesium hydroxide and carbon nanotubes have been used. UV curable coatings are economic and environmentally friendly coatings and they are one of the fastest growing segments in the paint and coatings industry. Many studies have been conducted on UV curable coatings and their properties. Among different resins, The UV curable polyurethane offer properties such as: Excellent hardness, High gloss, good chemical and weather... 

The goal of the present study is to analyze the effect of CaF2 and nano-TiO2 as additives on formulation and properties of common dental glass-ceramics. To achieve the goal, a glass system based on SiO2-Al2O3-Li2O-K2O-P2O5-ZnO-ZrO2 was considered to produce glass-ceramic samples and the additives, nano-TiO2 and CaF2, with the 0.5, 1, and 1.5 %Wt was added to the system. After the melting process, the glass samples poured in the water and ferrite was produced. In the next step, the ferrite was milled and pressed. In the heat treatment step, the samples were treated in the temperature range of 650-850°C in order to gain lithium disilicate glass-ceramics. In the last step, the chemical... 

Nowadays, dye-sensitized solar cells (DSSCs) are highly regarded as a cheap alternative for conventional silicon-based solar cells. Improvements of their efficiency and performance sustainability are two major challenges of their commercialization. Engineering of the photoanode electrode by controlling its thickness, chemical composition, and morphology was proposed as effective method in increasing the light conversion efficiency of the cells. In the present study, mesoporous TiO2 beads with different arrangements including pristine mesoporous beads, mixtures of mesoporous beads with nanoparticles, and in the form of two-layer structure of nanoparticles (as an active layer) and mesoporous... 

Today organometallic perovskites are very important in fabrication of solar cells. This materials have advantages like high mobility of charge carriers, changing in range of light aborption with changing in structures atoms, having longer charge carrier diffusion lengths than other materials, high stability and efficiency, Low-cost fabrication process, having capability of studying and processing in low temperatures and having flexibility because of Weak chemical bond in perovskite structure. Due to the low stability and rapid decomposition of this material with the presence of light and moisture, in this study has tried to use PbS quantum dots which is used in sensitive dye solar cells as... 

The purpose of this study is fabrication and characterization of a mesoporous Perovskite solar cell using Barium Titanate as the mesoporous electron transfer layer. In this study, TiO2 nanoparticles and BaTiO3 oxide perovskites were prepared by sol-gel synthesis method and their pastes were applied to the conductive substrate by spin coating method and applied to electron transfer layer in perovskite solar cells. Then Perovskite solar cells were fabricated with different structures from the electron transfer layer.The results of X-ray diffraction analysis showed that pure Barium Titanate and Titanium dioxide nanoparticles were successfully synthesized with tetragonal and cubic crystal... 

This study was performed to synthesize Ag-doped TiO2 nanotubes and investigate the antibacterial property of the nanostructure. In the first step, self-organized TiO2 nanotubes were fabricated through anodizing in an electrolyte containing 0٫3 Wt% NH4F, 0٫2٪V DI water and ethylene glycol. Anodizing was performed in 30 and 60V for 2hrs in order to have different nanotube diameters. In the second step, photoreduction process was done on the way to dope Ag nanoparticles on the nanotubes. Herein, AgNO3 solution concentration, time period of TiO2 nanotubes soaking in the solution, time period of UV irradiation and ethanol solution concentration were taken as factors to achieve Ag nanoparticles in... 

Titanium dioxide (TiO2) is a transparent n-type semiconductor with wide band gap which makes it suitable for applications such as solar cells. TiO2 dye-sensitized solar cells (DSSCs) transform the visible light energy to the electrical energy by excitation of absorbed dye. In the present study, TiO2 nanowires and nanoparticles were synthesized by hydrothermal and sol-gel methods, respectively. The effect of TiO2 morphology on photovoltaic performance of the cells was studied by fabrication of single layer DSSCs containing pure nanowires, pure nanoparticles and mixture of nanowires and nanoparticles with various weight ratios. The results revealed that, DSSC made of 10 wt% nanowires and 90... 

This study investigates the effect of titanium dioxide and magnesium oxide additives on hydroxyapatite synthesized by sol-gel and composite with the predominant phase of hydroxyapatite by in situ method to improve mechanical properties. Scaffold samples were synthesized with nanometer-sized hydroxyapatite and composite powder particles by gel casting and sintered at 1200 ° C. Then, to evaluate the synthesized powders, simultaneous thermal analysis (STA), X-ray diffraction test, FTIR test, FESEM, EDS, and MAP analysis were used. Also, to evaluate the mechanical properties of the scaffolds, a compressive test was used, and to evaluate the scaffolds' density, the Archimedes method was used.... 

In recent decades, desulfurization processes have become essential to decrease environmental pollution due to the emission of sulfur from fuels. In this study, in order to desulfurize liquid fuel, a model fuel (normal heptane) was investigated under visible light ) 350-watt sodium lamp(, using H2O2 as oxidant and methanol as a solvent in the presence of Cu-C-TiO2 nanostructure. C-TiO2 was synthesized by the hydrothermal method. In order to modify and improve the properties, we doped the copper metal by impregnation method with different loading of Cu. Experimental results exhibited the highest activity among samples attributed to 0.5% Cu-C-TiO2 Which caused 98.27% degradation of DBT after 2... 

Due to the increasing consumption of fuel, the use of new methods with high efficiency to remove sulfur from fossil fuels is felt more than ever. Hydrogenation and oxidation of sulfur organic matter, such as thiophenes, is an old method of desulfurization of liquid fuels. Using a photocatalyst, everything can be done in an environment that is very low cost. In this study, the photocatalytic elimination of dibenzothiophene was investigated. For this purpose, carbon-doped thiamine dioxide was used as the photocatalytic base, which is synthesized by hydrothermal method. This method is the same source of titanium and carbon. To increase the performance of the catalyst, platinum metal was loaded... 

The bladder is one of the most important internal organs of human that improper functioning of this organ causes various diseases such as bladder exstrophy, bladder syndrome, bladder cancer and bladder infection. The main challenge in treating these diseases is the presence of a mucous layer consisting of glycosaminoglysis (GAG) in the bladder wall that prevents drugs from reaching the surface of the bladder. Hence, drug delivery through the mucosal layer is not easy, Hence, urease micro/nano carriers have recently been considered for the treatment of bladder diseases. In this study, new janus micromotors based on black titanium oxide with asymmetric urease catalytic coating were synthesized... 

Currently, fossil fuels are the primary source of energy in the world. The increasing human need for energy and the limited resources of fossil fuels and their environmental side effects necessitate the search for other sources of energy. Considering its abundance and eco-compatibility, using solar energy is one of the best candidates for future. One of the methods to use solar energy is to convert and store it as hydrogen fuel by photoelectrochemical cells. In recent years, the main challenge with the production of hydrogen fuel in photoelectrochemical is optimizing them to increase efficiency. For this purpose, various approaches have been proposed such as the fabrication and use of...