Sharif Digital Repository

The effect of the layer in contact with tool (Al or Cu) and the depth of plunge on friction stir butt welding of Al-Cu bilayer laminated composites produced by cold roll welding were studied. The measurement of weld cross sections and variations of the axial load and torque during welding process showed that material flow is influenced by the material which is in contact with the shoulder. Being Al layer in contact with the shoulder led to higher force and torque during welding, and a defect-free weld could be obtained in this manner. By welding from Cu side, a higher plunge depth was needed to develop enough force and torque and thereby a defect-free weld. The amount of material swept by... 

Double oxide films (hereafter: oxides), inclusions and Fe-rich phases are known to be the most detrimental defects in cast Al-Si-Mg alloys. The effects of these defects on reproducibility of tensile properties in Al-7Si-0.35Mg alloy have been investigated in this study. Four different casting conditions (low oxide-low Fe, high oxide-low Fe, low oxide-high Fe and high oxide-high Fe) were studied. In each case, 30 tensile test samples were prepared by casting in a metallic mold and machining (total of 120 tensile test samples). Results of tensile test were analyzed by Weibull three-parameter and mixture analyses. The microstructure and fracture surface of samples were studied by optical and... 

Gas porosities and entrapped double oxide film (hereafter: oxides) are known to be the most detrimental defects in cast Al-Si-Mg alloys. This study investigated the effects of dissolved hydrogen (hereafter: H) and oxides on reproducibility of tensile properties in Al-7Si-0.35 Mg alloys. Also the effects of H and oxides content on the morphology of defects were studied. Four different casting conditions (low oxide-low H, low oxide-high H, high oxide-low H, high oxide-high H) were tested using tensile test bars that were cast in a metallic mold. Results of tensile test that were obtained for each casting condition were analyzed using Weibull two-parameter analysis. Microstructure and fracture... 

Gas porosities and Fe-rich phases and entrapped double oxide films (hereafter: oxides) are known to be the most detrimental defects in cast Al-Si-Mg alloys. The effects of H (gas porosities) and Fe (Β-Al5FeSi phase) on reproducibility of tensile properties in Al-7Si-0.35Mg alloy have been investigated in this study. Four different casting conditions (Low H-Low Fe, Low H-High Fe, High H-Low Fe and High H-High Fe) were studied. In each case, 30 tensile test samples were prepared by casting in a metallic mold and machining (total of 120 tensile test samples). Results of tensile test were analyzed by Weibull three-parameter analyses. The microstructures of samples were studied by optical... 

The effects of melt quality and the placement of a filter in the filling system on Weibull distributions of tensile strength and elongation of Al-7%Si-Mg alloy castings were investigated. Three different combinations of melt quality and filtering were used: (a) unstirred, with filter in the filling system, (b) stirred to produce and entrain surface oxide films with no filter in the filling system to emulate poor initial melt preparation and melt handling, and (c) stirred and with a filter placed in the filling system. The results showed that the highest elongation and tensile strength values were obtained from the unstirred, filtered condition and lowest values were from stirred and... 

An experiment was conducted to determine whether allowing an aluminum melt to solidify in the crucible and later remelting it would improve the quality of the melt and the casting. To investigate this, data were collected through reduced pressure test, density measurement, metallography, X-ray radiography and tensile testing and analyzed statistically. Results indicated that remelting improved the quality of the melt by reduction of the number of defects in the casting and their area and volume fractions. The improvement in elongation of remelted specimens was found to be statistically significant. Analysis of deformation characteristics showed that the improvement in elongation is due to... 

γ-Alumina is used to catalyze the Cannizzaro reaction in the absence of any base under microwave irradiation in high yields. In the case of terephthalaldehyde the reaction is carried out with high selectivity  

Oxide bifilms (double oxide films) are one of the most important defects that influence the mechanical properties of cast aluminum alloys. To investigate the formation of oxide bifilms, castings with different heights of runner were examined. SEM and EDX analysis were used to study the presence of oxide bifilms and fracture surface of tensile test samples. The fracture surface of the tensile test bars that were cast with lower height of runner revealed no oxide bifilm and features of ductile fracture mechanisms. On the other hand, the test bars that were cast with a higher height of runner showed a brittle fracture with areas covered by oxide bifilms. The results of tensile test were... 

Microwave induced Cannizzaro reaction, which was performed in presence of neutral γ-alumina as a polymeric catalyst, was discussed. Cannizzaro reaction was carried out on alumina surface and other unknown products were also obtained. Solvent extraction method was utilized to isolate mild and selective benzyl alcohol and carboxylic acids  

The spectral line based weighted sum of gray gases (SLW) model is considered as an advanced model, which can solve the radiative transfer equation (RTE) in non-gray participating media by dividing the absorption cross section spectrum into a limited number of intervals. Each interval is then treated as a gray gas medium, in which the attributed RTE should be solved separately. Therefore, the SLW model would be computationally more efficient than the other non-gray participating media solvers because it is faced with a small number of RTE solutions. In this work, we present a novel optimized SLW model and applied it to radiation heat transfer calculation in a model furnace. The current... 

Inclusion of nano-clays into hydrogels is an efficient approach to produce nanocomposite hydrogels. The introduction of nano-clay into hydrogels causes an increase in water absorbency. In the present work, Nanocomposite hydro-gels based on kappa-carrageenan were synthesized using sodium montmorillonite as nano-clay. Acrylamide and meth-ylenebisacrylamide were used as monomer and crosslinker, respectively. The structure of nanocomposite hydrogels was investigated by XRD and SEM techniques. Swelling behavior of nanocomposite hydrogels was studied by varying clay and carrageenan contents as well as methylenebisacrylamide concentration. An optimum swelling capacity was achieved at 12% of sodium... 

Standard sparse decomposition (with applications in many different areas including compressive sampling) amounts to finding the minimum ℓ 0-norm solution of an underdetermined system of linear equations. In this decomposition, all atoms are treated 'uniformly' for being included or not in the decomposition. However, one may wish to weigh more or less certain atoms, or, assign higher costs to some other atoms to be included in the decomposition. This can happen for example when there is prior information available on each atom. This motivates generalizing the notion of minimal ℓ 0-norm solution to that of minimal weighted ℓ 0-norm solution. On the other hand, relaxing weighted ℓ 0-norm via... 

An approach to access azaborininones (carbonyl-containing, boron-based heterocyclic scaffolds) using simple reagents and conditions from both organotrifluoroborates and boronic acids is described. An inexpensive, common reagent, SiO2, was found to serve as both a fluorophile and desiccant to facilitate the annulation process across three different azaborininone platforms. Computational analysis of some of the cores synthesized in this study was undertaken to compare the azaborininones with the analogous carbon-based heterocyclic systems. Computationally derived pKa values, NICS aromaticity calculations, and electrostatic potential surfaces revealed a unique isoelectronic/isostructural... 

The mechanical responses of biological tissues are well characterized by hyperelastic or viscoelastic models within the physiological loading range. However, during supra-physiological mechanical loading, as occurs during interventional procedures such as balloon angioplasty and arterial clamping, damage may occur in the tissue. The continuum and computational treatments of damage in soft biological tissues have attracted considerable attention over the recent years. In this chapter, we review the state of the art of this challenging area. We summarize and critically discuss various damage models, which are based on continuum damage mechanics, the theory of pseudo-elasticity, and the... 

α-Arylalkynols were converted into conjugated enynes (in a selective manner under solvent-free conditions) using the LiCl-acidic Al2O3 couple as catalyst and support  

For a given sequence of nonincreasing numbers, d = (d1, . . ., dn a necessary and sufficient condition is presented to characterize d when its realization is a unique labelled simple graph. If G is a graph, we consider the subgraph G′ of G with maximum edges which is uniquely determined with respect to its degree sequence. We call the set of E(G)/E(G′) the smallest edge defining set of G. This definition coincides with the similar one in design theory  

7H-benzimidazo[2,1-a]benz[de]isoquinolin-7-one compounds were prepared in a selective manner by reaction between o-phenylenediamines and appropriate 1,8-naphthalenedicarboxylic anhydrides using acidic alumina under microwave irradiation  

This study describes an efficient method for ortho-selective halogenation of N-arylcarbamates under mild conditions for the first time. Although being weakly coordinating, N-arylcarbamates act very well as a removable directing group for activation of C-H bonds. The developed procedure results in extremely valuable halogenated N-arylcarbmates that can further be hydrolyzed to halogenated anilines. The obtained reaction conditions showed broad scope and wide functional group tolerance. All the products were formed in good yields with extremely high selectivity  

Stay and guide vanes (distributor) are essential parts of a turbine. They are used to control the flow rate and to appropriately transfer the flow momentum to the runner. In this work, flow through the distributor is analyzed. For various Boundary Conditions (BC) and different configurations, threedimensional flows in the distributor of a Francis turbine are evaluated and compared with each other. The numerical simulations were carried out using Fluent software and the results were validated with a GAMM Francis turbine, where the geometry and detailed best efficiency measurements were publically available. In these simulations, the flow was assumed to be steady and the effect of turbulence...