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The Removal of CO2 from Flue Gas by Using MOF/Graphene Hybrid Adsorbents
, M.Sc. Thesis Sharif University of Technology ; Kazemeini, Mohammad (Supervisor) ; Ganji, Ensieh (Supervisor) ; Bozorgzadeh, Hamid Reza ($item.subfieldsMap.e)
Abstract
Due to the increase in greenhouse gases in earth’s atmosphere in recent years and its devastating environmental outcomes, there has been an increase in research trying to reduce these gases especially CO2. Flue gas is one of the most important sources of CO2 emission. Among the many techniques of removal, capturing and CO2 separation from flue gas, physical adsorption by a solid adsorbent is considered as a suitable and economic option. Among the solid adsorbent that are used for adsorption of CO2, Metal-Organic frameworks have many interesting features such as high specific surface area and high internal free volume. Among the Metal-Organic frameworks, MIL-53 (Al) and MIL-101 (Cr) are two...
Performance Evaluation and Investigation of Nano-Ceramic Membrane in order to Purification of Hydrogen in Laboratory Scale
, M.Sc. Thesis Sharif University of Technology ; Sayf Kordi, Ali Akbar (Supervisor) ; Zamanian, Akbar (Supervisor) ; Ganji Babakhani, Ensieh (Co-Advisor)
Abstract
Purification of hydrogen, as a clean source of energy has attracted great deal of attention in recent years. Among all available H2 separation methods, membrane technology has been known as the most appropriate way to produce hydrogen with high purity. In this study, we have tried to synthesis and evaluate the performance of perovskite ceramic membranes. The aim of preparing this type of membranes is to use them in separation processes in order to achieve H2 with high purity of >99%. First, general concepts about membranes are discussed. Then synthesis, recognition and performance evaluation of some perovskite membranes are presented. To prepare membranes, ceramic powders are synthesized by...
Formal Verification of Timed Security Protocols
, M.Sc. Thesis Sharif University of Technology ; Izadi, Mohammad (Supervisor)
Abstract
Security protocols assure the security of the communications in computer systems using techniques such as cryptographic primitives. However, the usage of such protocols is faced by the lack of fault tolerance, where a minor disruption could cause a destructive damage. Therefore, there is a requirement to assess the reliability of these protocols. In this thesis model checking of timed security protocols is done. Model checking process includes steps that will be modeling protocol with high level and human readable specification language named THLPSL and converting this specification to special kind of timed automata named XTA and model checking will be done with UPPAAL verification tool. We...
The Analysis of Cracked Atomic Force Microscope Micro-Cantilever by Strain Gradient Theory
, M.Sc. Thesis Sharif University of Technology ; Asghari, Mohsen (Supervisor)
Abstract
The present study deals with the analysis of Atomic Microscope with crack by making use of Strain Gradient Elasticity theory. Empirical observations represent that in micro dimensions, materials show behaviors, which the classic continuum mechanics theories are not able to explain. Thus, taking advantage of non-classic theories, which are capable of explaining such phenomena or behaviors in analyzing materials in micro dimensions seems necessary and of much significance. In this direction, by applying an Euler-Bernoulli beam assumption and neglecting the shear effects, governing equations and boundary conditions of the problem were obtained via taking advantage of variations in Hamilton...
Automated Generation of Commit Messages in Code Repositories
, M.Sc. Thesis Sharif University of Technology ; Heydarnoori, Abbas (Supervisor)
Abstract
Software requirements are changing continuously and hence during software evolution and maintenance, source codes changes are being committed in the software repositories. Reading source codes to understand the changes is a very time consuming and tedious activity. Commit messages contain information about code changes that let developers be aware of the essence of the changes without reading the source codes. Unfortunately, due to the pressure of deadlines and lack of time, developers neglect to write these messages. Commit messages can speed up the process of software understanding for developers and also play an important role in software documentation. Therefore, an automated method for...
The effects of reaction conditions on block copolymerization of chitosan and poly(ethylene glycol)
, Article Carbohydrate Polymers ; Volume 81, Issue 4 , July , 2010 , Pages 799-804 ; 01448617 (ISSN) ; Abdekhodaie, M. J ; Sharif University of Technology
2010
Abstract
A novel injectable in situ gelling thermosensitive chitosan-block-poly(ethylene glycol) formulation was synthesized for drug delivery applications. Block copolymerization of monomethoxy-poly(ethylene glycol) onto chitosan using potassium persulfate as an initiator was carried under a nitrogen atmosphere in aqueous solution. The effects of potassium persulfate and poly(ethylene glycol) concentrations, reaction time and reaction temperature on block polymerization were studied by determining the yield of reaction (%Y), polymerization efficiency (%E) and add-on percentage (%Add-on). Keeping the other conditions constant, the optimum reaction conditions were found to be initiator = 0.01 M,...
Chitosan-g-PLGA copolymer as a thermosensitive membrane
, Article Carbohydrate Polymers ; Volume 80, Issue 3 , 2010 , Pages 740-746 ; 01448617 (ISSN) ; Abdekhodaie, M. J ; Sharif University of Technology
2010
Abstract
A thermosensitive copolymer was synthesized by graft copolymerization of poly(lactide-co-glycolide) (PLGA) copolymers onto the surface of chitosan membranes. Acryloyl chloride was used as a coupling reagent for the covalent attachment of PLGA to the chitosan membranes. FTIR spectroscopy and DSC analysis were used to characterize the resulting graft copolymer. Thermosensitive swelling behaviors of the copolymer were investigated as well. The membranes exhibited reversible swelling-shrinking behavior; higher swelling ratios were obtained observed at higher temperatures. Drug permeation studies were carried out using vancomycin hydrochloride and betamethasone sodium phosphate as the model...
Synthesis and characterization of a new thermosensitive chitosan-PEG diblock copolymer
, Article Carbohydrate Polymers ; Volume 74, Issue 3 , 2008 , Pages 435-441 ; 01448617 (ISSN) ; Abdekhodaie, M. J ; Sharif University of Technology
2008
Abstract
A novel thermosensitive hydrogel was synthesized by block copolymerization of monomethoxy poly(ethylene glycol) macromere (PEG) onto chitosan backbone, using potassium per sulfate as a free radical initiator. This block copolymer exhibits a thermoreversible transition from an injectable solution at low temperature to a gel at body temperature. Synthesized copolymers were characterized using FT-IR, 1H NMR, 13C NMR, and DSC techniques. Solubility test was performed to compare water and organo-solubility of chitosan before and after copolymerization. Sol-gel transition behavior was investigated using the vial inversion method and viscosity measurements. The gelation behavior makes the...
Developing an Audit System Algorithm for Quality Management System of Flexible Pavement Construction
, M.Sc. Thesis Sharif University of Technology ; Tabatabaei, Nader (Supervisor)
Abstract
Early failure of pavement is one of the most important problems. As the research conclusions in Iran, Non-conformancity is the most important cause of this problem.Quality management system, Audits and expert systems are the solutions. This research provides an Audit system for quality management system of batch-type asphalt plants as the preliminary solution.A state survey conducted and useful part of state programs had been considered. After developing software, The system functionality has been tested
SRAM Cell Design for Low Power Applications
, M.Sc. Thesis Sharif University of Technology ; Haj Sadeghi, Khosrow (Supervisor)
Abstract
From the cache of the personal computers to the main memory unit of SOCs, medical and wearable chips, Static Random Access Memory (SRAM) is widely utilizes. Preferable performance for SRAM varies with regard to the operating field. For instance, high speed access and performance is emphasized in the design of the cache for PCs. In contrast, power consumption and the area of the memory are the key design considerations for SOCs. Hence, the field in which SRAM is used, should be thoroughly studied. SOCs and medical chips suffer limitations in design due to using batteries as the source of energy and SRAMs consume a significant part of total power and occupy a large area on these chips. One of...
A Service Matching Model in Cloud Manufacturing Systems Considering the Extended Relationship Among Supply Demand Services Focusing on Metaheuristic Algorithms
, M.Sc. Thesis Sharif University of Technology ; Fatahi Valilai, Omid (Supervisor)
Abstract
In recent years, economy globalization has led to a major focus on the needs of customers, Moreover globalization has resulted in geographically distributed suppliers across the globe. In such a space, using cloud manufacturing as one of the novel technologies in manufacturing that deals with resource management has been more and more taken into consideration. one of the most important issues in cloud manufacturing is service composition, in which, after receiving customer’s demand, a combination of cloud services is provided to meet customer’s demand. In fact, the customer's need is decomposed in different tasks, each of which is carried out by one (or more) manufacturing plant. the purpose...
Inventory-Pricing Models with Multiple Interdependent Products and Demand Uncertainty
, M.Sc. Thesis Sharif University of Technology ; Shavandi, Hassan (Supervisor)
Abstract
In this research, a pricing-inventory model with multiple interdependent products and stochastic demand is studied. In the relevant literature, there are many researches that are related to optimize the inventory or price independently and also optimizing joint inventory and pricing for single product. But joint optimization of inventory and pricing for multiple interdependent products is relatively new and still there are many potential research gaps in this area. We develop the model with additive and multiplicative demand uncertainty. Then we develop a genetic algorithm and tune its parameters to solve the models. We investigate the efficiency of proposed GA. Results were relatively good....
An architecture for a context-aware service broker in ubiquitous computing environments
, Article IEEE International Conference on Computer Systems and Applications, 2006, Sharjah, 8 March 2006 through 8 March 2006 ; Volume 2006 , 2006 , Pages 1097-1100 ; 1424402123 (ISBN); 9781424402120 (ISBN) ; Abolhassani, H ; Jalili, R ; Sharif University of Technology
IEEE Computer Society
2006
Abstract
In ubiquitous computing environments, many devices and agents interoperate with each other and use services provided by others. But the problem is that there may be requests that can not be fulfilled by available services. A solution to this problem is to use service brokers that compose existing services and create new value added services that can fulfill the clients' requests. In this paper, we present an architecture for a context-aware service broker that not only is able to compose services for responding to new requests, but also considers the context of its clients for providing customized and personalized outputs and behaviors. © 2006 IEEE
Prediction of erosive wear locations in centrifugal compressor using CFD simulation and comparison with experimental model
, Article Journal of the Brazilian Society of Mechanical Sciences and Engineering ; Volume 41, Issue 2 , 2019 ; 16785878 (ISSN) ; MomeniLarimi, M ; Ganji, B ; Ranjbar, A ; Sharif University of Technology
Springer Verlag
2019
Abstract
Erosive wear is one of the efficiency reduction causes in centrifugal compressors. The presence of suspended solid particles in the fluid causes deformations in different parts of the compressor, especially blades of the impeller. Therefore, erosion not only decreases the part lifetime by destruction of blades form, but also increases energy losses. For this reason, specifying the erosion locations and choosing a suitable material have an important effect on optimum functionality of the machine. In this paper, erosion locations of a compressor impeller by using computational fluid dynamics (CFD) in high temperature and pressure are attained and compared with experimental model. The...
Design of nanoswitch based on C20-bowl molecules: a first principles study
, Article Microelectronics Journal ; Volume 39, Issue 12 , 2008 , Pages 1499-1503 ; 00262692 (ISSN) ; Aghaei, H ; Gholami, M. R ; Sharif University of Technology
2008
Abstract
We demonstrate theoretically by density functional non-equilibrium Green's function method that a much simplest two-terminal wire can exhibit switching, and we present a realistic theory of its behavior. We consider a C20-bowl molecular wire sandwiched between an Au (1 0 0) substrate and a monatomic Au scanning tunneling microscope (STM) tip. Lateral motion of the tip over the pentagon ring causes it to change from one conformation class to the other and to switch between a strongly and a weakly conducting state. Thus, surprisingly, despite their apparent simplicity, these Au/C20/Au nanowires are shown to be a convenient switch, the simplest two-terminal molecular switches to date....
Theoretical study of the electron transport through the cysteine amino acid nanomolecular wire
, Article International Journal of Nanoscience ; Volume 7, Issue 2-3 , 2008 , Pages 95-102 ; 0219581X (ISSN) ; Aghaie, H ; Gholami, M. R ; Sharif University of Technology
World Scientific Publishing Co. Pte Ltd
2008
Abstract
In this paper, we study the electrical transport and Negative Differential Resistance (NDR) in a single molecular conductor consisting of a cysteine sandwiched between two Au(111) electrodes via the Density Functional Theory-based Nonequilibrium Green's Function (DFT-NEGF) method. We show that (surprisingly, despite their apparent simplicity, these Au/cysteine/Au nanowires are shown to be a convenient NDR device) the smallest two-terminal molecular wire can exhibit NDR behavior to date. Experiments with a conventional or novel self-assembled monolayer (SAM) are proposed to test these predictions. The projected density of states (PDOSs) and transmission coefficients T(E) under various...
4-tert-butyl pyridine additive for moisture-resistant wide bandgap perovskite solar cells
, Article Optical Materials ; Volume 123 , 2022 ; 09253467 (ISSN) ; Azizollah Ganji, B ; Taghavinia, N ; Sharif University of Technology
Elsevier B.V
2022
Abstract
Perovskite solar cells fabrication process need inert or low humidity atmospheres. While highly efficient perovskite solar cells to overcome the photovoltaic marketing should be achieved stability at any environmental conditions. At high humidity, water molecules react with the perovskite layer and increase the degradation rate, leading to a drastic decrease in device performance and perovskite crystallinity. In this work, the effect of environmental humidity on photophysical parameters of wide bandgap, (WBG) perovskite layer and solar cells stability is systematically investigated and tBP is proposed as an additive in perovskite precursor to increase the moisture resistance and improve the...
Exploitation of Construction Modeling (BIM)and Virtual Reality (VR)in Dam Infrastructure Monitoring and Maintenance
, M.Sc. Thesis Sharif University of Technology ; Alvanchi, Amin (Supervisor)
Abstract
Dams are one of the vital infrastructures of the country and their correct use can have a significant impact on reducing costs and increasing their productivity. Due to the fact that dams are mainly large structures with a large number of components and with many complications of operation and maintenance, their operation and maintenance require spending a lot of money. On the other hand, the depth and volume of water behind the dams and the entanglement of the connection between the dams and the surrounding environment make the operation and maintenance of dams face many risks. The use of new technologies that can reduce the costs and risks of operating and maintaining dams can greatly help...
Removal of the CO2 from flue gas utilizing hybrid composite adsorbent MIL-53(Al)/GNP metal-organic framework
,
Article
Microporous and Mesoporous Materials
;
Volume 218
,
2015
,
Pages 144-152
;
13871811 (ISSN)
; Kazemeini, M
; Ganji Babakhani, E
; Taheri, A
;
Sharif University of Technology
Elsevier
2015
Abstract
Abstract In this study, adsorption of the CO2 and N2 gases on the MIL-53(Al) and its hybrid composite with the graphene nano-plates (GNP), MIL-53(Al)/GNP, adsorbents were investigated. These materials were synthesized using the solvothermal reaction method. The prepared samples were characterized by means of the powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FESEM), N2 adsorption-desorption isotherms (BET-BJH surface area measurement) and Fourier transfer infrared (FT-IR) spectroscopy methods as well as; thermogravimetric analysis (TGA). Adsorption equilibrium of the CO2 and N2 on the sorbents were...
Hydrogen separation through LSF-perovskite membrane prepared by chelating method
, Article Journal of Natural Gas Science and Engineering ; Volume 22 , January , 2015 , Pages 483-488 ; 18755100 (ISSN) ; Ghasemi, F ; Ganji Babakhani, E ; Taheri, Z ; Sharif University of Technology
Elsevier
2015
Abstract
La0.3Sr0.7FeO3-δ (LSF) perovskite was prepared according to two methods: (1) applying new phenolic derivative of serine amino acid (L) as chelating agent, and (2) in absence of L as ligand-free perovskite (LFP). The newly prepared aminophenolic ligand L was fully characterized by 1H and 13C NMR, IR as well as elemental analysis while the LSF perovskite samples were characterized using the IR spectra, powder x-ray diffraction (PXRD) patterns, and SEM micrographs. The PXRD pattern obtained for the perovskite prepared by L (PPP) indicated on the presence of pure perovskite phase. The hydrogen permeation through PPP and LFP membranes with thickness of 1.0mm were measured as a function of...