Sharif Digital Repository

A molybdenum complex, [MoO2Cl2(DMSO)2], was immobilized on amino propyl and Schiff base modified magnetic Fe3O4@SiO2 nanoparticles by covalent linkage. The resulting nanoparticles were used as efficient and recyclable catalysts for the selective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as the oxidant. The complete characterization of catalysts was carried out by means of thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), X-ray photoelectron spectroscopy (XPS), elemental analysis, FT-IR and Raman microprobe... 

A molybdenum complex was immobilized on Schiff-base-modified magnetic and non-magnetic particles by covalent linkage. The characterizations of the obtained materials were carried out by means of TG–DTG, SEM, TEM, VSM, XPS, IR, and Raman microprobe techniques. All of them exhibited efficient activities in the oxidation of sulfides to sulfoxides by urea hydrogen peroxide oxidant. The advantages and disadvantages of these catalysts are discussed in detail. Molybdenum complex immobilized on silica bead can be recycled and recovered by simple filtration, but it demonstrated low activity in catalytic oxidation reaction. Immobilization on nano-SiO 2 leads to the formation of nanocatalyst having... 

The glucose-based ligand, N-salicylidene-d-glucosamine (Sal-d-glsmN), was readily obtained by reaction of salicylaldehyde (Hsal) with the d-glucosamine hydrochloride. Ligand Sal-d-glsmN was found to be an efficient ligand in the palladium-catalyzed Suzuki and Heck C-C coupling reactions in aqueous medium under aerobic condition. It was found that the use of Sal-d-glsmN/Pd(OAc) 2 system as a catalyst, aryl halides undergo Suzuki and Heck cross-couplings, respectively, with arylboronic acids and olefins to give the desired products in moderate to excellent yields  

Mass-transfer rates to and from drops in liquid-liquid extraction processes are often reduced by the presence of contaminants. To design an industrial extractor, it is essential to consider this contamination effect in a quantitative manner. To achieve this goal, an experimental investigation was conducted on the mass transfer into single drops for n-butanol-succinic acid-water, as the recommended test system by the European Federation of Chemical Engineering (EFCE). The effects of anionic (sodium dodecyl sulfate, SDS), cationic (dodecyl trimethyl ammonium chloride, DTMAC), and nonionic (octylphenol decaethylene glycol ether, Triton X-100) surfactants on the hydrodynamic and mass-transfer... 

Mass transfer rates to the drops in liquid-liquid extraction equipment are often likely to be reduced by the presence of surface active contaminants. This reduction in mass transfer is said to be due to a reduction in terminal velocity, and to changes in pattern of internal circulation. A single-drop extraction apparatus was used to investigate the dependency of mass transfer coefficient on the amount of surfactant added in a system of n-butanol/succinic acid/water. Three types of surfactants, SDS, DTMAC and Triton X-100, were used to study their effects on the inhibition of mass transfer in liquid-liquid extraction. The effect of surfactants concentration on extraction percentage, overall... 

In this work, an optimum frequency is found for the operation of single cavity photonic switches. At this optimum point, the transmission contrast of ON and OFF states takes its highest value, while keeping the device power threshold relatively low and the device speed acceptably high. Then, the dynamic behavior of a typical single cavity all optical switch is investigated in the optimum operation point through temporal Coupled Mode Theory. Switching speed and power are discussed, and the device is shown to be applicable for telecommunication and data processing applications. The analysis is quite general, and can be used for resonant structures, such as photonic crystals and microring... 

The emergence of new memory technologies provides us with opportunity to enhance the properties of existing memory architectures. One such technology is Phase Change Memory (PCM) which boasts superior scalability, power savings, non-volatility, and a performance competitive to Dynamic Random Access Memory (DRAM). In this paper, we propose a write buffer architecture for Solid-State Drives (SSDs) which attempts to exploit PCM as a DRAM alternative while alleviating its issues such as long write latency, high write energy, and finite endurance. To this end and based on thorough I/O characterization of desktop and enterprise applications, we propose a hybrid DRAM-PCM SSD cache design with an... 

Background & objectives: Malaria is the most important mosquito-borne disease in Iran. It is endemic in south to southeastern part of the country. Knowledge about bio-ecology of vectors will support authorities for appropriate management of the disease. Bashagard district is one of the main endemic areas for malaria in south of Iran. This study was conducted to determine anopheline fauna, diversity and affinity in the area, characterization of larval habitats, and mapping their potential distribution across the district. Methods: The potential aquatic habitats for Anopheles larvae were extracted from Indian Remote Sensing Satellite (IRS) image and digital elevation model of the area using... 

Two enantiomerically pure chiral dioxidomolybdenum(VI) complexes (1 and 2) of the type [MoO2L] (L = dianionic, tetradentate ONNO-ligand) were synthesized and investigated in enantioselective oxidation reactions. The solid-state structures of complex 1 and 2, determined via single-crystal X-ray diffraction analysis revealed two fundamentally different coordination geometries: a C1-symmetric cis-β isomer (Λ-1), and a C2-symmetric cis-α isomer (Δ-2). In both cases, only one of the two possible helical enantiomers (Λ- or Δ-helix) was formed. The complexes were examined as precatalysts in the epoxidation of the challenging prochiral substrate trans-stilbene, using either tert-butyl hydroperoxide... 

Bashagard district is one of the important malaria endemic areas in southern Iran. From this region a total of 16,199 indigenous cases have been reported in recent years. The aim of this study was to determine the situation of the disease and provide the risk map for the area. ArcGIS9.2 was used for mapping spatial distribution of malaria incidence. Hot spots were obtained using evidence-based weighting method for transmission risk. Environmental factors including temperature, relative humidity, altitude, slope and distance to rivers were combined by weighted multi criteria evaluation for mapping malaria hazard area at the district level. Similarly, risk map was developed by overlaying... 

In this paper, we enhance previously suggested vulnerability estimation techniques by presenting a detailed modeling technique based on Input-to-Output Masking (IOM). Moreover we use our model to compute the System-level Vulnerability Factor (SVF) for data-path components in a highperformance processor. As we show, recent suggested estimation techniques overlook the issue of error masking, mainly focusing on time periods in which an error could potentially propagate in the system. In this work we show that this is incomplete as it ignores the masking impact. Our results show that including the IOM factor can significantly affect the system-level vulnerability for data-path components. As a... 

Over the past few years, radiation-induced transient errors, also referred to as soft errors, have been a severe threat to the data integrity of high-end and mainstream processors. Recent studies show that cache memories are among the most vulnerable components to soft errors within high-performance processors. Accurate modeling of the Vulnerability Factor (VF) is an essential step towards developing cost-effective protection techniques for cache memory. Although Fault Injection (FI) techniques can provide relatively accurate VF estimations they are often very time consuming. To overcome the limitation, recent analytical models were proposed to compute the cache VF in a timely fashion. In... 

This paper presents a low cost fault-tolerant technique so called OWHR (Operand Width Aware Hardware Reuse) to ALU design in embedded processors. The OWHR technique is motivated by two facts: (1) Many of the produced and consumed values are narrow-width values in the embedded processors, i.e. they have leading zeros or ones in their most significant bits. This indicates that only a fraction of the circuit is performing useful operations when a particular arithmetic or logic circuit in the ALU is operating on narrow-width values; (2) other circuits of the ALU are not used, when a particular arithmetic or logic circuit is being utilized to perform a specific operation in the ALU in the... 

Effect of relaxation time on the performance of photonic crystal optical bistable switches based on Kerr nolinearity is discussed. This paper deals with optical pulses with the duration of about 50 ps. In such cases the steady state response of the optical device can be used to approximate the pulse evolution if the nonlinearity is assumed instantaneous, hence analytical solutions such as the coupled mode theory can be used to obtain the time evolution of the electromagnetic fields. However if the relaxation time of the material nonlinear response is also considered, changes in the power levels and in the shape of the hystersis loop is observed. In this case, we use the nonlinear finite... 

Using multiple antennas at the transmit and receive sides of a passive radar brings both the benefits of MIMO radar and passive radar. However one of the obstacles arisen in such configuration is the receive antennas placement in proper positions so that the radar performance is improved. Here we just consider the case of positioning one receiver among multiple illuminators of opportunity. Indeed it is a start for the solution of optimizing the geometry of the multiple receivers in a passive radar  

SbCl3 supported on montmorillonite K-10 is an efficient catalyst for the ring opening of epoxides with aromatic amines under solvent-free conditions and microwave irradiation to give the corresponding b-amino alcohols in high yields with high regioselectivity  

One of the important obstacles in MIMO (Multiple Input Multiple Output) radars is the issue of designing proper transmit signals. Indeed, the capability of signal design is a significant advantage in MIMO radars, through which, the system can achieve much better performance. Many different aspects of this performance improvement have been considered yet, and the transmit signals have been designed to attain such goal, e.g., getting higher SNR or better detector's performance at the receiver. However, an important tool for evaluating the radar's performance is its ambiguity function. In this paper, we consider the problem of transmit signal design, in order to optimize the ambiguity function...