Sharif Digital Repository

Alterations in the structure of a magnetron, e.g., the A6 relativistic magnetron, are proposed, which considerably increase the device's build-up speed. We cover the magnetron vane surfaces with semiconductor layers of nonzero electric conductivity, with an exact geometrical design. Semiconductor layers with considerable mechanical strength also provide excellent shielding for the vanes against the high-energy relativistic electrons' bombardment. The novel structure introduces several new free parameters to the magnetron design procedure and considerably increases the design flexibility. A multistage exact optimization procedure, performed by extensive computer simulations, shows that... 

The preparation of microcapsules containing perphenazine by solvent evaporation using ethyl cellulose is described. The microparticles are formed after solvent evaporation and polymer precipitation. The drug was dissolved in a polymer solution and emulsified into an aqueous phase to form microcapsules. To study the effects on particle size, encapsulation efficiency and morphology, three different molecular weights of ethyl cellulose (Mw=47000, 71000 and 99000) were used. Covalent bonding of drugs to polymers via hydrolytically or enzymatically cleavable covalent bond was achieved for sustained drug delivery. The release rate of perphenazine from these systems was investigated  

In this article, the problem of combined forced and free convection in vertical porous and regular channels for both regular fluids and nanofluids has been solved using the CFD technique in the entrance regions of momentum and heat transfer taking into account the influences of viscous heating and inertial force. In this regard, various types of viscous dissipation models reported in the literature such as the Darcy model, the power of the drag force model, and the clear fluid-compatible model were applied. In the case of nanofluid flow, both the Brownian and thermophoresis molecular transfer mechanisms were considered. The dimensionless distributions of velocity, temperature, and the volume... 

Zinc-rich ethyl silicate coatings are quite successful in protecting steel against corrosion under severe exposing conditions. In spite of providing excellent cathodic protection to steel structure after film curing, two-component zinc-rich ethyl silicate coatings have some limitations, one of which is inadequate shelf life as a result of in-can binder gelation. In this work, the preparation steps of ethyl silicate such as pre-hydrolysis, dehydration and organometallic reactions were surveyed and herein an approach towards understanding the cause and effect relationship of the use of ingredients is presented. The effects of water and catalytic acid dosages on gel time under accelerated... 

In this research, cold compaction behavior and pressureless sinterability of WC, WC-10%wtCu and WC-30%wtCu powders were investigated. WC and WC/Cu powders were milled in a planetary ball mill for 20h. The milled powders were cold compacted at 100, 200, 300 and 400 MPa pressures. The compressibility behavior of the powders was evaluated using the Heckel, Panelli-Ambrosio and Ge models. The results showed that the PanelliAmbrosio was the preferred equation for description the cold compaction behavior of the milled WC and WC-30%wtCu powders. Also, the most accurate model for describing the compressibility of WC-10%wtCu powders was the Heckel equation. The cold compacts were sintered at 1400oC.... 

In this article, a new method for solving multidimensional population balance (PB) equations for agglomeration is presented. First, discretized 2-dimensional PB (DPB) is derived and by applying probability approach, this method is extended to n-dimensional PB. The discretization of size intervals is in the form of v(j) = 2j-i v(i) and the volume based PB is used. Because of conservative nature of volume, all internal coordinates are converted to some independent volumes. A simple and clear procedure for solving multidimensional PB is proposed using probability concept. In addition, various types of birth and death mechanisms involved in PB are analyzed separately. Moreover, results of... 

Changing the wettability of reservoir rock towards strongly water-wet state is effective way to enhance oil recovery from fractured carbonate reservoirs which are typically oil-wet. Regarding this fact, the injection of surfactant and the bacterial solution as EOR agents is proposed in the current work as a potential method to alter the wettability of rock surface reservoir. Nevertheless, there is a definite lack of experimental data regarding this method and the synergistic effect of both chemical and bacterial solutions on this process. In this study, the sole and combined effects of the bacterial solution using an Enterobacter cloacae strain as a biosurfactant-producer are compared with... 

Microbial enhanced oil recovery (MEOR) refers to the process of using bacterial activities for more oil recovery from oil reservoirs mainly by interfacial tension reduction and wettability alteration mechanisms. Investigating the impact of these two mechanisms on enhanced oil recovery during MEOR process is the main objective of this work. Different analytical methods such as oil spreading and surface activity measurements were utilized to screen the biosurfactant-producing bacteria isolated from the brine of a specific oil reservoir located in the southwest of Iran. The isolates identified by 16S rDNA and biochemical analysis as Enterobacter cloacae (Persian Type Culture Collection (PTCC)... 

Thiomorpholine 1,1-dioxides were prepared with double Michael addition reaction of aromatic amines to divinyl sulfone catalyzed by boric acid/glycerol in water. This catalyst system was also used for the Michael addition reaction of aromatic amines to electron-deficient alkenes. The reaction is simple and green and gives good to excellent yields  

In this study, the effect of through-thickness shear (TTS) stress has been examined on the prediction of forming limit diagrams (FLDs). Determination of the FLD is based on the Marciniak–Kuczynski (M–K) model with some modifications on the stress states for consideration of the TTS stress effects. For solving the equations, the Newton–Raphson method has been used. Furthermore, the Nakazima test has been simulated to investigate the stress state which occurs in the sheet during the test. Results showed that the formability of sheet metal could be better as the through-thickness stress increased. Also, implementation of TTS stress in the present model, the corresponding FLD has better... 

In this study, the effect of through-thickness shear (TTS) stress has been examined on the prediction of forming limit diagrams (FLDs). Determination of the FLD is based on the Marciniak–Kuczynski (M–K) model with some modifications on the stress states for consideration of the TTS stress effects. For solving the equations, the Newton–Raphson method has been used. Furthermore, the Nakazima test has been simulated to investigate the stress state which occurs in the sheet during the test. Results showed that the formability of sheet metal could be better as the through-thickness stress increased. Also, implementation of TTS stress in the present model, the corresponding FLD has better... 

In this study, the effect of through-thickness shear (TTS) stress has been examined on the prediction of forming limit diagrams (FLDs). Determination of the FLD is based on the Marciniak–Kuczynski (M–K) model with some modifications on the stress states for consideration of the TTS stress effects. For solving the equations, the Newton–Raphson method has been used. Furthermore, the Nakazima test has been simulated to investigate the stress state which occurs in the sheet during the test. Results showed that the formability of sheet metal could be better as the through-thickness stress increased. Also, implementation of TTS stress in the present model, the corresponding FLD has better... 

Nanodiamond (ND)is an allotrope of carbon nanomaterials which exhibits many outstanding physical, mechanical, thermal, optical and biocompatibility characteristics. Meanwhile, ND particles possess unique spherical shape containing diamond-like structure at the core with graphitic carbon outer shell which intuitively contains many oxygen-containing functional groups at the outer surface. Such superior properties and unique structural morphology of NDs are essentially attractive to develop polymer composites with multifunctional properties. However, despite a long history from the discovery of NDs, which is dated back to the1960s, this nanoparticle has been less explored in the field of... 

A highly efficient magnetic Brønsted acid catalyst was synthesized based on immobilization of 2-methylimidazole functionalized by chlorosulfonic acid on the surface of silica-coated magnetic nanoparticles (Fe3O4@SiO2-2mimSO3H). The catalyst has an excellent activity and recyclable for at least 6 reaction runs and is proven to be highly effective in the synthes is of α-aminophosphonate compounds in a green way. The facile recovery of the catalyst is carried out by applying an external magnet device. It is both "green" and efficient. The catalyst was fully characterized by techniques of TEM, SEM, FT-IR, TGA, and elemental analysis (CHNS)  

In this research, the parameters affecting the Nusselt number of a generator rotor and stator under varying heat transfer rate are experimentally studied. In spite of the stator having no grooves, the rotor has four large triangular grooves. The temperature and then heat transfer rate of the rotor and stator are experimentally measured in three longitudinal and two angular positions. First, the effect of axial Reynolds number and rotor rotational speed on the rotor and stator Nusselt number with constant heat transfer rate ratio is studied. The range of the axial Reynolds number and rotational speed used is from 4000 to 30,000 and from 300 to 1500 rpm, respectively. Next, the effect of... 

Mn1.5Co1.5O4 oxide spinels are widely used as protective coatings for stainless steel interconnects within planar solid oxide fuel cell stacks. Containing both cubic and tetragonal crystalline phases, these Mn/Co oxide spinels exhibit favorable thermal stability and electronic conductivity for the SOFC interconnect application. Slurry-based coating applications of Mn/Co oxides require precursor powders, which can benefit from being nano-structured. In this study, the sol-gel synthesis of nanocrystalline Mn1.5Co1.5O4 spinel is investigated. The decomposition of sol-gel precursors, as well as the crystalline phase structures and microstructures of the product Mn1.5Co1.5O4 are characterized by... 

In this paper a novel algorithm for detection, parameter estimation, and image formation of a moving target in ground-based circular strip-map synthetic aperture radar (GBCSAR) is proposed. Because multiple similar scans of the scene with short revisit time are possible, moving target detection is performed by clutter cancellation. Despite of the frequency-domain or multi-antenna clutter cancellation methods, this system has the capability of removing the clutter completely regardless of the target speed or the signal to clutter ratio (SCR). Estimation of target parameters and range-cell migration correction (RCMC) is based on comparing two consecutive target images. Finally the azimuth... 

Graphene oxide (GO) was chemically modified withpara-aminobenzoic acid (PABA) to immobilize copper(ii) ions on its surface and used as a nanocatalyst for the oxidative C(sp2)-H bond amination reaction. A practical method to prepare Cu2+supported onpara-aminobenzoic acid grafted on GO was reported. The prepared Cu2+@GO/PABA was characterized by FT-IR, XRD, SEM, AFM, TEM, UV-Vis, and ICP techniques. The results showed that the morphology, distribution, and loading of copper ions could be well-adjusted by grafting of PABA on GO. Moreover, just 2 mol% of Cu2+@GO-PABA could catalyze the C-H activation reaction of benzoxazole and benzothiazole with secondary amines in >94% yields. Also, the... 

This study represents the investigation of In2S3 thin films, which have been deposited with different Indium salts (Chloride, Acetate, and Nitrate) using the Chemical Spray Pyrolysis (CSP) method. The Mott-Schottky analysis has been used in case of studying the electrical properties of films such as conduction and valence band, carrier densities, Fermi level (Efn), flat band potential, and semiconductor type. In the next step, the Rb1MAFA perovskite solar cell has been simulated, and the results have been validated by the experimental data (with the least parameters for fitting). Finally, In2S3 layers have been inserted on the SnO2 layer to decrease the recombination rate and enhance the... 

Synthesis of dithiocarbamates by the one-pot three-component Markovnikov addition reaction of an amine, carbon disulfide and an alkyl vinyl ether or N-vinylpyrrolidone is reported in polyethylene glycol (PEG) under a mild and green procedure with high yields and completely regiospecific. Also, the products were used as efficient starting materials for amidoalkylation of electron-rich arenes such as naphthols and indoles