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The use of 1,3-bis(N-heterocyclic)carbene ligands with different alkyl wingtip groups (alkyl = methyl, isopropyl and tert-butyl) is an effective method for the palladium-catalysed direct S-arylation of methylphenyl sulfoxide and C-C coupling of various of aryl halides with alkenes. The reactions proceed in moderate to good yields. Interestingly, it is shown experimentally that, by using bulkier bidentate N-heterocyclic carbene ligands, more selective catalytic systems towards cis products in Heck coupling reactions can be achieved  

The use of 1,3-bis(N-heterocyclic)carbene ligands with different alkyl wingtip groups (alkyl = methyl, isopropyl and tert-butyl) is an effective method for the palladium-catalysed direct S-arylation of methylphenyl sulfoxide and C–C coupling of various of aryl halides with alkenes. The reactions proceed in moderate to good yields. Interestingly, it is shown experimentally that, by using bulkier bidentate N-heterocyclic carbene ligands, more selective catalytic systems towards cis products in Heck coupling reactions can be achieved. Copyright © 2016 John Wiley & Sons, Ltd  

In quantum approaches to consciousness, the authors try to propose a model and mechanism for the mind-brain interaction using modern physics and some quantum concepts which do not exist in the classical physics. The independent effect of mind on the brain has been one of the challenging issues in the history of science and philosophy. In some recent mind-brain interaction models, the direct influence of mind on matter is either not accepted (as in Stapp's model) or not clear, and there have not been any clear mechanism for it (as in Penrose-Hameroff's model or in Eccles's model). In this manuscript we propose a model and mechanism for mind's effect on the matter using an extended Bohmian... 

In quantum approaches to consciousness, the authors try to propose a model and mechanism for the mind-brain interaction using modern physics and some quantum concepts which do not exist in the classical physics. The independent effect of mind on the brain has been one of the challenging issues in the history of science and philosophy. In some recent mind-brain interaction models, the direct influence of mind on matter is either not accepted (as in Stapp's model) or not clear, and there have not been any clear mechanism for it (as in Penrose-Hameroff's model or in Eccles's model). In this manuscript we propose a model and mechanism for mind's effect on the matter using an extended Bohmian... 

The preparation of two new azulene-based imine ligands N-(2,6-diisopropylphenyl)-6-tBu-1-azulenylmethaneimine, 3, and N-(2,6-diisopropylphenyl)-6-tBu-3-(2,6-diisopropylphenyliminomethyl)-1-azulenylmethaneimine, 4, is described. These imine ligands display stimuli responsive emissive behavior and their fluorescence can be switched on and off by protonation and neutralization with trifluoroacetic acid and trimethylamine, respectively. The cyclometalation of the monoimine ligand by platinum gave the cyclometalated complex [PtMe(SMe2)(3′)], 5, (where the prime denotes the cyclometalated ligand 3). The reaction of 5 with TlPF6 yields the trinuclear bent Pt2Tl complex {[PtMe(SMe2)(3′)]2(μ-Tl)}PF6,... 

This work takes a new approach to solving non-hydrostatic equations of layered flows over bottom topography. A perturbation technique is used to find explicit expressions for a flow for different regimes of single- and two-layer flows over a sill. Excellent agreement with previous solutions and experimental data is obtained, and more details of the non-hydrostatic flow over a sill are revealed. The proposed method is simple and compact and removes the need for complex numerical techniques to solve the non-hydrostatic equations. It is shown that in the approach-controlled regime of two-layer flow over a sill, the flow upstream and farther downstream the sill crest can be described by the... 

This study is concerned with numerical modeling of viscous surface wave motion using boundary element method (BEM). The equations of motion for thin boundary layers at the solid surfaces are coupled with the potential flow in the bulk of the fluid, and a mixed BEM-finite difference technique is used to obtain the viscosity-related quantities such as wave damping rate, shear stress, and velocity distribution inside the boundary layer. The technique is presented for standing surface wave motion. An excellent agreement is obtained between the numerical predictions and the previous results. The extension to other free surface problems is straightforward. © 2005 Elsevier Ltd. All rights reserved  

An effective numerical technique is presented to model turbulent motion of a standing surface wave in a tank. The equations of motion for turbulent boundary layers at the solid surfaces are coupled with the potential flow in the bulk of the fluid, and a mixed BEM-finite difference technique is used to model the wave motion and the corresponding boundary layer flow. A mixing-length theory is used for turbulence modelling. The model results are in good agreement with previous physical and numerical experiments. Although the technique is presented for a standing surface wave, it can be easily applied to other free surface problems. Copyright © 2005 John Wiley & Sons, Ltd  

This study is concerned with evolution of selective withdrawal of a linearly stratified fluid through a line sink at the base of a reservoir with bottom topography in the form of a sill of small height. The problem is investigated theoretically in the linear, inviscid limit using a perturbation technique. The induced flow due to motion of the first few shear waves is studied. It is shown that the effect of a sill on the flow field is confined mostly to the withdrawal layer in the vicinity of the sill. Equations are proposed for the steady withdrawal layer thickness and the critical Froude number in the presence of a sill. © 2003 American Institute of Physics  

An effective numerical technique is presented to model turbulent motion of a standing surface wave in a tank. The equations of motion for turbulent boundary layers at the solid surfaces are coupled with the potential flow in the bulk of the fluid, and a mixed BEM-finite difference technique is used to obtain the wave and boundary layer characteristics such as bed shear stress. A mixing-length theory is used for turbulence modeling. Although the technique is presented for a standing surface wave, it can be easily applied to other free surface problems. Copyright © 2005 by ASME  

This study is concerned with numerical modeling of viscous surface wave motion using boundary element method (BEM). The equations of motion for thin boundary layers at the solid surfaces are coupled with the potential flow in the bulk of the fluid, and a mixed BEM-finite difference technique is used to obtain the surface wave motion characteristics including the decay rate. The technique is presented for a standing surface wave motion. The extension to other free surface problems is discussed  

New binuclear palladium (II) complex featuring ONO pincer type hydrazone ligand was synthesized and characterized by spectroscopic and single-crystal XRD analysis. This complex showed excellent catalytic activity towards the copper-free Sonogashira cross coupling reaction. The main advantages over previous methodologies include low catalyst loading, less problematic reaction media (H2O–DMSO) and reusability in homogenous systems for optimal performance  

Reservoir topography has significant effects on mechanism of selective withdrawal. We study selective withdrawal of a linearly stratified fluid through a point sink in a long rectangular reservoir with a sill at the bed experimentally and analytically. Experiments were conducted for various flow rates and sill heights to evaluate their effects on withdrawal layer in the inertial-buoyancy regime. Transition to the steady state is discussed in terms of dynamics of shear waves over the sill. The results show that in presence of a sill the withdrawal layer is thicker and higher in elevation. For flows controlled at the sill crest, the withdrawal layer thickness in the point-sink flow is almost... 

Base isolation is an acknowledged means to reduce the transmission of earthquake accelerations from the ground into the structure. Of particular interest here are systems where the bearing slides on a concave surface which produces a self-centering force restoring the building to its original position. While the idea behind the technology is straightforward, the numerical simulation of the structural response is difficult, since the contact between the bearing and the sliding surface changes continually between sticking and sliding in a nonlinear process. The research presented here aims at developing a computational model for base-isolated building which would allow the engineer to simulate... 

To date various commercial systems have been used in the GAIT analysis. These systems have some difficulties for clinical use, such as interfering with normal movement and high prices. The possibility of utilization of Kinect as a sensor for GAIT analysis has been studied in this research. The accuracy of Kinect in calculation of GAIT parameters such as lower limb joint angles, stride time, and stride length were computed during normal walking. The effects of the sensor's position and direction relative to the walkway were also investigated. The Kinect sensor was installed at different positions toward the motion path. In each position the data was recorded by both Kinect and a commercial... 

This paper quantitatively investigates the role of flexibility of blade-like stems and, in particular, the occurrence of stem resonance on lateral dispersion in emergent aquatic canopies. Two sets of experiments are presented: single-stem and canopy tests. In the first set, the flow around single blade-like flexible model stems and the proximity to a resonant state are studied. Wake areas behind four model stems with distinct flexibilities are measured by particle image velocimetry for stem Reynolds numbers between 350 and 850. A single flexible emergent stem bends and oscillates in in-line and cross-flow directions due to periodic forcing associated with the vortex shedding. The plant... 

This study is concerned with a theoretical and laboratory investigation of selective withdrawal of a linearly stratified fluid through a line sink at the base of a reservoir with a side contraction. The width-averaged equations of motion are solved numerically. The evolution of selective withdrawal and the flow properties at the steady state are studied. Using the numerical results, an equation is proposed for the withdrawal layer thickness, the critical Froude number, and the density thickness. For comparison, experiments were conducted in a flume and particle image velocimetry technique was used to capture the flow field upstream of a contraction during evolution of selective withdrawal.... 

A social network is a set of people (or organizations or other social entities) connected by a set of social relationships, such as friendship, co-working or information exchange. Social network analysis focuses on the analysis of patterns of relationships among people, organizations, states and such social entities. Social network analysis provides both a visual and a mathematical analysis of human relationships. Web can also be considered as a social network. Social networks are formed between Web pages by hyperlinking to other Web pages. In this paper a state of the art survey of the works done on social network analysis ranging from pure mathematical analyses in graphs to analyzing the... 

A resonant interaction analysis is used to study the two-dimensional interaction of a surface wave with two waves on a diffuse interface in a stratified fluid. The fluid system is modeled as a combination of two homogenous finite-depth layer with a free surface, divided by a thin third layer. Two possibilities for the interaction are found: one between the surface wave and two first-mode interfacial waves and a second between the surface wave, a first-mode, and a second-mode interfacial wave. By taking the nondimensional density difference δ as a small perturbation parameter, the evolution equations of the interfacial waves are derived asymptotically. The analysis indicates that growth of...