Sharif Digital Repository

Water Gas Shift (WGS) reaction is an old reaction in which syngas is used for producing Hydrogen. At the present time, the major application of this reaction is in fuel cells, since the necessary Hydrogen for these cells is provided by this reaction.
The present study investigate the influence of different preparation methods on properties of Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction, which is now known as the Commercial catalyst for low temperature WGS, and its influence on performance of Cu-ZnO/Al2O3 catalyst to derive an optimal Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction. Cu-ZnO/Al2O3 catalysts was synthesized by CP, DP, DP-Ultra, IWI , CP-Urea, and... 

Dimethyl Ether (DME) is a pure and economic fuel which can be used as a suitable alternative for diesel fuels. Two processes are traditionally used for DME synthesis: producing methanol from synthesis gas and then dehydrating it to DME (direct process), and converting methanol into DME in a catalytic dehydration reactor over a solid-acid catalyst (indirect process), in which the indirect process seems to have economical advantage. In this research, the γ-Al2O3 catalyst was synthesized through precipitation process and then characterized by powder X-ray diffraction (XRD) and porosimetry analysis. Afterwards this catalyst was utilized in methanol dehydration reaction in a slurry reactor. Next,... 

In this research, an Index of Iran informal economy in response to the government interventions in credit, labor and product markets is stimated by EMIMIC model. To do this, first these interventions are measured using principal components analysis. In the model, the variables GDP and employment are used as indicators and taxation rates, government distortions in credit, labor and product markets, government expenditure, per capita income, unemployment and inflation as causes of the informal economy. We conclude these government interventions have affected Iran informal economy and their influence is more than indirect interventions influence such as taxation. The estimated index of Iran... 

One of the ways that corrosion control is presented is the use of coatings that have good properties such as high adhesion, impact resistance, ultraviolet radiation, and so on. They also have other unique properties like anti-corrosion property. To achieve coatings with these advanced properties, they use special properties of nanocomposites. Nanocomposites can add or improve one or more properties to coating properties.In the present study, we tried to first synthesize NanoDiamond/Polyaniline hybrid nanoparticles in different percentages and then use this hybrid in epoxy ester coating. To characterize this hybrid, various analyzes such as FE-SEM, TEM, FT-IR, UV-Visible, TGA and XRD were... 

In recent years, nanodiamond (ND) has been used as reinforcement in polymeric nanocomposites in order to improve mechanical properties, thermal conductivity, etc. The surface of nanodiamond has several functional groups which make it appropriate adsorbent. In this study, nanodiamond was modified with dodecylamine corrosion inhibitor and was utilized (1wt %) in epoxy based nanocomposite. Fourier transform infrared spectroscopy (FTIR) analysis was used to confirm the surface modification of Nanodiamond. In order to estimate the loading amount of corrosion inhibitor, thermogravimetric analysis was investigated. FE-SEM analysis demonstrated nanoparticle dispersibility in epoxy matrix. Regarding... 

In cases with excessive anteversion even after adolescence, surgeons have to choose osteotomy surgery to modify this abnormality. This surgery and modifying the anatomical problem does not necessarily lead to modify the patients’ gait cycle abnormalities; the authors’ hypothesis is the probable reason may be the persistence of the implement of the patients’ kinematics compensation mechanism even after the surgery. This mechanism is used to almost correct the gait of those with excessive anteversion. First, by using gait analysis text books, a patient’s gait cycle is analyzed; this analysis is consist of 3DGA with EMG and observational gait. Then, by using OpenSim, the patient’s patterns of... 

One of the most important EOR methods in oil reservoirs is surfactant and polymer flooding. Surfactants cause decreasing in interfacial tension between oleic and aqueous phases. However, polymers give us efficient mobility control in displacing oil by increasing the viscosity of aqueous phase. Therefore, oil is displaced in aqueous phase by viscous forces.
One of the most important challenges in surfactant flooding is adsorption. The net surface charge distributed on the rock surface depends strongly on pH. When we inject surfactant in reservoir, electrostatic charge on rock surface causes the first-layer adsorption. After that we have had second-layer adsorption.
In this thesis we... 

Critical flux is an important parameter in membrane bioreactors, which studying it can give a better understanding of treatment by these bioreactors and make utilizing them easier. In this study, the effect of some sludge properties like it’s concentration, sludge volum index, concentration of protein and carbohydrate in EPS and SMP and the effect of some operating conditions like aeration flow rate and rest mode on critical flux in a submerged membrane bioreactor are investigated. In addition to comparison of TMP-t figures drived from flux step experiment, the hystersis figures are also compared. Finally, two long term experiments at two sub critical fluxes are done in order to study the...