Sharif Digital Repository

The problem of launching a satellite to low earth orbit has been considered. Preliminary concepts such as satellite orbits, launcher missiles and their equations of motion, and traditional methods for guidance of launchers are reviewed first. Then a new method for optimizing the launch trajectory under non-ideal conditions is introduced in which the solution of a known ideal trajectory optimization problem is used as an initial guess for the actual optimization problem. Several methods for guiding a launcher to place a satellite in Earth orbit are presented next; they have been titled as (1) launch path re-computation outside the atmosphere, (2) prediction error minimization, and (3) output... 

Separation of particles and cells is one of the most important and practical methods in fields such as biomedicine, medicine and industry. In microfluidics There are various methods for particles and cells separation According to the source of them, they can be categorised as active and passive techniques. Active techniques rely on an external force field. The most important advantage of this method is controlling the force on the particles during the experiment. However, the flow speed is always limited because particles must be exposed to the outer force field for sufficient duration to achieve effective functionality. passive techniques depend entirely on the channel geometry or intrinsic... 

Issues arising from host-centric nature of IP-based networks lead to emerging Informationcentric networks (ICN). One the most promising architectures of ICN is named data networking (NDN). Unlike IP-based networks, the foundation of NDN is the content not the location which it resides. Voluminous growth of mobile devices necessitates supporting mobility in NDN. Although consumer mobility is supported natively by NDN, the support of producer mobility is yet an open challenge in NDN design. Since producer mobility affects both network performance and end-users satisfaction, it is crucial to handle this problem. The solution is proposed in this paper is based on virtual coordinate-based... 

Titanium and its alloys have wide applications in industry and recently researches have been expanded in this area. The main reasons are unique features of titanium such as biological behavior, corrosion resistance and high strength to weight ratio. The fundamental problem of titanium is low wear resistance that leads to be worn in industrial applications. For more efficiency of titanium, extensive efforts have been made for solving this problem, one of the best solutions is coating.Micro Arc Oxidation (MAO) is a novel method to create ceramic coatings on metals to improve wear and corrosion resistance. In this research nano alumina particles were added to electrolyte to create... 

In recent years, mesoporous nanocrystalline TiO2 films have been regarded extensively. This kind of materials due to having unique surface area, structural and bulk properties, is used in many technological applications. In this work, a stable TiO2 sol was prepared using F127 Copolymer template and evaporation induced self-assembly method (EISA). The mesoporous TiO2 powders and thin films were then prepared. The as-deposited thin films were aged under five different conditions for 72h. Finally the samples were heat treated at 350°C, 400°C and 450°C. N2 adsorption/desorption results verified formation of mesoporous structure. Moreover, x-Ray diffraction patterns exhibited that the synthesized... 

For designing a unit operation, knowledge about physical properties is essential. This is attained either by direct measurement, which needs spending time and cost or, using proposed correlations. This project is subjected to theoretical analysis of viscosity as the most important rheological property of dilute suspensions of microgels, or in other words colloidal suspensions of porous spheres. They are applied in drug delivery, enhanced oil recovery, synthesis of catalyst and adsorption of heavy metal ions from aqueous systems for water purification purposes. In dilute suspensions particles are faraway from each other and there is no interaction between them therefore, it is better to... 

Gas pollutants are included volatile inorganic compositions and odorous materials, which are harmful and dangerous for environment and human health. There are several methods for removing gas pollutants such as physical, chemical and biological methods. In this work, we discuss about ethyl-mercaptan adsorption in LPG by ZSM-5 zeolite and in use of micro systems (micro channels). This work is also concerned about micro channel coating by ZSM-5 and NaY zeolites on glass and the method of coating with (3-Chloropropyl) trimethoxysilane linker. After selecting the appropriate method for zeolite coating, we proceed to micro channel coating. In this research, four different designs of micro channel... 

In this project, synthesis of sol-gel derived Pb(Zr0.52Ti0.48)O3 nanotubes in the form of PZT-CNT hybrid, was accomplished by using multi-walled carbon nanotubes as sacrificial template. Simultaneous thermal analyses proved that the as-derived amorphous material crystallized at a significantly low temperature by a considerably low activation energy. X-ray diffraction and selected area electron diffraction patterns showed that the final crystal structure is tetragonal perovskite. Raman spectroscopy results proved that significant changes happened at the surface of carbon nanotubes which are believed to be due to coating. Electron images supported the deposition of a coating on the surfaces of... 

The purpose of this study is to study heterogeneous nanocatalysts for the production of biofuels by the method of exchange of styrene using oil and methanol as a fossil fuel alternative. Preparation of nanocatalysts, performing characteristic tests and investigating the reaction in different operating conditions in the batch reactor has already been studied. Therefore, in this study, the production of biodiesel fuel using the trans-esterification of canola oil with nanocatalysts in the micro-reactor reactor will be discussed. Previously, a heterogeneous catalyst (lithium based on calcium-lanthanum) was constructed using a co-incineration method and a wet inoculum, and as active and stable... 

% of human blood makes up of plasma, that this plasma is a rich source of proteins that can be used as biomarkers for a variety of clinical diseases and laboratory research, therefore, it is necessary that the plasma be separate by a high purity percentage. Using a centrifuge It is a common method used to separate plasma from blood, but because it requires large equipment and a large volume of blood, as well as stress caused by centrifugal force, increases the probability of damage to the biomarkers, so it has been tried today that Use methods that are easy to transport and require a small amount of blood. The idea of using the microfluidic device has been put forward for the purpose of... 

The use of polyether ether ketone (PEEK) in bone implants is limited due to a lack of cell adhesion and proliferation. Therefore, in this study, we modified the surface of PEEK with a nanocomposite coating containing piezoelectric and bioactive properties. Sulfonated PEEK with suitable mechanical and hydrophilic properties along with polyvinylidene fluoride was used as a biocompatible polymer with piezoelectric properties for coating. Also, nanohydroxyapatite was used as a bioactive material, and carbon nanofibers with significant mechanical and electrical properties were used in the nanocomposite. The surface was sulfonated as an intermediate layer to improve the connection between the... 

In the present work preparation of Ni-TiO2 films and their microstructural and mechanical properties were studied. For film preparation, DC current mode of electrochemical deposition method was used in Watts Nickel bath with different concentrations of transparent TiO2 sol up to 30 mL/L. It presents a new generation of nano Ni-TiO2 coating as a composite film for corrosion and erosion resistance applications. The best wear volume of 0.0046 mm3 was achieved for 30 mL/L Ni-TiO2 nanocomposite in comparison to 0.0071 mm3 for pure Ni film. Moreover, the coating hardness increased to ~345 HV50 for Ni-TiO2 nanocomposite. Corrosion rate of the coatings improved down to 1.10E-05 mm/year with addition... 

The aqueous phase reforming (APR) of glycerol is an attractive yet challenging pathway to convert abundant biomass into value added hydrogen. Pt catalysts have received attention due to their ability to produce hydrogen-rich gas under APR conditions. In this work, the conversion of glycerol into hydrogen is demonstrated using Pt0.05CexZr0.95-xO2 (x=0, 0.29, 0.475, 0.66 and 0.95) solid solution catalysts and a series of M-doped Pt-MgO (M = Pd, Ir, Re, Ru, Rh and Cr) sheet-shaped nano-catalysts. Both characteristic (XRD, BET, H2-TPR, CO-chemisorption, TEM and XPS) and reactivity measurements were used to investigate the activity of the catalysts. Results indicated that reactivity depended on... 

Methiocarb [3,5-dimethyl-4-(methylthio) phenyl methylcarbamate] is an N-methylcarbamate with neurotoxic action. Because carbamate pesticides are acetylcholinesterase inhibitors, they are considered to be carcinogens and mutagens. Methiocarb pesticide is widely used throughout the world particularly effective as fungicides, insecticide and bird repellent. To prevent its harmful effects on animals, humans, and the environment, it is of crucial importance to develop simple and sensitive methods for in-situ detection of methiocarb. This research describes a simple and low-cost method for on-site monitoring of methiocarb insecticide. Gold nanoparticles (AuNPs) aggregation caused by methiocarb,... 

A droplet placed on the boundary of two solids with different wettabilities will move to the more wettable part. This is a well-known phenomenon and has been extensively used in a variety of processes and applications ranging from biological systems and ink jet printing to the commercial lab-on-a-chip. Because of its importance, many studies are conducted around this phenomenon. The difference between the equilibrium contact angles of the droplet on the two parts gives rise to an interfacial driving force which moves the droplet. Such a motion is not continuous as the droplet slides to the more wettable area, the driving force diminishes and consequently the droplet stops. A non-stop motion... 

Nowadays, using of microwave integrated circuits in military and industry applications has been became popular, especially with the advent of monolithic microwave integrated circuits which provide possibility of fabrication of amplifiers in large volume with high precision and appropriate cost. Power amplifiers as the last block of transmitters, are such circuits that are too attractive in this area. Since high power amplifiers consume a lot of power in transistors, large amount of heat will be in the surface of chip. Loss of some of consumed power in amplifiers results increasing transistor’s channel and chip surface temperature. Increase in channel temperature results degradation in... 

Although unsaturated soils exist all around the world, civil engineers are not familiar with unsaturated soil behavior; consequently, the soil structures they design may neither be safe nor economical. Thus, implementing unsaturated soil constitutive models to practical computer softwares can be very beneficial for geotechnical engineers. Geotechnical engineering softwares normally consider soil in saturated or dry conditions. So, their built-in constitutive models do not usually consider unsaturated soils. In this study, Barcelona Basic Model (BBM), which is developed using critical states soils mechanics principles, is implemented to the FLAC2D software. This model can simulate complex... 

Lifetime extension would be a necessary preventive action to halt micro cracks expansion on the airplane external surface. To decide about whether to perform this operation, one should examine technological maturity, costs and technical parameters. Technical status in lifetime extension is one of the major drivers of this decision which should be considered in the first step of technology management process which is known as the technology attractiveness step. In this research, major technologies of rejuvenation is examined and categorized by the technology mapping. Also, key processes of rejuvenation and technological fields ranking has been determined by the procedural view tools of the... 

Centrifugal compressors have wide applications in the turbochargers, aircraft propulsion and petrochemical industry. Therefore it is important to design high efficiency centrifugal compressor. Knowledge of compressor performance at different conditions, energy losses and the contribution of each component of compressor in efficiency losses have of great importance.
In this research, different loss models of the centrifugal compressor were reviewed and investigated. Then 1D codes were developed based on the loss models, and performance characteristics of S2B Schweitzer and GT4082 Garret compressors at different conditions were achieved. In order to evaluate the modeling results,... 

Due to the potential risk of sulfur compounds in fossil fuels and according to today’s regulations, sulfur content should be kept as low as possible, e.g., below 5 ppm. Mercaptans are one of the sulfur components in natural gas. Scope of this research defined as catalytic removal of ethyl mercaptan from the gas stream. For this purpose, two microreactor systems placed in series. In the first microreactor, catalytic decomposition of ethyl mercaptan has been investigated. In the first step of this survey, a microreactor with 24 microchannels with a newly designed distributor has been developed with a computational fluid dynamic technique. in comparison to the conventional triangular...