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nematpour--mohsen
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Highly regioselective, base-catalyzed, biginelli-type reaction of aldehyde, phenylacetone and urea/thiourea kinetic vs. thermodynamic control
, Article Journal of Sulfur Chemistry ; Volume 39, Issue 2 , 2018 , Pages 151-163 ; 17415993 (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, A ; Sharif University of Technology
Taylor and Francis Ltd
2018
Abstract
An efficient one-pot regioselective synthesis of various novel 3,4-dihydropyrimidin-2(1H)-one (DHPMs) via a three-component Biginelli-type condensation of aldehyde, phenylacetone and urea/thiourea under two different based-catalyzed conditions is described. In kinetic control path, lithium N, N-diisopropylamide (LDA-20 mol % generated in situ from n-BuLi and diisopropylamine) was used as the base, in tetrahydroforane (THF) as the solvent at 0°C. Thermodynamic control path was run with NaH as the base, in EtOH as the solvent under reflux status. The simple procedure, mild base-catalytic reaction conditions, no column chromatography and good to high yields are important features of this...
Solubility of CO2 and H2S in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate
, Article Journal of Natural Gas Science and Engineering ; Volume 30 , Volume 30 , 2016 , Pages 583-591 ; 18755100 (ISSN) ; Jalili, A. H ; Ghotbi, C ; Rashtchian, D ; Sharif University of Technology
Elsevier
2016
Abstract
The solubility of carbon dioxide and hydrogen sulfide gases in the ionic liquid 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([C2mim][OTf]) was measured at temperatures from (303.15-353.15) K and pressures up to about 3.0 MPa. The Henry's law constants were determined from the new experimental data, which in turn were used to derive the change of some thermodynamic functions of dissolution of the gases in that particular ionic liquid. The new experimental data were correlated by a combination of the extended Henry's law and Pitzer's model for the excess Gibbs energy. The average relative percent deviation (ARD%) of correlated molality values from experimental data are within...
Highly regioselective, base-catalyzed, biginelli-type reaction of aldehyde, phenylacetone and urea/thiourea kinetic vs. thermodynamic control
, Article Journal of Sulfur Chemistry ; 2017 , Pages 1-13 ; 17415993 (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
2017
Abstract
An efficient one-pot regioselective synthesis of various novel 3,4-dihydropyrimidin-2(1H)-one (DHPMs) via a three-component Biginelli-type condensation of aldehyde, phenylacetone and urea/thiourea under two different based-catalyzed conditions is described. In kinetic control path, lithium N, N-diisopropylamide (LDA-20 mol % generated in situ from n-BuLi and diisopropylamine) was used as the base, in tetrahydroforane (THF) as the solvent at 0°C. Thermodynamic control path was run with NaH as the base, in EtOH as the solvent under reflux status. The simple procedure, mild base-catalytic reaction conditions, no column chromatography and good to high yields are important features of this...
A copper-catalyzed synthesis of functionalized quinazolines from isocyanides and aniline tri- and dichloroacetonitrile adducts through intramolecular C-H activation
, Article Synlett ; Volume 28, Issue 12 , 2017 , Pages 1441-1444 ; 09365214 (ISSN) ; Rezaee, E ; Tabatabai, S. A ; Jahani, M ; Sharif University of Technology
2017
Abstract
A novel class of substituted quinazolines were prepared in good yields by a one-pot three-component reaction of isocyanides with adducts of anilines and tri- or dichloroacetonitrile, followed by intramolecular C-H activation, catalyzed by copper(I) iodide with l -proline as a ligand in acetonitrile at room temperature. © 2017 Georg Thieme Verlag Stuttgart .New York-Synlett
Synthesis of functionalized benzothiadiazine 1,1-dioxide derivatives via intramolecular C–H activation reactions of trichloroacetamidine and benzenesulfonyl chloride
, Article Tetrahedron Letters ; Volume 59, Issue 21 , 23 May , 2018 , Pages 2054-2056 ; 00404039 (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
Elsevier Ltd
2018
Abstract
The synthesis of functionalized benzothiadiazine 1,1-dioxide derivatives was achieved through a novel three-component intramolecular C–H activation reaction of trichloroacetonitrile, benzenesulfonyl chloride, and various primary amines. This reaction was performed in the presence of catalytic copper(I) and L-proline as the ligand in tetrahydrofuran at room temperature. © 2018 Elsevier Ltd
Novel one-pot synthesis of functionalized quinolines from isocyanides, aniline, and acetylene dicarboxylate via cu-catalyzed intramolecular C─H activation reactions
, Article Journal of Heterocyclic Chemistry ; Volume 56, Issue 4 , 2019 , Pages 1254-1259 ; 0022152X (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
HeteroCorporation
2019
Abstract
The one-pot synthesis of a novel class of substituted quinoline derivatives with good yields is achieved via the Cu-catalyzed intramolecular C─H activation reaction between isocyanides, aniline, and acetylene dicarboxylate in MeCN at room temperature. The existence of one-pot conditions, availability of a starting material-catalyst, the absence of column chromatography, and a high yield of products are among the advantages of this method. The structures are confirmed spectroscopically (1H NMR and 13C NMR, IR, and EI-MS) and through elemental analyses
Ultrasound-assisted synthesis of highly functionalized benzo[1,3]thiazine via Cu-catalyzed intramolecular C–H activation reaction from isocyanides, aniline-benzoyl(acetyl) isothiocyanate adduct
, Article Ultrasonics Sonochemistry ; Volume 50 , 2019 , Pages 1-5 ; 13504177 (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
Elsevier B.V
2019
Abstract
A facile sonochemical route for the synthesis of benzo[1,3]thiazine derivatives via a one pot, multicomponent, intramolecular C–H activation reaction from isocyanides, aniline and benzoyl (acetyl) isothiocyanate adduct catalyzed by copper (I) iodide in acetone at 30 °C have been reported. The advantages of the described method include using simple and readily available starting materials and performing under mild copper-catalytic reaction conditions and also obtaining pure product with high yield without applying column chromatography. Furthermore, using the sonochemical methodology as an efficient method led to reduce the reaction times. © 2018 Elsevier B.V
Ultrasound-assisted synthesis of highly functionalized benzo[1,3]thiazine via Cu-catalyzed intramolecular C–H activation reaction from isocyanides, aniline-benzoyl(acetyl) isothiocyanate adduct
, Article Ultrasonics Sonochemistry ; Volume 50 , 2019 , Pages 1-5 ; 13504177 (ISSN) ; Rezaee, E ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
Elsevier B.V
2019
Abstract
A facile sonochemical route for the synthesis of benzo[1,3]thiazine derivatives via a one pot, multicomponent, intramolecular C–H activation reaction from isocyanides, aniline and benzoyl (acetyl) isothiocyanate adduct catalyzed by copper (I) iodide in acetone at 30 °C have been reported. The advantages of the described method include using simple and readily available starting materials and performing under mild copper-catalytic reaction conditions and also obtaining pure product with high yield without applying column chromatography. Furthermore, using the sonochemical methodology as an efficient method led to reduce the reaction times. © 2018 Elsevier B.V
Synthesis of highly functionalized quinazoline-2,4(1H,3H)-diones from isocyanides, aniline and isocyanate via Cu-catalyzed intermolecular C-H activation reactions
, Article Letters in Organic Chemistry ; Volume 17, Issue 11 , 2020 , Pages 832-836 ; Fasihi Dastjerdi, H ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
Bentham Science Publishers
2020
Abstract
A simple and appropriate procedure for the synthesis of quinazoline-2,4(1H,3H)-dione derivatives from isocyanides, aniline and isocyanate via the Cu-catalyzed intramolecular C-H activation reaction is reported. The advantages of this method are one-pot conditions, accessible starting materials-catalyst, high yield of products, and short reaction times. The structures are confirmed spectroscopically (1H-and13C-NMR, IR and EI-MS) and by elemental analyses. © 2020 Bentham Science Publishers
Synthesis of poly-substituted thiophenes in the realm of sulfonylketenimines chemistry
, Article Journal of Sulfur Chemistry ; Volume 41, Issue 2 , 2020 , Pages 146-153 ; Sedaghat, A ; Nematpour, M ; Jahani, M ; Tabatabai, S. A ; Sharif University of Technology
Taylor and Francis Ltd
2020
Abstract
An efficient synthesis of highly substituted thiophenes was developed by means of sulfonylketenimines in a multi-step reaction including heterocumulene system containing sulfur and nitro-alkanes with acidic α-hydrogen. The speed and ease of conducting this four-component reaction under mild conditions and using available materials makes it an ideal method to synthesize high purity substituted thiophenes with sulfonamide moiety. All structures synthesized are confirmed by the instrumental analysis (EI-MS, IR and 1H /13C-NMR). © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group
Experimental Measurement, Modeling And Simulation Of Carbon Dioxide And Hydrogen Sulfide Absorption And Separation By [Emim][Otf]
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Siroos (Supervisor) ; Rashtchian, Davood (Co-Advisor) ; Jalili, Amir Hossein (Co-Advisor)
Abstract
Inrecent years,research onionic liquidsarehighly developed. Because ofthe uniqueproperties ofionic liquidssuch asnegligiblevapor pressureandthermalstability for use inlarge areasofmajor industries have been considered.However,ionic liquids because they have lessenvironmental wasteas an alternative to convention alorganic solventssuch asaminesalkanolanarise.Ionic liquid sassolventsfor theremoval ofacid gases such as water and gasare investigated. The solubility of CO2 and H2S in the [Emim] [OTF] (1-ethyl-3-methylimidazolium triflate) in the temperature range 303.15 to 343.15 K and pressures up to 2 MPa has been studied experimentally. In order to capture modeling, the model equations of state...
Sole versus dual-sourcing under order dependent lead-times and prices [electronic resource]
, Article Computers And Operations Research, Published in: Elsevier Journals ; Volume 36, Issue 12, December 2009, Pages 3272–3280 ; Eshghi, Kourosh ; Sharif University of Technology
Abstract
In this paper, we consider a dual-sourcing model with constant demand and stochastic lead times. Two suppliers may be different in terms of purchasing prices and lead-time parameters. The ordering takes place when the inventory level depletes to a reorder level, and the order is split among two suppliers. Unlike previous works in the order splitting literature, the supply lead time between vendor and buyer as well as unit purchasing prices is considered to be order quantity dependent. The proposed model finds out the optimal reorder point, order quantity and splitting proportion, using a solution procedure. Numerical results show that neglecting the relationship between ordering batch size...
Human serum protein adsorption onto synthesis nano-hydroxyapatite
, Article Protein Journal ; Volume 31, Issue 2 , February , 2012 , Pages 150-157 ; 15723887 (ISSN) ; Massah Bidgoli, M ; Behrashi, M ; Mohsen Nia, A ; Sharif University of Technology
2012
Abstract
Adsorption of human serum proteins (Albumin and total protein) onto high purity synthesis nano-hydroxyapatite (HA), Ca 10(PO 4) 6(OH) 2, has been studied in a wide temperature range by UV-visible spectrophotometer. Adsorption isotherm is basically important to describe how solutes interact with adsorbent, andiscriticalinoptimizing the use of adsorbent. Inthe present study, the experimental results werefitted tothe Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (DR) models to obtain the characteristic parameters of each model and square of the correlation coefficients (R 2). According to the results, the DR isotherm model had the best agreement with the experimental data. The effect of...
Effective Permeability of Isotropic Overlapping Sandbodies in 2D Using Percolation Theory
, M.Sc. Thesis Sharif University of Technology ; Masihi, Mohsen (Supervisor)
Abstract
Permeability is an essential parameter used for reservoir evaluation, simulation and management to optimize oil recovery. The conventional approach to estimate reservoir connectivity, conductivity, sweep efficiency and other critical information for decision-making is to build detailed geological models, which are then upscaled to a coarser grid where flow simulations are run. However, this takes many hours to be carried out even for a single realization practically. In practice, a very small number of realizations are considered and consequently the true uncertainty in the results is very poorly estimated. In this study, a statistical model of isotropic overlying sandbodies is used to...
A Metabonomics Study of Samples of Different Diseases: Investigation of Linear and Non-Linear Model by Nuclear Magnetic Resonance
, Ph.D. Dissertation Sharif University of Technology ; Tafazzoli, Mohsen (Supervisor)
Abstract
Metabonomics is a quantitative measurement of time dependent metabolic interactions for living systems in response to the pathological or genetic variations. NMR spectroscopy has emerged as a key tool for understanding metabolic processes in living systems. In this project, the study of metabolomics was performed as classification and regression on samples of parkinson’s disease, multiple sclerosis disease, celiac disease and crohn’s disease. In classification part, various methods were applied using optimal parameters.classification methods in Parkinson’s disease, multiple sclerosis disease, celiac disease and crohn’s disease were RF, CART, PLS-DA, RF and RF respectively. Based on the...
Determination of Parameters Affecting the Linear Seismic Evaluation of Gravity Dams Using Nonlinear Analysis
, M.Sc. Thesis Sharif University of Technology ; Ghaemian, Mohsen (Supervisor)
Abstract
Gravity dams are solid concrete structures that maintain their stability against design loads from the geometric shape and the mass and strength of the concrete. Because of their critical role in supplying portable and agricultural water and problems which would happen if they broke, it is required to consider their stability and keep them in safe conditions. They should be able to continue their function after a disaster such as earthquake. But most of them are aged dams with some have been built near faults. Indeed, there are some concerns regarding the performance of these dams under the effect of seismic loads. This research deals with performance evaluation of concerete gravity . The...
Numerical Analysis of Soil-Nailed Walls in Seismic Condition
,
M.Sc. Thesis
Sharif University of Technology
;
Haeri, Mohsen
(Supervisor)
Abstract
Soil nailing is an in-situ technique of mechanically stabilizing soil masses which has been used in France, Germany, United states, and recently in Iran. A review of literature shows that Soil-Nailed walls have performed well during strong ground motions in comparison with the gravity retaining structures. After the 1989 Loma Prieta earthquake, minor signs of distress or corresponding deformation were found on the Soil-Nailed walls, indicating excellent performance of such structures during moderate and strong shakings. These observations indicate that Soil-Nailed walls have an inherent satisfactory seismic response. This has been attributed to the intrinsic flexibility of the Soil-Nailed...
Collapsible Behavior of Gorgan Loess Using Odeometer
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
In nature, there are types of soils that when goinging under stress at constant moisture, or increase of moisture at constant stress, or change of both characters, they show a sudden and high level decrease in their volume. These type of soils are named as Collapsible soils. Iran is one of the countries that at some parts of its land collapsible soils are found. In this research by using of laboratory equipments, the volume change behavior of collapsible loess soils of Gorgan plain (North of Iran) is evaluated under increase of water content and inundation stress. In these experiments, the usual odeometer cell has been used for exploring the behaviour of collapsibility and volume change of...
The Effect of Cementation by Lime on Collapsible Soils Behavior Using Suction Controlled Oedometer Device Case Study: Loess of Gorgan
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohsen (Supervisor)
Abstract
Collapsible soils such as loess, which are naturally found unsaturated, are kind of problematic soils that undergo sudden and noticeable decrease in volume under increasing stress at constant moisture, increasing moisture at constant stress, or increase in both of them. This kind of soil can be found in some parts of Iran such as plain of Gorgan. To fulfill the main purpose of this study, evaluating the effect of cementation on collapse behavior of loess of Gorgan, some oedometer tests under controlled matric suction were performed on reconstituted samples without and with lime. The lime was added for stabilizing of the collapsible materials and the amount was chosen to be %3 by weight of...