Sharif Digital Repository

FAPbI3 perovskites are excellent candidates for fabrication of perovskite solar cells (PSCs) with high efficiency and stability. However, these perovskites exhibit phase instability problem at room temperature. In this work, to address this challenge we use methylammonium chloride (MACl) as an additive and employed a layer-by-layer thermal evaporation technique to fabricate high-quality perovskite films on a large scale of 25 cm2. The optimized perovskite films show high crystallinity with large grains in the μm-range and reveals phase stability due to the presence of MACl after the annealing process. Finally, we achieved PSCs with 17.7% and 15.9% for active areas of 0.1 cm2 and 0.8 cm2,... 

PbS quantum dots (QDs) have been extensively studied for photovoltaic applications, thanks to their facile and low-cost fabrication processing and interesting physical properties such as size dependent and tunable band gap. However, the performance of PbS QD-based solar cells is highly sensitive to the humidity level in the ambient air, which is a serious obstacle toward its practical applications. Although it has been previously revealed that oxygen doping of the hole transporting layer can mitigate the cause of this issue, the suggested methods to recover the device performance are time-consuming and relatively costly. Here, we report a low-power oxygen plasma treatment as a rapid and... 

Herein, a simple and novel method was used to synthesize a new structure of graphene which can be called hollow graphene. First, the ZnO-Graphene QDs synthesized by solution method and then ZnO QDs were dissolved from this structure using an acidic solution to obtain hollow structure of graphene. Afterward, this structure was used in PbS QDs solar cell in order to improve the transport of electron and decrease the recombination of the carriers. A power conversion efficiency of 5.3% was obtained using hollow graphene as a fast electron extraction layer due to the enhancement of EQE and current density. The improvement of PCE in this device was corresponded to efficient photosensitized... 

Solution-processed quantum dots (QDs) have attracted significant attention for the low-cost fabrication of optoelectronic devices. Here, we synthesized PbS QDs via hot injection method and passivated the trap states by using short thiols and dopant elements for photovoltaic application. In order to study the effect of dopants on photovoltaic application, PbS QDs were doped by using three different cations: Cadmium, Calcium, and Zinc. We utilized Time resolvel Photoluminescence measurement to study the carriers lifetime for different samples and found that the carriers life time increases ∼80% by using Cd as a dopant compared with undoped sample. In addition, the results of J-V measurement... 

This paper presents solid-state ligand exchange of spin-coated colloidal lead sulfide quantum dot (PbS QD) films by methylammonium iodide (MAI) and integration of them in depleted heterojunction solar (DHS) devices having an antireflecting (AR) nanocone plastic structure. Time-resolved photoluminescence measurements determine a shorter lifetime of the charge carries on a semiconductor (TiO2) electron transfer layer for the MAI-passivated QD films as compared with those with long-chain aliphatic or short thiol ligands. Consequently, the DHS device yields improved power conversion efficiency (>125%) relative to oleic-acid-passivated PbS QD films. Using anodized aluminum oxide templates, an... 

Interfacial studies and band alignment engineering on the electron transport layer (ETL) play a key role for fabrication of high-performance perovskite solar cells (PSCs). Here, an amorphous layer of SnO2 (a-SnO2) between the TiO2 ETL and the perovskite absorber is inserted and the charge transport properties of the device are studied. The double-layer structure of TiO2 compact layer (c-TiO2) and a-SnO2 ETL leads to modification of interface energetics, resulting in improved charge collection and decreased carrier recombination in PSCs. The optimized device based on a-SnO2/c-TiO2 ETL shows a maximum power conversion efficiency (PCE) of 21.4% as compared to 19.33% for c-TiO2 based device.... 

The fabrication of efficient perovskite solar cells (PSCs) using all-vacuum processing is still challenging due to the limitations in the vacuum deposition of the hole transporting layer (HTL). Herein, inverted PSCs using copper (II) phthalocyanine (CuPC) as an ideal alternative HTL for vacuum processing are fabricated. After proper optimization, a PSC with a power conversion efficiency (PCE) of 20.3% is achieved, which is much better than the PCEs (16.8%) of devices with solution-based CuPC. As it takes a long time to dissolve CuPC in the solution-based device, the evaporation approach has better advantage in terms of fast processing. In addition, the device with the evaporated CuPC HTL... 

Stability is the main challenge in the field of perovskite solar cells (PSCs). Finding new strategies is required to protect the PSCs from deteriorating agents such as humidity, heating, and illumination. Herein, a new electron transporting layer (ETL), i.e., CdSe/ZnS quantum dots (QDs), is proposed for the fabrication of efficient and stable PSCs. CdSe/ZnS QDs layer not only works as an ETL but also has downshifting property, which can improve both efficiency and stability of the PSCs. Using CdSe/ZnS QDs ETL with green emission, a PSC with maximum power conversion efficiency (PCE) of 18% is achieved. More importantly, the device shows great UV stability, much better than the device with... 

The oxidation of sponge iron products and its destructive effects on iron content as well as other properties have been considered by ferrous technologists for a long time. In this investigation, a unique new low temperature method of preventing and/or retarding the oxidation of direct reduced iron is introduced. Experimental results from laboratory and pilot plant tests show the success of the method which has been named cold briquetting of sponge iron. The optimum condition for briquetting is achieved at 80 kN (Lcm)-1, 6% binder, 10% sponge iron fines and 4% anthracite. While hot briquetted iron has become a successful method for the new generation of iron reduction plants, cold... 

Linear-dendritic ABA triblock copolymers containing poly(ethylene glycol) (PEG) as B block and hyperbranched poly(citric acid) (PCA) as A blocks were synthesized through polycondensation. The molecular self-assembly of synthesized PCA-PEG-PCA copolymers in water led to formation of nanoparticles and fibers in different sizes and shapes depending on the time and size of PCA blocks. Ten days after dissolving PCA-PEG-PCA copolymers in water, the size of fibers had reached several millimeters. Mixing a water solution of fluorescein as a small guest molecule and PCA-PEG-PCA copolymers led to the encapsulation of fluorescein by products of molecular self-assembly. To investigate their potential... 

Linear-dendritic copolymers containing hyperbranched poly(citric acid) and linear poly(ethylene glycol) blocks (PCA-PEG-PCA) were used as reducing and capping agents to synthesize and support gold nanoparticles (AuNPs). PCA-PEG-PCA copolymers with 1758, 1889 and 3446 molecular weights, called A1, A2 and A3 through this work, respectively, were synthesized using 2, 5, and 10 citric acid/PEG molar ratios. The diameter of A1, A2 and A3 in a fresh water solution was investigated using dynamic light scattering (DLS) and it was between 1.8 and 2.8 nm. AuNPs were simply synthesized and supported by addition a boiling aqueous solution of HAuCl4 to aqueous solutions of A1, A2 and A3. Supported AuNPs... 

This paper presents a novel patchwork audio watermarking scheme with a psychoacoustic model of HAS in DFT domain that has significantly higher detection robustness compared to standard and modified patchwork watermarking algorithms. In addition, watermark is perceptually tuned, so that its embedding is transparent. The proposed algorithm can be used for transmitting hidden data through telephone channel. Experimental results show that the proposed watermarking algorithm is sustainable against compression algorithms such as MP3, LPF, resampling, requantization and AWGN attacks. © 2008 IEEE  

The solar to electric power conversion efficiency (PCE) of perovskite solar cells (PSCs) has recently reached 22.7%, exceeding that of competing thin film photovoltaics and the market leader polycrystalline silicon. Further augmentation of the PCE toward the Shockley-Queisser limit of 33.5% warrants suppression of radiationless carrier recombination by judicious engineering of the interface between the light harvesting perovskite and the charge carrier extraction layers. Here, we introduce a mesoscopic oxide double layer as electron selective contact consisting of a scaffold of TiO2 nanoparticles covered by a thin film of SnO2, either in amorphous (a-SnO2), crystalline (c-SnO2), or... 

Control input energy efficiency is an important issue which should be considered in designing any control system. Due to the importance of this subject, in the present paper fractional order control systems are studied in the viewpoint of control input energy efficiency. In this study, the divergent terms of the control input energy function of fractional order control systems are obtained. It is shown that these terms have a significant role in the amount of the energy injected to the plant by the controller. Finally, two examples are provided to demonstrate the usefulness of the presented results in the paper  

In this paper, the concept of minimal state space realization for a fractional order system is defined from the inner dimension point of view. Some basic differences of the minimal realization concept in the fractional and integer order systems are discussed. Five lower bounds are obtained for the inner dimension of a minimal state space realization of a fractional order transfer function. Also, the concept of optimal realization, which can be a helpful concept in practice, is introduced for transfer functions having rational orders. An algorithm is suggested to obtain the optimal realizations of rational order transfer functions. The introduced concept might be used to get minimal... 

In this paper, firstly a four-parameter fractional order model structure is introduced to approximate processes having S-shaped step responses. Three different strategies are presented in order to determine the parameters of the proposed model. In a special case where the proposed model is not satisfactory, another fractional order model structure with five free parameters is introduced to improve the model approximation. Also in this case, a procedure is provided to estimate the parameters of the introduced five-parameter model. Then, some common classical integer order control design approaches are modified or extended to their fractional order counterparts in order to incorporate the... 

Herein, a new dopant-free organic material, PV2000, as a stable hole transporting layer (HTL) for the fabrication of stable and efficient perovskite solar cells (PSCs) is introduced. For this purpose, planar PSCs using a triple-A cation perovskite composition are fabricated and the commonly used 2,2′,7,7′-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9′-spirobifluorene (spiro-OMeTAD) HTL is replaced by dopant-free PV2000 polymer. The characterization results disclose that the PV2000 has a great thermal stability, good hole mobility, and suitable band alignment that matches well with the valence band of triple-A cation perovskite. After proper optimization of PV2000 film thickness, a planar PSC... 

A new algorithm for the solution of multimaterial topology optimization problems is introduced in the present study. The presented method is based on the splitting of a multiphase topology optimization problem into a series of binary phase topology optimization sub-problems which are solved partially, in a sequential manner, using a traditional binary phase topology optimization solver; internal solver. The coupling between these incomplete solutions is ensured using an outer iteration strategy based on the block coordinate descend method. The presented algorithm provides a general framework to extend the traditional binary phase topology optimization solvers for the solution of multiphase... 

In this paper, an autonomous orbit control of a satellite in Low Earth Orbit is investigated using model predictive control. The absolute orbit control problem is transformed to a relative orbit control problem in which the desired states of the reference orbit are the orbital elements of a virtual satellite which is not affected by undesirable perturbations. The relative motion is modeled by Gauss's variational equations including J2 and drag perturbations which are the dominant perturbations in Low Earth Orbit. The advantage of using Gauss's variational equations over the Cartesian formulations is that not only the linearization errors are much smaller, but also each orbital element can be... 

Fractional order PI and PID controllers are the most common fractional order controllers used in practice. In this paper, a simple analytical method is proposed for tuning the parameters of these controllers. The proposed method is useful in designing fractional order PI and PID controllers for control of complicated fractional order systems. To achieve the goal, at first a reduction technique is presented for approximating complicated fractional order models. Then, based on the obtained reduced models some analytical rules are suggested to determine the parameters of fractional order PI and PID controllers. Finally, numerical results are given to show the efficiency of the proposed tuning...