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Investigation the Dependency of Surface Tension to Density and Temperature at Dense Systems
, M.Sc. Thesis Sharif University of Technology ; Parsafar, Gholamabbas (Supervisor)
Abstract
In this thesis heat transfer coefficient and temperature distribution of two Non-Newtonian and a Newtonian fluids in stirred vessel are investigated using Computational Fluid Dynamic (CFD). This vessel is agitated with new impeller called MAXBLEND. Non-Newtonian fluids are aqueous solutions of carboxymethyl cellulose 1.5%w/w and xanthan gum 3% w/w and Newtonian fluid is glycerin. This vessel is simulated in laminar regime with Reynolds number less than 14. The results of simulation are compared with correlation proposed by Kawase et al.
Furthermore as a new research for this impeller, the effects of vessel diameter and position of impeller in the vessel on heat transfer coefficient are...
Furthermore as a new research for this impeller, the effects of vessel diameter and position of impeller in the vessel on heat transfer coefficient are...
Measurement of Thermophysical Properties of Aqueous Solutions of Alkanolamine
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Siroos (Supervisor) ; Taghikhani, Vahid (Supervisor) ; Jalili, Amir Hossin (Supervisor)
Abstract
In this study, density, viscosity and surface tension of aqueous solution of Sulfolane, ( TEA+TMS+H2O) and (DIPA+TMS+H2O) systems were measured . Density, viscosity and surface tension were measured using pycnometer, Cannon – Fenske viscometer and Capillary rise method, respectively. Surface tension measurements of (DIPA+TMS+water) were carried out by the ring method using a LAUDR TD3 tensiometer,. The experiments were carried out in low concentrations and atmospheric pressure in the temperature range (70 - 30) . The obtained Data was modeled using empirical and thermodynamic models. Density calculation was done using the Setchenov and Redlich – Kister models.and the results indicated that...
Preparation of Nanofluid by Using Hybrid Nanostructures and Investigation of Thermal and Rheological Properties and Using it in the Petroleum Fluids
, M.Sc. Thesis Sharif University of Technology ; Rashtchian , Davood (Supervisor) ; Rashidi, Alimorad (Supervisor) ; Lotfi, Roghayeh (Co-Advisor)
Abstract
In this study, thermal and rheological properties of nanofluids of water/carbon nanotubes, water/spherical silica nanoparticles and water/hybrid nanoparticles (hybrid of carbon nanotubes and spherical silica nanoparticles) have been investigated. To do so, carbon nanotubes have been synthesized by CCVD process and spherical silica nanoparticles and hybrid nanoparticles by wet chemical method. After synthesis of nanomaterials, nanofluids have been prepared by using SDBS as a dispersant with the concentration of 1.5 times of concentration of nanomaterials and then thermal conductivity, kinematic viscosity, dynamic viscosity and density of nanofluids have been investigated. As the results show,...
Thermodynamic Properties of Aqueous Electrolyte Solutions Containing Urea
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Siroos (Supervisor) ; Taghikhani, Vahid (Supervisor)
Abstract
The behavior of biomolecules in mixtures is affected by the presence of electrolytes. For instance, in the presence of an electrolyte, solubility of most biomolecules like proteins,peptids and amino acids can be increased or decreased. As a biomolecule, urea is a protein denaturant and influences protein folding and protein-DNA binding. The presence of ions can affect the interactions between urea and water In this thesis, experimental data of density and electrical conductance of aqueous solutions of urea-NaCl were obtained at different physical conditions. Density measurement experiments were carried out at different temperatures from 20-40 oC. Apparent and infinite dilution molar volumes...
Chaotic Network Flows in an Evolutionary Model of Traffic Assignment Based on Speed and Density
, M.Sc. Thesis Sharif University of Technology ; Poorzahedy, Hossein (Supervisor)
Abstract
Chaotic Flow in transportation networks has been the subject of several studies. Evolutionary models have been employed to simulate traffic flows. This study takes advantage of an existing evolutionary model of traffic assignment to show that chaotic phenomena arise when the model’s driving force is speed or density, of traffic flow. It has been observed that drivers show higher sensitivity when the network is more loaded.
Design of a Ultrasonic system for a Multi-purpose Production Logging Tool (PLT)
, M.Sc. Thesis Sharif University of Technology ; Movahhedian Attar, Hamid (Supervisor)
Abstract
In the oil industry, a better understanding of the well condition leads to improve the management and increase the oil production. Production logging tools is a set of tools for measuring different parameters such as density, diameter and flow in oil and gas wells. These tools are considered among high-tech tools in the oil industry. The reason is that they should work in harsh conditions, i.e. high temperature about 170 ° C and pressure around 15000 psi, and at the same time give an accurate measurement of the quantity. Current production-logging tools measure the fluid velocity and the diameter of an oil well by individual mechanical tools, and the density by a radioactive densitometer. ...
Synthesis of Mn1.5Co1.5O4 by Solid State Raction for SOFC Interconnect Applications
, M.Sc. Thesis Sharif University of Technology ; Faghihi Sani, Mohammad Ali (Supervisor) ; Nemati, Ali (Supervisor)
Abstract
Interconnects in SOFC’s has oxidation problems which is Because of high temperature operation. Also Cr migration to cathode make chroumiom poisoning problems and all of this affects SOFC’s efficiency. To solve this problem researchers decided to use some protective coating on interconnect. The best group of coatings is Mn-Co Spinels. In this thesis (Mn,Co)3O4 spinels was synthesized via solid state reaction. MC reffered to Mn1.5Co1.5O4 was calcined at 850°C and then sintered at 1200°C. It’s electrical conductivity measured by 4-point probe DC method. It had the lowest ASR (17mΩ.cm2) among other stochiometries. To reduce the sintering temperature, Cu and Y was added as dopants. Among the...
Determination of Solubility and Density in Acidic Gas Absoption Systems by Ionic Liquids by Means of Cubic Equations of State
, M.Sc. Thesis Sharif University of Technology ; Ghotbi, Cyrus (Supervisor) ; Jalili, Amir Hossein (Supervisor)
Abstract
Due to their low volatility, negligible flammability, and high regeneration capacity, ionic liquids have attracted a lot of attention in chemical and process engineering fields. Regarding the limited access to the laboratory facilities, developing theoretical methods such as equations of state is important in this research field. Thus, data for density and viscosity of pure ionic liquids and vapor pressure data for binary mixtures of ionic liquids and acidic gas have been collected and validated from the IL Thermo website for 42 ionic liquids. By consideration of theoretical studies and comparison of the performance of different cubic equations of state in predicting the aforementioned...
Estimating the Amount of Evaporation, Salinity, Precipitation and Dissolution of Salt on Lake Urmia
, M.Sc. Thesis Sharif University of Technology ; Tajrishy, Masoud (Supervisor)
Abstract
Lake Urmia is the largest hypersaline lake in Iran, as well as a significant aquatic habitat. In recent decades, extreme increasing of extent plans and exploitation of water resources in this basin, cause decreasing inflow, water level and creating several environmental and economic issues. In recent decades, the excessive expansion in the development and exploitation of this basin's water resources has resulted in a drop in the flows into the lake, a decline in the lake's water level, and the creation of several environmental and economic issues. In recent years, these stressors have caused the lake's salinity to exceed 400 g/L, and salt deposits have emerged on the lake bottom and...