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Molecular dynamics simulation of orientation dependency in the shock-induced phase transition of C60 fullerene single crystals into amorphous diamond

Mahnama, M ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1080/01411594.2013.803286
  3. Abstract:
  4. A molecular dynamics simulation of the shock-wave propagation in the face-centered cubic (FCC) structured C60 fullerene along the <100>, <110> and <111> crystallographic directions is performed. For this purpose, the response of the material under different shock-wave loadings is studied through Hugoniot curves. Three regimes of the material behavior have been observed from fully elastic to elastic-plastic to plastic. The Hugoniot elastic limit and the phase transition are also investigated along different crystallographic directions. It is shown that the shock wave travels faster along the <110> and <111> directions than in the <100> direction in the material. Comparing the results with the experimental data, it is found that the trends of the Hugoniot data are the same as the experiments. Also, the piston velocities corresponding to different structures, such as the FCC C60 fullerene, graphite like and final diamond like, are determined based on the Hugoniot results. Moreover, it is shown that after the phase-transition occurrence, at high piston velocities the material responses along the low-index directions merge with each other; thus, an amorphous structure is expected for the final diamond-like phase
  5. Keywords:
  6. Amorphous diamond ; C60 fullerene ; Hugoniot curve ; Molecular dynamics simulations ; Phase transition ; Shock-wave transmission ; Diamonds ; Elastoplasticity ; Molecular dynamics ; Phase transitions ; Pistons ; Shock waves ; Single crystals ; Amorphous structures ; C60 fullerenes ; Crystallographic directions ; Face-centered cubic ; Hugoniot elastic limit ; Orientation dependencies ; Fullerenes
  7. Source: Phase Transitions ; Vol. 87, Issue. 3 , 2014 , Pages 271-285 ; ISSN: 01411594
  8. URL: http://www.tandfonline.com/doi/abs/10.1080/01411594.2013.803286#.VeLi2H01rcs