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The role of reactants and droplet interfaces on nucleation and growth of ZnO nanorods synthesized by vapor-liquid-solid (VLS) mechanism
Hejazi, S. R ; Sharif University of Technology | 2008
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- Type of Document: Article
- DOI: 10.1016/j.jallcom.2007.01.100
- Publisher: 2008
- Abstract:
- Short ZnO nanorods and long ZnO nanowires have been produced on SiO2 and Si substrates by VLS and VS mechanisms via a double tube chemical vapor transport and condensation (CVTC) process. The role of reactants and droplet interfaces on the nucleation and growth of ZnO nanorods have been investigated. A conceptual model for nucleation of ZnO nanorods has been proposed by describing the half-oxidation and reduction reactions at the growth front. The importance of Zn vapor in the nucleation phenomena has been studied by changing starting materials. Atomic force microscopy (AFM), scanning electron microscopy (SEM), and EDX analysis have been used to characterize ZnO nanorods and investigate the nucleation model. © 2007 Elsevier B.V. All rights reserved
- Keywords:
- Chemical vapor deposition ; Condensation ; Drops ; Mathematical models ; Nucleation ; Zinc oxide ; Chemical vapor transport ; Conceptual models ; Reactants ; Nanorods
- Source: Journal of Alloys and Compounds ; Volume 455, Issue 1-2 , 2008 , Pages 353-357 ; 09258388 (ISSN)
- URL: https://www.sciencedirect.com/science/article/abs/pii/S0925838807001582