Loading...

A new and highly effective method for catalytic oxidation of alcohols to the corresponding carbonyl compounds using the tris[(2-oxazolinyl)phenolato] manganese(III)/Oxone®/n-Bu4NBr oxidation system

Bagherzadeh, M ; Sharif University of Technology | 2003

185 Viewed
  1. Type of Document: Article
  2. DOI: 10.1016/j.tetlet.2003.10.018
  3. Publisher: Elsevier Ltd , 2003
  4. Abstract:
  5. Oxone® (2KHSO5·KHSO4·K 2SO4) in the presence of mer-tris[(2-oxazolinyl)phenolato] manganese(III), Mn(phox)3, as catalyst under biphasic reaction conditions (CH2Cl2/H2O) and tetra-n-butylammonium bromide as phase transfer agent efficiently oxidises alcohols to their corresponding aldehydes and ketones at room temperature with very short reaction times (5 min) and good to quantitative yields. © 2003 Elsevier Ltd. All rights reserved
  6. Keywords:
  7. Alcohol ; Catalytic oxidation ; Mn-oxazoline complex ; Oxone®
  8. Source: Tetrahedron Letters ; Volume 44, Issue 50 , 2003 , Pages 8943-8945 ; 00404039 (ISSN)
  9. URL: https://www.sciencedirect.com/science/article/abs/pii/S0040403903024298