Sharif Digital Repository

Temporal and spatial analysis of dynamics of hybrid transversely excited atmospheric pressure (TEA)-CO2 lasers is studied using two different models with four and eight energy levels. These models are used for simulation of the laser and computing the output energy. Effects of several parameters such as input energies and gas mixture concentrations (especially presence of CO molecules) are also studied. © 2007 Elsevier Ltd. All rights reserved  

Three-dimensional analysis of combustion chambers in industrial gas turbines suffers from lack of simple and accurate reduced mechanisms for oxidation of hydrocarbon fuels. Here, an integrated procedure is introduced based on a differential evolution optimization technique. The procedure is flexible and modular and allows optimization of many rate parameters of a multistep global mechanism based on many different combustion criteria and inlet or operational conditions. The procedure uses any selected chemical reactor model and any reference combustion mechanism provided. Sample design criteria used here are flame temperature, ignition delay time, and concentration of selected species,... 

Numerous studies yet have been carried out on downscaling of the large-scale climate data using both dynamical and statistical methods to investigate the hydrological and meteorological impacts of climate change on different parts of the world. This study was also conducted to investigate the capability of feedforward neural network with error back-propagation algorithm to downscale the provincial segmentation of Iran (30 provinces) on a daily scale. This model was proposed for the downscaling daily temperature, precipitation and wind speed data, and it was calibrated and verified by using the daily outputs derived from the National Center for Environmental Prediction (NCEP) database... 

Platinum extraction from spent reforming catalysts in iodine solutions under atmospheric pressure and at temperatures up to 95°C was previously investigated in our group. In this system, platinum is oxidized from the spent catalyst with tri-iodide. In some of the experiments, it was observed that platinum extraction peaked and then decreased. This indicates that a precipitation reaction slowly occurs that removes the dissolved Pt ions from the solution. Power-law rate equation for the Pt extraction to PtI6 2- and the precipitation of the dissolved platinum to PtI 4(s) was implemented to model the experimental Pt extraction data. The activation energies for the platinum dissolution reaction... 

Densities and viscosities of aqueous solutions containing sulfolane and ternary aqueous solutions of sulfolane and triethanolamine and ternary aqueous solutions containing sulfolane and disopropanolamine and also equilibrium surface tensions of the above ternary aqueous solutions were measured at temperatures ranging from (303.15 to 343.15) K and atmospheric pressure. The overall concentration of sulfolane, triethanolamine, and diisopropanolamine in solutions varied in the range of 0 to 16.5, 0 to 43, and 0 to 40 mass percent, respectively. Using the density, viscosity, and surface tension of pure water as the solvent, the corresponding experimental values obtained for the investigated... 

(Liquid + liquid) equilibrium (LLE) data for the ternary systems (heptane + toluene + 1-ethyl-3-methylpyridinium ethylsulfate) and (heptane + benzene + 1-ethyl-3-methylpyridinium ethylsulfate) were measured at T = 298.15 K and atmospheric pressure. The selectivity and aromatic distribution coefficients, calculated from the equilibrium data, were used to determine if this ionic liquid can be used as a potential extracting solvent for the separation of aromatic compounds from heptane. The consistency of tie-line data was ascertained by applying the Othmer-Tobias and Hand equations  

This paper proposes an artificial pheromone communication system inspired by social insects. The proposed model is an extension of the previously developed pheromone communication system, COS-Φ. The new model increases COS-Φ flexibility by adding two new features, namely, diffusion and advection. The proposed system consists of an LCD flat screen that is placed horizontally, overhead digital camera to track mobile robots, which move on the screen, and a computer, which simulates the pheromone behaviour and visualises its spatial distribution on the LCD. To investigate the feasibility of the proposed pheromone system, real micro-robots, Colias, were deployed which mimicked insects' role in... 

Microbial EOR (MEOR) is receiving renewed interest worldwide. The method is based on microorganisms' activities to reduce residual oil of reservoirs, which is dependent on behavior of inherent microorganisms or injection of bioproduct of external microorganisms. Five bacterial species were taken from MIS crude oil that is one of the aging Persian fractured reservoirs. Visualization experiments were carried out to examine the behavior of MEOR in micromodels designed to resemble the fractured system: static and dynamic. A new surface sample of the MIS oil was taken at the well head and physical specifications were measured at the lab. This was fairly light oil with API gravity of 42.5. The... 

A unique combination of a supported cobalt complex and the first example of supported NHPI in acetic acid gives a surprisingly stable heterogeneous catalytic system for the selective aerobic oxidation of methylaromatics to benzaldehydes at atmospheric pressure. © The Royal Society of Chemistry 2005  

Controlled growth of atomic monolayers of IV-VII transition metal dichalcogenides (TMDs) has provided unprecedented opportunities to fabricate modern optoelectronic nanodevices. However, synthesis of large-area and high quality two-dimensional TMDs is still challenging. We have synthesized WS2 and MoS2 nanosheets by atmospheric pressure chemical vapor deposition (APCVD) at wide-range of processing conditions. The nanostructures were analyzed by optical and confocal microscopy, atomic force microscopy, Raman spectroscopy, and X-ray diffraction to determine the thickness, lateral size and structure of the deposits. Through designing and performing of a set of controlled experiments as well as... 

A solar natural vacuum desalination system was experimentally investigated. Using a barometric water column and creating an equilibrium with atmospheric pressure and gravity, vacuum conditions were maintained inside the evaporation chamber throughout the day, which led to the beginning of evaporation at lower temperatures and as a result, lower energy consumption compared to conventional methods. Solar evacuated tubes were used to more efficiently absorb solar radiation and raise the temperature of saline water. In addition, at the system startup, a vacuum pump was utilized to fill the water column and create vacuum conditions. Then, the existing vacuum in the system was maintained naturally... 

In this paper, the Heidaryan and Jarrahian equation of state (Heidaryan and Jarrahian, 2013) has been adapted as a first worldwide cubic EOS to calculate the density of dry natural gases, wet natural gases, and single-phase gas condensates "sweet and sour mixtures" (up to 73.85, 97.63 and 38.37 mol percent of H2S, CO2, and N2 respectively) even when the gas composition is unknown, through new gas specific gravity correlation equations. Correction terms of water content as high as 10 mol percent of H2O and hythane (natural gas + hydrogen) as high as 74.9 mol percent of H2 were obtained. The equation of state was validated with 8985 experimental compressibility factor data points from 308... 

Carbon dioxide sequestration by a pH-swing carbonation process was considered in this work. A multi-step aqueous process is described for the fractional precipitation of magnesium carbonate and other minerals in an aqueous system at room temperature and atmospheric pressure. With the aim to achieve higher purity and deliver more valuable mineral products, the process was split into four steps. The first step consists of Mg leaching from the magnesium silicate in a stirred vessel using 1 M HCl at 80 °C, followed by a three step precipitation in reactors in sequence to remove Fe(OH)3, then Fe(OH)2 and other divalent ions, and finally MgCO3 nucleation and growth. Hydrated magnesium carbonate... 

A reduction in catalyst's activity with time-on-stream and the formation of side products are two of the problems associated with catalytic propane dehydrogenation (PDH). Previous studies have indicated that the presence of small amounts of oxygenated additives such as water can reduce coke formation and enhance catalyst activity. The aim of the present work was to develop an appropriate kinetic model for PDH over a commercial Pt-Sn/γ-Al 2O3 catalyst in the presence of small amounts of water. Experimental data were obtained from a previous study where catalytic PDH was carried out in a bench scale reactor system at atmospheric pressure in the temperature range of 575-620°C in the presence of... 

Propane dehydrogenation was carried over a commercial Pt-Sn/γ-Al 2O3 catalyst at atmospheric pressure and reaction temperatures of 580, 600, and 620°C and WHSV of 11 h-1 in an experimental tubular quartz reactor. Propane conversions were measured for catalyst time on stream of up to nine days. The amounts of coke deposited on the catalyst were measured after one, three, six, and nine days on stream using a thermogravimetric differential thermal analyzer (TG-DTA) for each reaction temperature. The coke formation kinetics was successfully described by a coke formation model based on a monolayer-multilayer mechanism. In addition, catalyst deactivation was presented by a time-dependant... 

In this paper, a nonlinear model is used to analyze the dynamic pull-in instability and vibrational behavior of a microcantilever gyroscope. The gyroscope has a proof mass at its end and is subjected to nonlinear squeeze film damping, step DC voltages as well as base rotation excitation. The electrostatically actuated and detected microgyroscopes are subjected to coupled flexural-flexural vibrations that are related by base rotation. In order to detune the stiffness and natural frequencies of the system, DC voltages are applied to the proof mass electrodes in drive and sense directions. Nonlinear integro differential equations of the system are derived using extended Hamilton principle... 

In this paper, the effects of different parameters on the hairiness of siro-jet spun yarns, such as the nozzle pressure, the distance between the front roller nip and inlet of the nozzle, and jet structure were investigated. Using the Taguchi method, it was concluded that the factor air pressure has the strongest effect and the factor distance between the front roller nip and inlet of the nozzle does not have a significant effect on the performance of the siro-jet spinning system in reducing yarn hairiness. A computational fluid dynamics model was developed to simulate the airflow pattern inside the jets. The effect of air pressure and the jet structure was simulated using Fluent 6.3... 

Liquid-liquid equilibrium (LLE) data for the ternary systems (heptane. +. p-xylene. +. 1-ethyl-3-methylpyridinium ethylsulfate) and (n-octane. +. p-xylene. +. 1-ethyl-3-methylpyridinium ethylsulfate) were measured at . T=. 313.15. K and atmospheric pressure. The selectivity and aromatic distribution coefficients, calculated from the equilibrium data, were used to determine if this ionic liquid can be used as a potential extracting solvent for the separation of p-xylene from heptane and n-octane. The consistency of tie-line data was ascertained by applying the Othmer-Tobias and Hand equations