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Synthesis, characterization and application of magnetic room temperature dicationic ionic liquid as an efficient catalyst for the preparation of 1,2-azidoalcohols

Godajdar, B. M ; Sharif University of Technology | 2013

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  1. Type of Document: Article
  2. DOI: 10.1016/j.molliq.2013.03.022
  3. Publisher: 2013
  4. Abstract:
  5. An environmentally benign, aqueous synthesis of 1,2-azidoalcohols via regioselective ring opening of their epoxides using magnetic imidazolium based dicationic room temperature ionic liquid, [pbmim](FeCl4)2, as an efficient magnetic phase transfer catalyst in water has been described. The present approach offers the advantages of clean reaction, simple methodology, short reaction time, high yield, easy purification and reusable catalyst
  6. Keywords:
  7. Magnetic room temperature dicationic ionic liquid ; 1,2-azidoalcohols ; Dicationic ionic liquids ; Dicationic room temperature ionic liquids ; Efficient catalysts ; Environmentally benign ; Green chemistry ; Regio-selective ; Regioselective ring opening ; Catalysts ; Computer software reusability ; Regioselectivity ; Synthesis (chemical) ; Ionic liquids
  8. Source: Journal of Molecular Liquids ; Volume 183 , 2013 , Pages 14-19 ; 01677322 (ISSN)
  9. URL: http://www.sciencedirect.com/science/article/pii/S0167732213001037