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Experimental study and mathematical modeling of asphaltene deposition mechanism in core samples

Jafari Behbahani, T ; Sharif University of Technology | 2015

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  1. Type of Document: Article
  2. DOI: 10.2516/ogst/2013128
  3. Publisher: Editions Technip , 2015
  4. Abstract:
  5. In this work, experimental studies were conducted to determine the effect of asphaltene deposition on the permeability reduction and porosity reduction of carbonate, sandstone and dolomite rock samples using an Iranian bottom hole live oil sample which is close to reservoir conditions, whereas in the majority of previous work, a mixture of recombined oil (a mixture of dead oil and associated gas) was injected into a core sample which is far from reservoir conditions. The effect of the oil injection rate on asphaltene deposition and permeability reduction was studied. The experimental results showed that an increase in the oil injection flow rate can result in an increase in asphaltene deposition and permeability reduction. Also, it can be observed that at lower injection flow rates, a monotonic decrease in permeability of the rock samples can be attained upon increasing the injection flow rate, while at higher injection rates, after a decrease in rock permeability, an increasing trend is observed before a steady-state condition can be reached. The experimental results also showed that the rock type can affect the amount of asphaltene deposition, and the asphaltene deposition has different mechanisms in sandstone and carbonate core samples. It can be seen that the adsorption and plugging mechanisms have a more important role in asphaltene deposition in carbonate core samples than sandstone core samples. From the results, it can be observed that the pore volumes of the injected crude oil are higher for sandstone cores compared with the carbonate cores. Also, it can be inferred that three depositional types may take place during the crude oil injection, i.e., continuous deposition for low-permeability cores, slow, steady plugging for high-permeability cores and steady deposition for medium-permeability cores. It can be seen from the experimental results that damage to the core samples was found to increase when the production pressures were increased. The experimental results show that the amount of remaining asphaltene in carbonate core samples is higher than those in sandstone core samples. Also, SEM (Scanning Electron Microscopy) micrographs of carbonate core samples showed the formation of large clusters of asphaltene in comparison with sandstone core samples during natural depletion. It can be seen from the modeling results that the proposed model based on the multilayer adsorption equilibrium mechanism and four material balance equations is more accurate than those obtained from the monolayer adsorption equilibrium adsorption mechanism and two material balance equations, and is in agreement with the experimental data of natural depletion reported in this work and with those reported in the literature
  6. Keywords:
  7. Adsorption ; Adsorption isotherms ; Asphaltenes ; Carbonation ; Crude oil ; Deposition ; Mixtures ; Petroleum reservoir engineering ; Rocks ; Sandstone ; Scanning electron microscopy ; Asphaltene deposition ; Continuous deposition ; Material balance equation ; Permeability reduction ; Reservoir conditions ; Steady-state condition ; Core samples ; Carbonate ; Dolomite ; Experimental study ; Numerical model ; Permeability ; Porosity ; Iran
  8. Source: Oil and Gas Science and Technology ; Volume 70, Issue 6 , Nov , 2015 , Pages 1051-1074 ; 12944475 (ISSN)
  9. URL: http://ogst.ifpenergiesnouvelles.fr/articles/ogst/abs/2015/06/ogst120001/ogst120001.html