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First-principles study on lattice instabilities and structural phase transitions in Ba doped La2CuO4

Tavana, A ; Sharif University of Technology | 2015

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  1. Type of Document: Article
  2. DOI: 10.1016/j.physc.2015.07.001
  3. Publisher: Elsevier , 2015
  4. Abstract:
  5. We present linear-response density-functional theory calculations for the high-Tc superconductor La2-xBaxCuO4 to study the doping dependence of phonon dispersion. Using the virtual crystal approximation, the doping range up to x = 0.20 is investigated. We find unstable phonon modes that soften around high-symmetry points of the Brillouin zone. These branches are analyzed as a function of doping and pressure. The structural distortions related to these phonons are in accordance with the observed phase transitions from the high-temperature tetragonal (HTT) phase to the low-temperature orthorhombic (LTO) and the low-temperature tetragonal (LTT) phases. The calculated tilting angles of the CuO6 octahedra corresponding to these phases are in good agreement with experiment. Our findings confirm that strong electron correlations have only minor impact on the structural properties of high-Tc cuprates
  6. Keywords:
  7. Cuprate superconductors ; Acoustic dispersion ; Calculations ; Copper compounds ; Dispersions ; Doping (additives) ; High temperature superconductors ; Oxide superconductors ; Phonons ; Strain measurement ; Superconducting materials ; Temperature ; Density functionals ; First-principles study ; High-symmetry points ; Phonon dispersions ; Strong electron correlations ; Structural distortions ; Structural phase transition ; Virtual crystal approximation ; Density functional theory
  8. Source: Physica C: Superconductivity and its Applications ; Volume 517 , October , 2015 , Pages 20-25 ; 09214534 (ISSN)
  9. URL: http://www.sciencedirect.com/science/article/pii/S0921453415002221