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The possibilities of palladium-catalyzed aromatic cyanation in aqueous media

Vafaeezadeh, M ; Sharif University of Technology

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  1. Type of Document: Article
  2. DOI: 10.1016/j.inoche.2016.08.014
  3. Publisher: Elsevier
  4. Abstract:
  5. Owing to the inherent incompatibility with water, cyanation of aryl halides may be the most challenging category of palladium-catalyzed coupling reactions. The major challenges are attributed to the catalyst deactivation by the soluble cyanide (CN−) ions and desirable conversions only could be obtained by employing toxic organic solvents. The current minireview highlights mechanistic insights and breakthrough achievements for this reaction in the aqueous media
  6. Keywords:
  7. Coupling reactions ; Cyanation ; Green synthesis ; Palladium ; Water
  8. Source: Inorganic Chemistry Communications ; Volume 72 , 2016 , Pages 86-90 ; 13877003 (ISSN)
  9. URL: http://www.sciencedirect.com/science/article/pii/S1387700316302702