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Application of the MSA-based models in correlating the surface tension for single and mixed electrolyte solutions

Sadeghi, M ; Sharif University of Technology | 2009

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  1. Type of Document: Article
  2. DOI: 10.1016/j.jct.2009.05.014
  3. Publisher: 2009
  4. Abstract:
  5. Experimental values for surface tension of single and mixed electrolyte solutions were correlated using the models based on the perturbation theory. The Mean Spherical Approximation (MSA) model, coupled with the Ghotbi-Vera (GV) and the Mansoori et al. (BMCSL) equations of state, were used to correlate the experimental values of the surface tension. The results showed that the models can favourably correlate the experimental values for single electrolyte solutions. However, it was observed that the GV-MSA model can more accurately predict the surface tension for single electrolytes, especially at higher concentrations. Two different expressions for concentration dependency of cation hydrated diameters were used. Therefore, in terms of such dependency different forms of the models, i.e., GV-MSA1, GV-MSA2, BMCSL-MSA1 and BMCSL-MSA2 were introduced. It should be stated that the prediction of the surface tension for the mixed electrolyte solutions were made without introducing any new adjustable parameters. The results showed that GV-MSA2 model can predict more accurately the surface tension of electrolyte mixtures particularly at higher concentrations. Finally, the GV-MSA model was directly used to correlate the experimental results for the surface tension for both single and mixed electrolyte solutions with 2 and 4 adjustable parameters. The results showed that both of the models can accurately predict the experimental data of surface tension. These models can favourably fit and also, predict the surface tension of single electrolyte solutions with less than 1% average absolute relative deviation (AARD). The prediction capability of the proposed models is also acceptable for mixtures of electrolytes. © 2009 Elsevier Ltd. All rights reserved
  6. Keywords:
  7. Adjustable parameters ; Average absolute relative deviations ; Electrolyte mixtures ; Electrolyte solution ; Electrolyte solutions ; Experimental data ; Experimental values ; Mean spherical approximation ; Mean Spherical Approximation (MSA) ; Mixed electrolyte solutions ; Perturbation theory ; Prediction capability ; Capillarity ; Electrolysis ; Equations of state ; Hydrates ; Perturbation techniques ; Spheres ; Surface chemistry ; Surface properties ; Surface tension ; Surface waves ; Wetting ; Electrolytes
  8. Source: Journal of Chemical Thermodynamics ; Volume 41, Issue 11 , 2009 , Pages 1264-1271 ; 00219614 (ISSN)
  9. URL: https://www.sciencedirect.com/science/article/pii/S0021961409001256