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    Effect of Nitrogen Addition on the Microstructure and Mechanical Properties of a Pearlitic Matrix Gray Cast Iron

    , M.Sc. Thesis Sharif University of Technology Kamoori Yousefabad, Elham (Author) ; Davami, Parviz (Supervisor)
    Abstract
    Gray Cast Irons are the most important engineering Cast Irons. Gray color of fracture surface and morphology of graphite flakes are the reasons of this naming. Gray iron is relatively cheap with easy production; because of wide chemical composition range rather other cast irons. Furthermore, shrinkage and feeding in the casts from gray iron, besides surface finishing by machining are easy. The other properties of gray iron are resistance against sliding wear, high thermal conduction coefficient, low module of elasticity and thermally shock resistance. In this research, the effects of added nitrogen as an alloying element and cooling rate on microstructure, hardness and tensile properties of... 

    Static Melt Crystallizer Simulation and Design with CFD

    , M.Sc. Thesis Sharif University of Technology Karimzadeh Sureshjani, Hamed (Author) ; Farhadi, Fathollah (Supervisor) ; Pishvaei, Mahmood Reza (Supervisor)
    Abstract
    Layer melt crystallization is one of the most attractive and productive separation methods in the chemical industry. One of the most important coal tar components, which is present in concentration between 10 to 12% is naphthalene. One of the most commonly used techniques for producing naphthalene crystallization. In this thesis, the layer melt crystallization in a mixture of naphthalene and benzothiophene has been investigated using computational fluid dynamics. The simulation of crystallization was performed in Comsol Multiphisics version 5.6 and the thickness of the crystal layer was obtained according to the time. At first, simulation results were verified with the labroratory results of... 

    Investigation on the Influence of Cooling Rate on Microstructure of CuCr25% Melt-spun Alloy

    , M.Sc. Thesis Sharif University of Technology Nadi Mobarakeh, Elham (Author) ; Varahram, Nasser (Supervisor) ; Davami, Parviz (Supervisor)
    Abstract
    The Cu-Cr10% ingots were prepared in induction furnace and these ingots were used to prepare CuCr25% in VAR. The percentages of elements were checked by chemical analysis. The ingots were divided to slices with 20gr mass and these slices were put in quartz tubes. The quartz tubes were assembled in melt spinning machine and the ribbons were quenched onto a rotating copper wheel. Three different wheel speeds, 8, 16, 36 m/s were chosen. The microstructure of the ribbons was examined using a scanning electron microscopy (SEM). The relationship between wheel speed and thickness of the ribbons were compared with mathematical modeling. The disk of ribbons with thickness of 0.5mm and radius of 5mm... 

    Experimental Study and Finite Element Modeling of the Effect of Microstructure on Fracture Behavior and Fracture Load Prediction of Solder Joints

    , M.Sc. Thesis Sharif University of Technology Mohammadi Amiri, Mostafa (Author) ; Farrahi, Gholamhossein (Supervisor) ; Nourani, Amir (Supervisor)
    Abstract
    The critical strain energy release rate for the solder joint fracture was measured as a function of cooling rate, time above liquidus (TAL) and soldering temperature. The specimens were prepared at 4 different levels of cooling rate, 3 varying levels of TAL, and 3 soldering temperature levels. Then, experiments were designed using the Taguchi method. Fracture tests were performed under bending at a strain rates of 10-5 and 0.5 s-1 and mode I loading conditions. It was found that the effect of soldering temperature insignificant on the Jci, but the cooling rate and the TAL due to their many effects were also studied by their interaction effects. It was observed that at the cooling rate of... 

    The Effect of Cooling Rate and Heat Treatment on An Al-4.5% Cu Alloy

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Hesam (Author) ; Varahram, Naser (Supervisor)
    Abstract
    Al-4.5% Cu alloy, an age-hardenable alloy, is an important alloy in industry due to such unique characteristics as high strength-to-weight ratio and considerable strength at elevated temperatures. In this study, the aim was to evaluate the combined effect of cooling rate and heat treatment on an A206 alloy having more impurities—especially iron—than the nominal specifications. To this end, the melt was poured in a five-step mold. Afterwards, each step was subjected to T4 and T6 treatments in order to study the changes compared to the as-cast samples. Ultimate tensile strength, yield strength, elongation, and grain size were determined by using tensile tests and optical microscopy,... 

    Investigation on the Effect of Cooling Rate on the Solidification Behavior and Microstructure of Al 713 alloy using Thermal Analysis Technique

    , M.Sc. Thesis Sharif University of Technology Abbasi, Mohammad Hossein (Author) ; Varahram, Nasser (Supervisor)
    Abstract
    Considering the limited number of works on investigation of solidification characteristics of Al-Zn-Mg-Cu cast alloys as well as the applications of this alloy system in aerospace industries, the solidification conditions of Al 713 alloy were investigated in this study. In order to achieve this goal, a number of experiments were designed and conducted including quantometry, thermal analysis, metallography and hardness measurements. In this thesis, effects of cooling rate on secondary dendritic arms spacing as well as solidification parameters including nucleation temperature, solidification time and temperature range, dendrite coherency point and formation temperature of intermetallic... 

    Simulation of the Effect of Cooling Rate and Chemical Composition on the Atomic Structure of Bulk Metallic Glass Iron-Phosphorus and Nickel-Phosphorus

    , M.Sc. Thesis Sharif University of Technology Hosseinzadeh, Danial (Author) ; Tavakoli, Rouhollah (Supervisor)
    Abstract
    bulk metallic glass Unlike metal materials that have a crystalline structure, amorphous glass is an amorphous material with an irregular atomic structure that simultaneously has the same physical properties as metals. Due to the absence of crystal defects such as dislocation and grain boundaries, these materials show unique mechanical properties such as high strength and elastic strain, abrasion resistance and proper corrosion. However, their plastic deformation is heterogeneous, concentrated, and accompanied by sudden failure. Unlike metals, these materials do not have a long-range crystalline order, and their atomic structure includes short-range and mid-range order. The short-range order... 

    Effect of Grain Refining, Cooling Rate and Modification on Shrinkage Porosities in A356 Aluminum Alloy

    , M.Sc. Thesis Sharif University of Technology Hajizadeh Bidgoli, Ali (Author) ; Varahram, Naser (Supervisor)
    Abstract
    In this study, the influence of eutectic modification, grain refining and cooling rate on amount of shrinkage porosity in aluminium A356 alloy were investigated. Modification process for changing the morphology of eutectic silicon from needle like to fibrous like, use in aluminium – silicon alloys. This process often leads to increasing porosity in melt and affect harmfully on mechanical properties. For studying shrinkage porosity, the melt degassed completely to minimizing amount of gas in the melt. For modification, strontium in Al-10Sr master alloy and sodium in NaF salt used and for grain refining Al-10Ti and Al-5Ti-1B master alloys used. To study the effect of cooling rate, three mold... 

    Physical Modeling of Microstructure in Gray Cast Iron

    , M.Sc. Thesis Sharif University of Technology Jabbari Behnam, Mir Masoud (Author) ; Davami, Parviz (Supervisor) ; Varahram, Naser (Supervisor)
    Abstract
    The aim of this project is simulation of microstructure and prediction of microstructural length scales in gray cast iron. To attain this, the Fourier heat transfer equations have been solved in a simple domain by FDM (Finite Difference Method), and both thermal distribution and cooling rate were obtained. By coupling experimental results and numerical methods, a model developed for predicting primary and secondary dendrite arm spacing, thickness of eutectoid layers and graphite, and fraction of graphite, cementite and austenite. Besides this model predicts the ultimate tensile strength and Hardness Brinel. Another approach in this project is a new and simple computational method for... 

    Effect of Chemical Composition on Atomic Structure and Mechanical Properties of Mg-Zn Glass Alloys Using Molecular Dynamics Simulation

    , M.Sc. Thesis Sharif University of Technology Asl Roosta, Pouneh (Author) ; Tavakoli, Rohollah (Supervisor)
    Abstract
    In this research, Mg-Zn bulk metallic glasses have been investigated using molecular dynamics simulation. In order to study the structure of this alloy, coordination number, short and medium order of chemical range, Voronoi analysis, glass conversion temperature and atomic pair distribution function have been used. According to the results, the full icosahedral structure with IS connection type in comparison with other structures has an essential role in the stability of the system during cooling and creating medium-scale areas. The results show that the ability to form glass depends on the chemical composition and cooling rate. In this research, the cooling rate is considered to be 1011 K/s... 

    Modeling the microstructural evolution and effect of cooling rate on the nanograins formed during the friction stir processing of Al5083

    , Article Materials Science and Engineering A ; Volume 527, Issue 1-2 , 2009 , Pages 192-197 ; 09215093 (ISSN) Yazdipour, A ; Shafiei M., A ; Dehghani, K ; Sharif University of Technology
    Abstract
    An analytical model is developed to study the effect of cooling rate on the final grain size of stirred zone of the Al5083 subjected to friction stir processing. The effect of cooling rate on the grain size of the stirred zone was investigated experimentally and numerically. A new microstructural evolution model was also suggested illustrating the mechanisms contributed in refining the microstructure. A new mechanism termed meta-dynamic recovery (MDRV) is introduced here in this regard. The simulation results also show that the rapid cooling rate resulted in superior mechanical properties through refining the microstructure of the stirred zone. However, decreasing the rotational speed and... 

    Molecular dynamics simulation of melting, solidification and remelting processes of aluminum

    , Article Iranian Journal of Science and Technology - Transactions of Mechanical Engineering ; Volume 36, Issue M1 , 2012 , Pages 13-23 ; 22286187 (ISSN) Solhjoo, S ; Simchi, A ; Aashuri, H ; Sharif University of Technology
    2012
    Abstract
    A molecular dynamics simulation study has been performed to investigate the solidification and remelting of aluminum using Sutton-Chen many body potential. Different numbers of atoms from 108 to 2048 atoms were considered to find an adequate size for the system. Three different cooling and heating rates, i.e. 10 12 K/s, 10 13 K/s and 10 14 K/s, were used. The structure of the system was examined using radial distribution function. The melting and crystallization temperatures of aluminum were evaluated by calculating the variation of heat capacity during the phase transformation. Additionally, Wendt-Abraham parameters were calculated to determine the glass transition temperature. It is shown... 

    Role of the nucleating agent masterbatch carrier resin in the nonisothermal crystallization kinetics of polypropylene

    , Article Polymer Journal ; Volume 54, Issue 9 , 2022 , Pages 1127-1132 ; 00323896 (ISSN) Shokrollahi, M ; Marouf, B. T ; Bagheri, R ; Sharif University of Technology
    Springer Nature  2022
    Abstract
    The effect of the nucleating agent masterbatch carrier resin on the nonisothermal crystallization of a pipe-grade polypropylene block copolymer was investigated at three different cooling rates using differential scanning calorimetry (DSC). Bis(3,4-dimethylibenzylidene) sorbitol (DMDBS), a well-known, third-generation sorbitol derivative, was used as a nucleating agent in this study. Crystallization kinetic parameters obtained from DSC cooling curves showed that incorporation of a nucleating agent by means of a masterbatch increased the crystallization rate by approximately two times compared to that of the sample with the same concentration of nucleating agent without the use of a... 

    Prediction of porosity percent in Al-Si casting alloys using ANN

    , Article Materials Science and Engineering A ; Volume 431, Issue 1-2 , 2006 , Pages 206-210 ; 09215093 (ISSN) Shafyei, A ; Mousavi Anijdan, S. H ; Bahrami, A ; Sharif University of Technology
    2006
    Abstract
    In this investigation a theoretical model based on artificial neural network (ANN) has been developed to predict porosity percent and correlate the chemical composition and cooling rate to the amount of porosity in Al-Si casting alloys. In addition, the sensivity analysis was performed to investigate the importance of the effects of different alloying elements, composition, grain refiner, modifier and cooling rate on porosity formation behavior of Al-Si casting alloys. By comparing the predicted values with the experimental data, it is demonstrated that the well-trained feed forward back propagation ANN model with eight nodes in hidden layer is a powerful tool for prediction of porosity... 

    Experimental study on macro segregation behavior in short and wide range solidification of different aluminum alloys

    , Article Materials Science and Technology Conference and Exhibition 2013, MS and T 2013 ; Volume 2 , 2013 , Pages 822-829 ; 9781629933092 (ISBN) Shafiei Zadeh, B ; Mohammad Salehi, E ; Hassan Nejad, H ; Shafiei Zadeh, S ; Sharif University of Technology
    2013
    Abstract
    Data are presented on the solidification of aluminum alloys and their macro segregation behavior. Three alloys with different solidification ranges were prepared in two temperatures. Two types of molds were also prepared by sand and metallic materials. The solidification of Al alloys were studied and the effects of four parameters were determined, including cooling rate, casting temperature, degassing and nucleation effects on solidification and a comparison was conducted to Scheil model performance. Three types of aluminum alloys (Al-12.1%Si, Al-6.9%Si and Al-4.4% Cu) with short, medium and wide solidification ranges were studied and the results showed that degassing, nucleation, increasing... 

    In vitro bioactivity and corrosion resistance enhancement of Ti-6Al-4V by highly ordered TiO 2 nanotube arrays

    , Article Journal of the Australian Ceramic Society ; Volume 55, Issue 1 , 2019 , Pages 187-200 ; 25101560 (ISSN) Sarraf, M ; Sukiman, N. L ; Bushroa, A. R ; Nasiri Tabrizi, B ; Dabbagh, A ; Abu Kasim, N. H ; Basirun, W. J ; Sharif University of Technology
    Springer International Publishing  2019
    Abstract
    In the present study, the structural features, corrosion behavior, and in vitro bioactivity of TiO 2 nanotubular arrays coated on Ti–6Al–4V (Ti64) alloy were investigated. For this reason, Ti64 plates were anodized in an ammonium fluoride electrolyte dissolved in a 90:10 ethylene glycol and water solvent mixture at room temperature under a constant potential of 60 V for 1 h. Subsequently, the anodized specimens were annealed in an argon gas furnace at 500 and 700 °C for 1.5 h with a heating and cooling rate of 5 °C min −1 . From XRD analysis and Raman spectroscopy, a highly crystalline anatase phase with tetragonal symmetry was formed from the thermally induced crystallization at 500 °C.... 

    Effect of cooling rate on the microstructure and mechanical properties of microalloyed forging steel

    , Article Journal of Materials Processing Technology ; Volume 206, Issue 1-3 , 12 September , 2008 , Pages 92-98 ; 09240136 (ISSN) Rasouli, D ; Khameneh Asl, S ; Akbarzadeh, A ; Daneshi, G. H ; Sharif University of Technology
    2008
    Abstract
    The effect of cooling rate after hot deformation on the microstructure and mechanical properties of a commercial microalloyed forging steel (30MSV6 grade) was investigated using the hot compression test. Hot compression test was performed at 1150 and 925 °C followed by air cooling at different rates. Final microstructures and mechanical properties were evaluated by optical microscopy and shear punch test (SPT), respectively. The results indicated that by increasing the cooling rate, the as-received ferritic-pearlitic microstructure changes to the acicular ferrite, bainite or martensite. It is shown that both yield and ultimate strength increase but the ductility decreases significantly. At a... 

    Microstructural evolution of Al-20Si-5Fe alloy during rapid solidification and hot consolidation

    , Article Rare Metals ; Volume 28, Issue 6 , 2009 , Pages 639-645 ; 10010521 (ISSN) Rajabi, M ; Vahidi, M ; Simchi, A ; Davami, P ; Sharif University of Technology
    Abstract
    Al-20Si-5Fe melt was rapidly solidified into particles and ribbons and then consolidated to near full density by hot pressing at 400°C/250 MPa/1 h. According to the eutectic-growth and dendritic-growth velocity models, the solidification front velocity and the amount of undercooling were estimated for the particles with different sizes. Values of 0.43-1.2 cm/s and 15-28 K were obtained. The secondary dendrite arm spacing revealed a cooling rate of 6 × 105 K/s for the particles with an average size of 20 μm. Solidification models for the ribbons yielded a cooling rate of 5 × 107 K/s. As a result of the higher cooling rate, the melt-spun ribbons exhibited considerable microstructural... 

    Effect of rapid solidification on the microstructure and mechanical properties of hot-pressed Al-20Si-5Fe alloys

    , Article Materials Characterization ; Volume 60, Issue 11 , 2009 , Pages 1370-1381 ; 10445803 (ISSN) Rajabi, M ; Vahidi, M ; Simchi, A ; Davami, P ; Sharif University of Technology
    2009
    Abstract
    The aim of this work is to study the effect of cooling rate and subsequent hot consolidation on the microstructural features and mechanical strength of Al-20Si-5Fe-2X (X = Cu, Ni and Cr) alloys. Powder and ribbons were produced by gas atomization and melt spinning processes at two different cooling rates of 1 × 105 K/s and 5 × 107 K/s. The microstructure of the products was examined using optical microscopy, scanning electron microscopy, transmission electron microscopy, and X-ray diffraction. The particles were consolidated by hot pressing at 400 °C/250 MPa/1 h under a high purity argon atmosphere and the microstructure, hardness and compressive strength of the compacts were evaluated.... 

    Welding metallurgy of stainless steels during resistance spot welding part I: Fusion zone

    , Article Science and Technology of Welding and Joining ; Volume 20, Issue 6 , Mar , 2015 , Pages 502-511 ; 13621718 (ISSN) Pouranvari, M ; Alizadeh Sh, M ; Marashi, S. P. H ; Sharif University of Technology
    Maney Publishing  2015
    Abstract
    Weldability is one of the key requirements for automotive materials. This two-part paper aims at understanding the metallurgical phenomena during resistance spot welding of stainless steels, as interesting candidates for automotive body in white. Part I addresses the phase transformations in the fusion zone of three types of stainless steels including austenitic, ferritic and duplex types. The solidification and solid state phenomena including columnar to equiaxed transition, ferrite– austenite post-solidification transformation, martensitic transformation and carbide precipitation are discussed. Particular attention is given to the effect of high cooling rate of resistance spot welding...