Sharif Digital Repository

In the present research, the influence of nanodiamond (ND) and a physical hybrid of ND and fumed nano-SiO2 were investigated on the performance of a typical tire tread compound. The styrene-butadiene rubber (SBR) and cis-butadiene rubber (BR) blend filled with a commercial grade highly dispersive silica at 70 phr loading were used as typical tire tread compound. ND was substituted partially with silica at two different concentrations of 5 and 10phr. Meanwhile, 5 phr of ND/nano-SiO2 hybrids with the weight ratio of 2.5/2.5 and 1/4 were substituted with silica. ND-Filled compounds exhibit increased scorch and cure time compared to controls. Improvement in different characteristics of the... 

Two new correlation functions with three adjustable parameters for the calculation of thermal conductivity of gases, liquids, and refrigerants over wide temperature-pressure ranges are presented. It is shown that by using suitable mathematical expressions for the correlation functions, the number of adjustable parameters can be limited to three, which is less than for similar functions. The average and maximum deviation of the correlation compared with the measured data is about 1% and 8%, respectively  

A numerical analysis is presented to model the cone penetration test (CPT) tip resistance in layered soil. Analyses are performed for two-layer soils composed of either sands with different relative densities or different materials (sand and clay). Parametric numerical modeling is used to determine the distance that a cone senses a new upcoming soil layer interface or a layer interface behind. Analyses are also carried out for a thin sand layer embedded in soft clay. It is seen that the full tip resistance may not be reached in thin stiff layers. This is especially true for penetration in thin dense sand layers interbedded in softer clay. A correction factor is suggested to correct the cone... 

Crude oil density is an important thermodynamic property in simulation processes and design of equipment. Using laboratory methods to measure crude oil density is costly and time consuming; thus, predicting the density of crude oil using modeling is cost-effective. In this article, we develop a neural network-based model to predict the density of undersaturated crude oil. We compare our results with previous works and show that our method outperforms them  

In this research, the effects of nano-sized MgO in Al2O 3-SiC composites were investigated. The overall changes in the density and mechanical properties of sintered samples (hardness, bending strength and toughness) were evaluated. After mixing, drying and uniaxial compaction of the powders, they were first heat-treated at low temperature in an electric furnace to remove any residuals. They were then heat-treated at high temperature (1700 °C) inside a graphite furnace in argon atmosphere for sintering (at normal and high pressure). The content of MgO in the Al 2O3-10 vol% SiC composite was 0, 500, 1000, and 1500 ppm. Thefracture toughness(KIC)of sintered composite with 10... 

Graphene nanoplatelets (GNPs) are ideal reinforcements for improving the mechanical properties of aluminum-based matrices due to their outstanding properties. However, it essentially depends on their uniform dispersion in the matrix. In this study, the challenge of uniform dispersion of graphene was performed by functionalizing the non-covalent surface and sonication of GNPs applying non-ionic polymeric ethyl cellulose (EC) surfactant, in which a colloidal mixture was provided with Al powder and graphene, followed by sintering at 620 °C and consolidation. The density and mechanical properties of nanocomposite specimens were investigated and compared with a non-surfactant-assisted Al/GNP... 

Nanocomposite films based on low density polyethylene (LDPE), containing of 2, 3, and 4. wt.% organoclay (OC) and ethylene vinyl acetate (EVA) copolymer as a new compatibilizer were prepared and characterized using rheological tests, X-ray diffraction, differential scanning calorimetry, oxygen permeation measurements, and tensile tests. There was no exfoliation or intercalation of the clay layers in the absence of EVA, while an obvious increase in d-spacing was observed when the samples were prepared with EVA present. This issue was reflected in the properties of nanocomposites. The oxygen barrier properties of the LDPE/EVA/OC film were significantly better than those of the LDPE/OC film.... 

The objective of this paper is to study the improvement in the seismic behavior of concrete gravity dams by optimization of concrete mechanical properties. The criteria to measure the improvement have been: 1) reduction in the extent of cracks and 2) increase in the amount of time dams are able to tolerate earthquakes before failure. The mechanical properties considered have included the density and modulus of elasticity of concrete. The Pine Flat Dam has been selected for this numerical study. During a high intensity earthquake, dams enter a nonlinear phase, where the cracks open and close repeatedly. A smeared crack model has been used for simulation of nonlinearity. For the purpose of... 

Copper matrix composites reinforced with TiO2particles are promising materials widely used as contact materials due to their excellent mechanical and physical properties such as good electrical and thermal conductivity and strength at high temperature. In this research, the novel contact material were prepared by in-situ oxidation of Cu-Ti pre alloyed powders. The morphology of milled powders and microstructure of nano-composite specimens were studied by SEM and TEM. To evaluate mechanical alloying progress of Cu and Ti powders mixture and internal oxidation after Cu2O addition, XRD analysis were carried out. The Physical and mechanical properties results of specimens indicate that the... 

Thermosensitive Chitosan hydrogels which can be injected into defects with minimally invasive approach were prepared. Also starch micro/nano particles were synthesized via water-in-oil (W/O) miniemulsion technique. The starch particles were incorporated into the chitosan hydrogel to prepare injectable thermosensitive hydrogel composites. Tube inverting method, compression tests, swelling studies, XRD, SEM, OM, DLS, UV–vis spectroscopy were used for investigations. Results revealed that increasing crosslinker and surfactant contents and stirring rate leads to particle size reduction. Particle size was modeled using design of experiments (DOE) via the response surface method (RSM). Due to... 

Artificial Neural Networks (ANNs) have recently been introduced as an efficient artificial intelligence modeling technique for applications involving a large, number of variables, especially with highly nonlinear and complex interactions among input/output variables in a system without any prior knowledge about the nature, of these, interactions. Various types of ANN models are developed and used for different problems. In this paper, an artificial neural network of the feed-forward back-propagation type has been applied for the prediction of density and compressive strength properties of the cement paste portion of concrete mixtures. The mechanical properties of concrete are highly... 

Magnesia-dolomite refractories have advantages such as stability in the basic environments, clean steel production, high corrosion resistance, proper covering in the cement furnace, and low production costs. However, their application is restricted due to low hydration resistance. In this research, the effects of nano and micro alumina particles on the microstructure, sintering behavior, and properties of magnesia-dolomite refractories were studied. For this purpose, MgO-CaO refractories were formulated using dolomite and magnetite and 0, 2, 4, 6 and 8 wt percentage nano and micro alumina were added to the formulation. Phase and microstructure analysis of the samples were performed using... 

Reservoir fluid modelling is one of the most important steps in reservoir simulation and modelling of flow lines as well as surface facilities. One of the most uncertain parameters of the reservoir fluids is the plus fraction. An accurate and consistent splitting scheme can reduce this uncertainty and as a result, enhance the modelling of reservoir fluids. The existing schemes for splitting plus fractions are all based on assuming a specific mole fraction-molecular weight distribution with predefined constant values that may yield inaccurate and inconsistent results. In this study, an optimization-based algorithm was developed to determine the aforementioned controlling parameters of the... 

Mechanical alloying and hot extrusion techniques were employed to produce in-situ fully dens Al-Ti composites without applying any heat treatment. The focus of this study is the investigation of fracture toughness in produced composites in order to improve it and to explain the mechanisms responsible for the fracture. The morphology of milled powders was studied by Scanning Electron Microscopy (SEM). The microstructure of the extruded composites was examined by Optical Microscopy (OM) and Field Emission Scanning Electron Microscopy (FESEM). Moreover, the density and hardness of samples were investigated. Three point bending test of the single edge notched beam (SENB) samples was applied to... 

As noteworthy properties of amine aqueous solutions, the densities and viscosities of aqueous N-Methyldiethanolamine (MDEA) solutions and mixtures of MDEA with 2-Amino-2-methyl-1-propanol (AMP), Diisopropanolamine (DIPA), Monoethanolamine (MEA), and Diethanolamine (DEA) were estimated under CO2 gas loading using Adaptive Neuro-Fuzzy Inference System (ANFIS), Multi-Layer Perceptron Artificial Neural Network (MLPANN), Support Vector Machine (SVM), and Least Square Support Vector Machine (LSSVM). The density and viscosity were estimated as a function of temperature, CO2 loading, pressure, and molecular weight of mixtures. In this regard, the actual data points were collected from the... 

Due to shear layer at the interface of density current and ambient fluid, density current disturbs and entrains the surrounding fluid. Most existing analytical and numerical models for density current flows are based on the equations for single-phase flows. In this research, the density current has been modeled with two-phase flow model. The governing equations are continuity, x- momentum, and y- momentum equations for every fluid. The volume-of-fluid (VOF) interface tracking technique which uses a piecewise-linear interface calculation (PLIC) in each cell is used to determine the deformation of free surface in density current, numerically. Surface tension is implemented by the continuous... 

Accurate determination of natural gas viscosity is important for successful design of production, transportation, and gas storage systems. However, most of available models/correlations suffer from complexity, robustness, and inadequate accuracy especially when wide range of pressure and temperature is applied. Present study illustrates development of two novel models for predicting natural gas viscosity for pure natural gas (CH4) as well as natural gas containing impurities. For this purpose, 6484 data points have been gathered and analyzed from the open literature covering wide range of pressure, temperature, and specific gravity levels, temperature ranges from -262.39 to 620.33 °F (109.6... 

In the initial recovery stage, only 5 to 15% of hydrocarbons can be extracted from oil reservoirs, so it is necessary to supply energy from an external reservoir or to use advanced solutions to increase oil recovery. By using secondary recovery method and flooding, greater amount of oil can be extracted. In this study, a new procedure of flooding using nanofluid was simulated. The nanofluid and source rock were modeled as a single phase and heterogeneous porous media, respectively. The geometry was considered as a two-dimensional rectangular area. Two phase Darcy equations and mass transfer equations were utilized to simulate this process. Moreover, the effects of different volume fractions... 

A new simple and explicit reduced temperature and reduced pressure function has been proposed in the present study for modifying Redlich-Kwong equation of state (EoS) to calculate the density of carbon dioxide in the supercritical region. The average absolute error of the model was found to be 1.63 and 2.07% in the comparison with the literature and NIST density data respectively, which demonstrates superiority of the model over other EoSs  

We have studied the mechanical properties of a few-layer graphene cantilever (FLGC) using atomic force microscopy (AFM). The mechanical properties of the suspended FLGC over an open hole have been derived from the AFM data. Force displacement curves using the Derjaguin-Müller-Toporov (DMT) and the massless cantilever beam models yield a Young modulus of Ec ∼ 37, Ea ∼ 0.7TPa and a Hamakar constant of ∼ 3 × 10 -18J. The threshold force to shear the FLGC was determined from a breaking force and modeling. In addition, we studied a graphene nanoribbon (GNR), which is a system similar to the FLGC; using density functional theory (DFT). The in-plane Young's modulus for the GNRs were calculated from...