Sharif Digital Repository

In the current era, the urgent need to reduce the use of fossil fuels and limit carbon emissions has highlighted the importance of shifting from traditional gasoline-powered vehicles to electric vehicles. The evolving landscape and challenges in the field of electric vehicles highlight the importance of ensuring the safety and reliability of energy storage systems. Lithium-ion batteries play a central role in electric vehicle technology, requiring thorough research efforts. Notably, the detection of internal short circuit, a common issue in lithium-ion batteries, has become a focus of researchers in recent years. This study aims to investigate the internal short circuit fault in lithium-ion... 

Although much progress has been made in eliminating, conserving, and reducing migration and emissions of radioactive materials, the risk of radioactive material release into the environment is still one of the most important hazards in the use of nuclear energy. In this study, graphene compounds have been used as adsorbents for the removal of radioactive materials due to their high level, cost-effectiveness and simplicity of the synthesis process of various composites. In this regard, the removal of strontium and cobalt by graphene compounds has been investigated. Magnetite nanoparticles were anchored on the surface of graphene by sol-gel method and adsorption in batch mode was investigated.... 

Batteries have always been used as one of the most important sources of electricity storage and supply. Among different types of batteries, lithium-ion batteries are widely used in various fields and engineering applications due to their high-density energy/power, high discharge/charge rate, and long life. The most common of these applications are using these batteries in all-electric and hybrid vehicles, which reduce environmental problems. Due to the high cost of these types of batteries and the environmental issues of battery decomposition, researchers are seeking to discover long-lasting batteries that lithium titanate oxide batteries have the most extended lifespan among lithium-ion... 

Energy storage systems are expected to play an important role in future renewable-based power systems. Recently, lithium-ion batteries have been attracting considerable attention as alternative energy storage systems due to their advantages. In this study, viability of battery storage systems as large-scale energy storage systems is studied in the context of a residential energy hub. A stochastic optimization problem is proposed for energy management of the energy hub where wind generation and demand are considered uncertain. In order to account for the degradation costs of the battery storage system, a data-driven State-of-health prediction model is developed based on the relevance vector... 

The operating conditions of the battery in renewable energy systems affect its electrochemical behavior and degradation process. Recent research mainly estimates battery lifetime through conventional methods such as counting the number of equivalent battery life cycles or based on simple experimental models that may lead to optimistic predictions in battery service period. In this study, a reduced-order thermoelectrochemical-aging battery model is developed for the application of renewable energy systems and the battery degradation analysis is investigated by this model. The proposed microscopic model evaluates the effect of battery operating conditions such as state of charge, current and... 

Lithium ion battery is one of the innovative and emerging technologies in energy sector that has played a major role in electricity supply security by integration of renewable energy technologies in electrical grid, implementation of electrical transportation system and de-carbonation of the both sectors in recent years. On the other hand, the formation of the potential market of technology as one of the functions of the technological innovation system plays an essential role in creation and advancement of innovation in the energy sector. Therefore, in this thesis, the development of lithium ion battery technology in Iran has been investigated from the perspective of the technology market in... 

Lithium has two stable isotopes, 6Li and 7Li. Abundance of these isotopes are 7.53% and 92.43% respectively. Each isotope has an important role in nuclear industry. For example, 6Li compounds is used in production of tritium in nuclear fusion reactors coated with DT fuel and as fuel in nuclear fusion reactors that operate with laser inertial confinement method applied. 7LiOH is used to adjust the pH of the fluid coolant in light water reactors and also in Breeding Reactors. Lithium isotope separation in different ways so far been brought into operation. The other aspect to this work, it can be both continuous and batch for action. Lithium isotopes for the first time by electrolysis using... 

Lithium has 9 isotopes which two isotopes are stable and remaining isotopes are unstable and have half-life. Lithium stable isotopes include 6Li and 7Li that their abundance is 7.53% and 92.47% respectively. Importance of lighter lithium isotope appears for its small cross section against thermal neutron and producing fusion reactors fuel in nuclear industries. Thermal neutron absorption cross section for 6Li and 7Li are 950 barn and 37 mbarn respectively. Interesting of these isotopes in nuclear industry is due to the large difference in the absorption cross section.6Li compounds implied for tritium producing in coat of nuclear fusion reactor with DT fuel. Following tritium is used in... 

In recent decades, due to economic, political and environmental issues, tend to use of the CHP systems (combined heating and power) have increased. CHP systems not only increase energy efficiency, but also decrease fuel consumption and emission levels of systems. The use of CHP technology in the industry has a long history, but the use of these systems in the commercial and residential sector, is considered, recently. As to the residential buildings, both electricity and thermal energy demands fluctuate seasonally and hourly, so it is necessary to take account of the plant’s annual operational strategies for the variations of load demands. In this paper, a nonlinear programming model is... 

Lithium has two stable isotopes naturally including 6Li at 7.5% and 7Li at 92.5% relative abundance. In spite of the similarities of lithium isotopes in common chemical reactions, they have some completely distinctive behaviors in nuclear reactions. 6Li has considerable neutron cross section capturing in thermal neutron range about 945 barns while this feature for 7Li is insignificant about 0.037 barns. This difference makes them to play different roles in nuclear uses. 7LiOH is applied for pH adjustment of coolant in light water reactors. 6Li is not only used as a shielding material against thermal neutrons, but also is known as a source of tritium in the blanket of fusion reactors which... 

The elastic field is one of the challenges in optimizing the lifetime and capacity of the lithium-ion batteries. Graphite nanoparticles have been widely used in Li-ion batteries, due to their mechanical, thermal and electrical properties. During the lithiation, chemical reactions occurred in the electrolyte, which forms a solid electrolyte interphase(SEI) in the surrounding of nanoparticles as well as stress fields inside the nanoparticles. Therefore, the purpose of this research is to examine the effects of the surface/interface on diffusion induced stresses(DIS) within core-shell nanosphere due to non-uniform distribution of eigenstrain fields. Due to the mechanical behavior of the phases,... 

The elastic field is one of the challenges in optimizing the lifetime and capacity of the lithiumion batteries. Graphite nanoparticles have been widely used in Li-ion batteries, due to their mechanical, thermal and electrical properties. During the lithiation, chemical reactions occurred in the electrolyte, which forms a solid electrolyte interphase(SEI) in the surrounding of nanoparticles as well as stress fields inside the nanoparticles. Therefore, the purpose of this research is to examine the effects of the surface/interface on diffusion induced stresses(DIS) within core-shell nanosphere due to non-uniform distribution of eigenstrain fields. Due to the mechanical behavior of the phases,... 

Lithium-ion batteries have the ability to store a significant amount of energy and work at high power, which has led to the wide spread of their use in various industries. In high-power applications, battery heat management increases lifespan, safety, and reduces battery power loss. In this study, the heat management of a very common and widely used 18650 battery using multi-layered phase change material has been investigated. The reason for using multiple layers is that each phase change material has its own weaknesses in addition to its advantages. It is expected that with the proper use of several phase change materials in the thermal management system, the materials will reduce the... 

In Li-ion batteries, large volume changes of electrodes with high capacity, such as silicon electrodes during charging and discharging processes (insertion/extraction of lithium into/from the electrode), lead to restrictions on the use of this type of electrode. Given the very high capacity of silicon, predicting and modeling the behavior of silicon electrodes during electrochemical cycles is important and is also addressed in this thesis. First, using the theory of linear elasticity, relations are proposed that couple the diffusion of particles with small elastic deformation. The effect of hydrostatic stress on diffusion and stresses is investigated in lithiation processes. Then, the... 

In this study, three active, passive, and hybrid thermal management systems are applied to a lithium battery module with industrial specifications, i.e., Tesla battery module, and the optimal conditions are extracted. The thermal and electrochemical behavior of battery cells is modeled using the quasi-two-dimensional approach by Newman’s method. The effects of inter-cellular distance on the maximum temperature and on the temperature distribution in the pack as the target variables are thoroughly investigated. A suitable range for the above distances is then determined in order to reduce the overall cooling power and the expected thermal performance of the pack. The results of temperature... 

Application of light metals such as Magnesium alloys due to proper mechanical behavior is increasing in industries such as automotive, electronics and so on. In this project, ingot of Mg-9Li-1Zn alloy with 10 mm thickness were produced by casting, then hot rolled at 300oC to reach 2mm thickness. Annealing at 350oC for 3 hours resulted homogenous properties in the final sheet.Study of monotonic and cyclic behavior of Mg-Li alloy by experiments and FE simulation was the goal of this project. Experimental monotonic and cyclic test were carried out in order to obtain the hysteresis loops and cyclic stress-strain curve. The Chaboche constant were extracted from the experimental test and used to... 

Among the various materials, silicon anodes have the highest lithium absorption in lithium-ion batteries. But this high lithium absorption capacity can cause 300 percent volume expansion and large stresses. Experimental observations show that charge and discharge cycles may cause plastic deformation in some parts of the electrode particle. On the other hand, there is a possibility of a ratcheting phenomenon due to changing in elastic properties of the electrode material during the charging and discharging processes. However, this phenomenon has not been reported for silicon spherical electrode particles yet.This study aims to model the elastic-plastic behavior of silicon spherical electrode... 

Battery thermal management system is the indispensable part of the electric vehicles working with Lithium-ion batteries. Accordingly, Lithium-ion batteries modelling, battery heat generation and thermal management is the main focus of researchers and car manufacturers. While Computational Fluid Dynamics (CFD) has been used quite successfully for battery thermal management, CFD models can be too large and too slow for assembling in battery pack level models or vehicle models. In this research a much smaller reduced order model is developed, which is in the core is based on CFD models. Thus, without losing the accuracy, this model can be implemented in the vehicle model. The developed model... 

In this study, Lithium recovery process from lithium-ion battery was investigated by electrodialysis method. First, the cathode of the battery was leached in NMP to separate cathode from aluminum foil. Then, the cathode was leached in sulfuric acid with concentration 3.25 M and 10 volume percent hydrogen peroxide that pulp density was 55 g/L at 60°C for 100 minutes. in the next step, an electrodialysis cell was designed and created to recover lithium. And the influence of time, voltage, flow rate of feed solution, concentration of electrode solution and concentration of feed solution on process was investigated. Purpose of this project were investigated lithium ion recovery rate, lithium... 

One of the problems that affects the lifetime and cycle life of lithium ion batteries is the localized corrosion of aluminum current collector (during the storage and charging cycle). Since applying corrosion-resistant coating has always been one of the ways to reduce corrosion of materials in different environments, in the present project, this method has been used to prevent corrosion of aluminum in lithium-ion batteries. For this purpose, the graphene oxide coating, which has desirable anti-corrosion properties, was coated on aluminum by Electrophoretic deposition and doctor blade methods. linear polarization, cyclic voltammetry and electrochemical impedance spectroscopy were performed to...