Sharif Digital Repository

In this work, biosorption of Zirconium from aqueous solution by A.niger as a biosorbent was investigated. For this goal, both of live and dried biomasses were used. The effect of factors pH, temperature, contact time, initial concentration of metal and biomass dosage were investigated on biosorption. To preparing dried biomass,the live biomass was dried at 60-80 º C for 24 hr and then this dried cell was crushed by mortar and pestle and the drying biomass was ground through a set of sieve with 100 mesh. Also, effect of the pretreatment of biomass by NaOH 0.5 M on biosorption was studied. Optimization of factors was performed by Response Surface Methodology (RSM). The experiments were... 

Water plays an essential role in the daily lives of humans, plants, and animals. Due to the lack of safe water on the planet, in recent years there have been many challenges in the field of water treatment, which has made water desalination technology always one of the most advanced technologies. The most advanced technology in this field is the use of nanotechnology in water and wastewater treatment, especially the use of Membrane processes such as reverse osmosis. Unlike conventional reverse osmosis membranes, nanoporous membranes can ensure rapid water transfer during the displacement process. The purpose of this thesis is to introduce new monolayers that have an incredible performance in... 

The major features of batch sublimation were investigated in an experimental-theoretical study. An experimental setup with real-time displays, sublimated dry ice blocks of different sizes, with circular or rectangular geometries. When temperature of hotplate was changed from -30 to 200 oC, heat transfer coefficient “hsub” decreased from 126 to 70 W/m2K, while thermal flux increased, linearly. Weight and area of the block had a positive/negative effects on “hsub”, respectively. In theoretical part, at first, two “linear-gradient” and “cubic” models were developed by a combined mass-momentum-energy balance. The latter used Von Karman temperature profile, and in cases of circular and... 

Transistors’ miniaturization and advent of short-channel effects causes searching for another devices with least adverse characteristics in short channels. Among all the considered devices, monolayer transistors attracted the attention. Although most of the papers in literature focused on the physical phenomenon of the device, circuit design of these transistors have been overlooked. Most of the papers related to monolayer transistors did not explain the design methodology of their circuits and they confined their work just to the report of the circuits constructed with 2D-based transistors. In order to take advantage of 2D materials in electronic circuits, simple modelling for... 

Propylene, as one of the most important raw materials of petrochemical industries, is produced through different methods. One of the major methods is propane dehydrogenation. This reaction is endothermic and many by-products will be produced in high temperature. Therefore catalytic dehydrogenation is preferred. Reduction in catalyst's activity and too many side reactions are the most important problems. Coke formation is the most effective reason of deactivation. Main source of coke is propylene. Experiments show that very small amount of water presence within reaction can reduce rate of coke formation. Water content growth does not always increase activity. If water be more than optimum... 

In this thesis the effects of impurities and different defects on electrical and magnetic properties of monolayer and bilayer graphene is investigated. Calculations are performed using density function theory. Alloying monolayer graphene with boron and nitrogen the energy gaps of 0.7 and 0.6 eV are obtained, respectively. Moreover, we show that BN is a good candidate for opening the band gap in graphene. Alloying monolayer graphene with BN the energy gap of 1.2 eV is obtained. Another way of opening band gap is to somehow break the symmetry between layers of the bilayer graphene. By alloying one layers of bilayer graphene with B, N or B-N, although the symmetry of layers is broken, each... 

Biosorption capacity of zinc (II) by biomasses produced from four species of microorganism including two kinds of bacteria (Pseudomonas putida and Streptomyces rimosus) and two kinds of fungi ( Aspergillus niger and Phanerochate chrysosporium) in batch case were investigated and compared. In all cases dried original bio mass and dried pretreated bio mass with NaOH were used. In all cases biosorption capacity of pretreated biomasses were much higher than non-treated biuomasses to the ratio of 3.8 – 1.4 times. Freundlich and Langmuir equilibrium isotherms were used to match with experimental results of this research. Except S.rimosus, all others were completely matched with Langmuir...