Loading...
Search for: monolayers
0.009 seconds
Total 63 records

    Low-frequency Model for Long-channel Monolayer Transistors

    , Ph.D. Dissertation Sharif University of Technology Omdeh Ghiasi, Hesam (Author) ; Safarian, Amin Ghasem (Supervisor) ; Pourfath, Mahdi (Co-Supervisor)
    Abstract
    Transistors’ miniaturization and advent of short-channel effects causes searching for another devices with least adverse characteristics in short channels. Among all the considered devices, monolayer transistors attracted the attention. Although most of the papers in literature focused on the physical phenomenon of the device, circuit design of these transistors have been overlooked. Most of the papers related to monolayer transistors did not explain the design methodology of their circuits and they confined their work just to the report of the circuits constructed with 2D-based transistors. In order to take advantage of 2D materials in electronic circuits, simple modelling for... 

    Performance Modeling of Nano-Porous Monolayers in Water Desalination Using Molecular Dynamics Simulations Approach

    , Ph.D. Dissertation Sharif University of Technology Mehrdad, Mohammad (Author) ; Moosavi, Ali (Supervisor) ; Nejat, Hossein (Co-Supervisor)
    Abstract
    Water plays an essential role in the daily lives of humans, plants, and animals. Due to the lack of safe water on the planet, in recent years there have been many challenges in the field of water treatment, which has made water desalination technology always one of the most advanced technologies. The most advanced technology in this field is the use of nanotechnology in water and wastewater treatment, especially the use of Membrane processes such as reverse osmosis. Unlike conventional reverse osmosis membranes, nanoporous membranes can ensure rapid water transfer during the displacement process. The purpose of this thesis is to introduce new monolayers that have an incredible performance in... 

    Kinetic Modeling of Coke Formation in PDH over Pt-Sn/Al2O3 in Presence of Oxygenated Additives

    , M.Sc. Thesis Sharif University of Technology Samavati, Abolfazl (Author) ; Khorasheh, Farhad (Supervisor)
    Abstract
    Propylene, as one of the most important raw materials of petrochemical industries, is produced through different methods. One of the major methods is propane dehydrogenation. This reaction is endothermic and many by-products will be produced in high temperature. Therefore catalytic dehydrogenation is preferred. Reduction in catalyst's activity and too many side reactions are the most important problems. Coke formation is the most effective reason of deactivation. Main source of coke is propylene. Experiments show that very small amount of water presence within reaction can reduce rate of coke formation. Water content growth does not always increase activity. If water be more than optimum... 

    , M.Sc. Thesis Sharif University of Technology Kalantari, Hamed (Author) ; Rosta Azad, Reza (Supervisor) ; Yagmaei, Soheila (Supervisor) ; Sana, Solat (Co-Advisor)
    Abstract
    In this work, biosorption of Zirconium from aqueous solution by A.niger as a biosorbent was investigated. For this goal, both of live and dried biomasses were used. The effect of factors pH, temperature, contact time, initial concentration of metal and biomass dosage were investigated on biosorption. To preparing dried biomass,the live biomass was dried at 60-80 º C for 24 hr and then this dried cell was crushed by mortar and pestle and the drying biomass was ground through a set of sieve with 100 mesh. Also, effect of the pretreatment of biomass by NaOH 0.5 M on biosorption was studied. Optimization of factors was performed by Response Surface Methodology (RSM). The experiments were... 

    Investigation of Impurities and Structural Defects in Graphene

    , M.Sc. Thesis Sharif University of Technology Rostami, Melika (Author) ; Faez, Rahim (Supervisor)
    Abstract
    In this thesis the effects of impurities and different defects on electrical and magnetic properties of monolayer and bilayer graphene is investigated. Calculations are performed using density function theory. Alloying monolayer graphene with boron and nitrogen the energy gaps of 0.7 and 0.6 eV are obtained, respectively. Moreover, we show that BN is a good candidate for opening the band gap in graphene. Alloying monolayer graphene with BN the energy gap of 1.2 eV is obtained. Another way of opening band gap is to somehow break the symmetry between layers of the bilayer graphene. By alloying one layers of bilayer graphene with B, N or B-N, although the symmetry of layers is broken, each... 

    Biosorption of Zinc Ions Using Biomasses Produced From Four Different Types of Microbes Under Batch and Continuous Conditions

    , M.Sc. Thesis Sharif University of Technology Hosseini, Soheil (Author) ; Roostaazad, Reza (Supervisor) ; Razavi, Jalil (Supervisor)
    Abstract
    Biosorption capacity of zinc (II) by biomasses produced from four species of microorganism including two kinds of bacteria (Pseudomonas putida and Streptomyces rimosus) and two kinds of fungi ( Aspergillus niger and Phanerochate chrysosporium) in batch case were investigated and compared. In all cases dried original bio mass and dried pretreated bio mass with NaOH were used. In all cases biosorption capacity of pretreated biomasses were much higher than non-treated biuomasses to the ratio of 3.8 – 1.4 times. Freundlich and Langmuir equilibrium isotherms were used to match with experimental results of this research. Except S.rimosus, all others were completely matched with Langmuir... 

    An Experimental-Theoretical Study on Batch (Static) Sublimation and Derivation of a Correlation for its Heat Transfer Coefficient

    , M.Sc. Thesis Sharif University of Technology Mottafegh, Amir Reza (Author) ; Otukesh, Mohammad (Supervisor)
    Abstract
    The major features of batch sublimation were investigated in an experimental-theoretical study. An experimental setup with real-time displays, sublimated dry ice blocks of different sizes, with circular or rectangular geometries. When temperature of hotplate was changed from -30 to 200 oC, heat transfer coefficient “hsub” decreased from 126 to 70 W/m2K, while thermal flux increased, linearly. Weight and area of the block had a positive/negative effects on “hsub”, respectively. In theoretical part, at first, two “linear-gradient” and “cubic” models were developed by a combined mass-momentum-energy balance. The latter used Von Karman temperature profile, and in cases of circular and... 

    Two-dimensional porous graphitic carbon nitride C6N7 monolayer: first-principles calculations

    , Article Applied Physics Letters ; Volume 119, Issue 14 , 2021 ; 00036951 (ISSN) Bafekry, A ; Faraji, M ; Fadlallah, M. M ; Abdolhosseini Sarsari, I ; Jappor, H. R ; Fazeli, S ; Ghergherehchi, M ; Sharif University of Technology
    American Institute of Physics Inc  2021
    Abstract
    The fabrication of the C6N7 monolayer [Zhao et al., Sci. Bull. 66, 1764 (2021)] motivated us to discover the optical, structural, mechanical, and electronic properties of the C6N7 monolayer by employing the density functional theory (DFT) method. We find that the shear modulus and Young's modulus of the C6N7 monolayer are smaller than the relevant values of graphene. However, Poisson's ratio is more significant than that of graphene. Applying the PBE (HSE06) functional bandgap of the C6N7 monolayer is 1.2 (1.97) eV, and the electronic dispersion is almost isotropic around the Γ point. C6N7 is more active in the ultraviolet region as compared to the visible light region. This study provides... 

    Theoretical study of light trapping in nanostructured thin film solar cells using wavelength-scale silver particles

    , Article ACS Applied Materials and Interfaces ; Volume 7, Issue 27 , July , 2015 , Pages 14926-14932 ; 19448244 (ISSN) Dabirian, A ; Taghavinia, N ; Sharif University of Technology
    American Chemical Society  2015
    Abstract
    We propose and theoretically evaluate a plasmonic light trapping solution for thin film photovoltaic devices that comprises a monolayer or a submonolayer of wavelength-scale silver particles. We systematically study the effect of silver particle size using full-wave electromagnetic simulations. We find that light trapping is significantly enhanced when wavelength-scale silver particles rather than the ones with subwavelength dimensions are used. We demonstrate that a densely packed monolayer of spherical 700 nm silver particles enhances integrated optical absorption under standard air mass 1.5 global (AM1.5G) in a 7 μm-thick N719-sensitized solar cell by 40% whereas enhancement is smaller... 

    The improvement of light scattering of dye-sensitized solar cells aided by a new dandelion-like TiO2 nanostructures

    , Article Solar Energy Materials and Solar Cells ; Volume 137 , 2015 , Pages 113-123 ; 09270248 (ISSN) Musavi Gharavi, P. S ; Mohammadi, M. R ; Sharif University of Technology
    Elsevier  2015
    Abstract
    We present a new dandelion-like TiO2 spheres by a modified hydrothermal method for manufacture of dye-sensitized solar cells (DSSCs). This construct is composed of numerous nanowires for employment as the scattering layer of DSSCs. Such morphology is produced by nucleation-growth-assembly mechanism. The size of the dandelion-like spheres and their morphology can be tailored by controlling the processing parameters of the modified hydrothermal process. TiO2 nanoparticles with narrow size distribution are also synthesized by hydrothermal route for the active layer of DSSCs. The nanoparticles show pure anatase phase with average size of 40 nm, whereas the dandelion-like TiO2 spheres are pure... 

    Symmetry enhanced spin-Nernst effect in honeycomb antiferromagnetic transition metal trichalcogenide monolayers

    , Article Physical Review B ; Volume 103, Issue 1 , 2021 ; 24699950 (ISSN) Bazazzadeh, N ; Hamdi, M ; Haddadi, F ; Khavasi, A ; Sadeghi, A ; Mohseni, S. M ; Sharif University of Technology
    American Physical Society  2021
    Abstract
    We investigate systematically the spin-Nernst effect in Néel and zigzag ordered honeycomb antiferromagnets. Monolayers of transition-metal trichalcogenides, MnPSe3, MnPS3, and VPS3 show an antiferromagnetic Néel order while CrSiTe3, NiPS3, and NiPSe3 show an antiferromagnetic zigzag order. We extract the exchange and Dzyaloshinskii-Moriya interaction parameters from ab initio calculations. Using these parameters, we predict that the spin-Nernst coefficient is at least two orders of magnitude larger in zigzag compared to the Néel ordered antiferromagnets. We find that this enhancement relies on the large band splitting due to the symmetry of magnetic configuration in the zigzag order. Our... 

    Strain effects on optical properties of linearly polarized resonant modes in the presence of monolayer graphene

    , Article Materials Science and Engineering B: Solid-State Materials for Advanced Technology ; Volume 277 , 2022 ; 09215107 (ISSN) Alidoust Ghatar, A ; Jahani, D ; Akhavan, O ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    Recently, huge attention has been drawn to improve optical sensing devices based on photonic resonators in the presence of graphene. In this paper, based on the transfer matrix approach and TE polarization of the incident electromagnetic waves, we numerically evaluate the transmission and reflection spectra for one-dimensional photonic resonators and surface plasmon resonances with strained graphene, respectively. We proved that a relatively small strain field in graphene can modulate linearly polarized resonant modes within the photonic bandgap of the defective crystal. Moreover, we study the strain effects on the surface plasmon resonances created by the evanescent wave technique at the... 

    Specific picomolar detection of a breast cancer biomarker her-2/neu protein in serum: electrocatalytically amplified electroanalysis by the aptamer/peg-modified electrode

    , Article ChemElectroChem ; Volume 4, Issue 4 , 2017 , Pages 872-879 ; 21960216 (ISSN) Salimian, R ; Kékedy Nagy, L ; Ferapontova, E. E ; Sharif University of Technology
    Wiley-VCH Verlag  2017
    Abstract
    Specific and sensitive electroanalysis of blood-circulating protein cancer biomarkers is often complicated by interference from serum proteins nonspecifically adsorbing at the biosensing interface and masking specific reactions of interest. Here, we have developed an electrocatalytically amplified assay for specific and sensitive analysis of human epidermal growth factor receptor-2 (HER-2/neu, a protein cancer biomarker over-expressed in breast cancers) that allows us to avoid both the interference from bovine serum albumin (BSA) and electrocatalytic amplification of the signal stemming from the specific aptamer−HER-2/neu binding. A HER-2/neu-specific thiolated aptamer sequence was... 

    Single-layer MoS2-MoO3-x heterojunction nanosheets with simultaneous photoluminescence and co-photocatalytic features

    , Article Catalysts ; Volume 11, Issue 12 , 2021 ; 20734344 (ISSN) Saadati, M ; Akhavan, O ; Fazli, H ; Sharif University of Technology
    MDPI  2021
    Abstract
    Single-layer MoS2-MoO3-x heterojunction nanosheets with visible-light-sensitive band gap energy and average lateral dimensions of ~70 nm were synthesized by using a two-step combined exfoliation method. The exfoliation was initiated from pristine MoS2, while some sulfur sites in expanded MoS2 sheets during exfoliating were substituted by ambient non-thermal oxygen, resulting in formation of α-MoO3-x crystalline domains. The morphological features, crystalline structure, phase formation, number of layers, and optical properties of the MoS2-MoO3-x nanosheets were determined by atomic force microscopy; X-ray diffraction; field emission electron microscopy; transmission electron microscopy; and... 

    Simultaneous removal of mercury ions and cationic and anionic dyes from aqueous solution using epichlorohydrin cross-linked chitosan @ magnetic Fe3O4/activated carbon nanocomposite as an adsorbent

    , Article Diamond and Related Materials ; Volume 124 , 2022 ; 09259635 (ISSN) Kaveh, R ; Bagherzadeh, M ; Sharif University of Technology
    Elsevier Ltd  2022
    Abstract
    An economical epichlorohydrin cross-linked chitosan @ magnetic Fe3O4/activated carbon nanocomposite, CH-EP@Fe3O4/AC, was successfully synthesized and used as a suitable adsorbent material for removal of a triphenylmethane cationic dye, Malachite green (MG), an anionic dye, Reactive red 120 (RR120), and Mercury ions (Hg2+) from aqueous solution. The prepared adsorbent has been characterized with Fourier transform infrared spectroscopy, X-ray diffraction, Scanning electron microscopy, Thermogravimetric analysis, Brunauer–Emmett–Teller analysis as well as Vibrating sample magnetometer. According to the result of Brunauer–Emmett–Teller isotherm, the prepared adsorbent has a specific surface area... 

    Self-limited growth of large-area monolayer graphene films by low pressure chemical vapor deposition for graphene-based field effect transistors

    , Article Ceramics International ; Volume 43, Issue 17 , 2017 , Pages 15010-15017 ; 02728842 (ISSN) Kiani, F ; Razzaghi, Z ; Ghadiani, B ; Tamizifar, M ; Mohmmadi, M. H ; Simchi, A ; Sharif University of Technology
    Abstract
    During the last decade, fabrication of high-quality graphene films by chemical vapor deposition (CVD) for nanoelectronics and optoelectronic applications has attracted increasing attention. However, processing of large-area monolayer and defect-free graphene films is still challenging. In this work, we have studied the effect of processing conditions on the self-limited growth of graphene monolayers on copper foils during low pressure CVD both experimentally and theoretically based on thermokinetics and kinetics of Langmuir adsorption. The effect of copper pre-treatment, growth time, and carbon potential of the atmosphere (indicated by the methane-to-hydrogen gas ratio, r) on the quality of... 

    Self-assembled monolayer of wavelength-scale core-shell particles for low-loss plasmonic and broadband light trapping in solar cells

    , Article ACS Applied Materials and Interfaces ; Volume 8, Issue 1 , 2016 , Pages 247-255 ; 19448244 (ISSN) Dabirian, A ; Malekshahi Byranvand, M ; Naqavi, A ; Nemati Kharat, A ; Taghavinia, N ; Sharif University of Technology
    American Chemical Society 
    Abstract
    Scattering particles constitute a key light trapping solution for thin film photovoltaics where either the particles are embedded in the light absorbing layer or a thick layer of them is used as a reflector. Here we introduce a monolayer of wavelength-scale core-shell silica@Ag particles as a novel light trapping strategy for thin film photovoltaics. These particles show hybrid photonic-plasmonic resonance modes that scatter light strongly and with small parasitic absorption losses in Ag (<1.5%). In addition, their scattering efficiency does not vary significantly with the refractive index of the surrounding medium. A monolayer of these particles is applied as the top-scattering layers in a... 

    Selective separation of Congo Red from a mixture of anionic and cationic dyes using magnetic-MOF: Experimental and DFT study

    , Article Journal of Molecular Liquids ; Volume 318 , 2020 Mirzaee Valadi, F ; Ekramipooya, A ; Gholami, M. R ; Sharif University of Technology
    Elsevier B.V  2020
    Abstract
    La-MOF-NH2@Fe3O4 (magnetic-MOF) was used as an efficient, ultrafast, and selective adsorbent for the separation of Congo Red (CR) with 92.02% removal after 2 min. The magnetic-MOF was identified by X-ray diffraction (XRD), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET) surface area, Zeta Potential analysis, analysis of the magnetic hysteresis, Fourier-transform infrared spectroscopy (FTIR), scanning electron microscope (SEM) and energy-dispersive X-ray spectroscopy (EDS). Kinetics, isotherms, the effect of pH, thermodynamic, and selectivity of CR adsorption were investigated. The results confirmed that the adsorption kinetics complied with the pseudo-second-order model. The... 

    Role of precursors and coating polymers in sol-gel chemistry toward enhanced selectivity and efficiency in solid phase microextraction

    , Article Analytica Chimica Acta ; Volume 742 , 2012 , Pages 45-53 ; 00032670 (ISSN) Bagheri, H ; Piri Moghadam, H ; Ahdi, T ; Sharif University of Technology
    Elsevier  2012
    Abstract
    To evaluate the selectivity and efficiency of solid phase microextraction (SPME) fiber coatings, synthesized by sol-gel technology, roles of precursors and coating polymers were extensively investigated. An on-line combination of capillary microextraction (CME) technique and high performance liquid chromatography (HPLC) was set up to perform the investigation. Ten different fiber coatings were synthesized in which five of them contained only the precursor and the rests were prepared using both the precursor and coating polymer. All the coatings were chemically bonded to the inner surface of copper tubes, intended to be used as the CME device and already functionalized by self-assembly... 

    Rapid and simultaneous determination of tetracycline and cefixime antibiotics by mean of gold nanoparticles-screen printed gold electrode and chemometrics tools

    , Article Measurement: Journal of the International Measurement Confederation ; Vol. 47, Issue. 1 , 2014 , pp. 145-149 ; ISSN: 02632241 Asadollahi-Baboli, M ; Mani-Varnosfaderani, A ; Sharif University of Technology
    Abstract
    The screen-printed gold electrode (SPGE) modified with the formation of self-assembly monolayer (SAM) of cysteine (Cys) on gold-nanoparticles (Au nano) was utilized for rapid and simultaneous determination of tetracycline and cefixime antibiotics by square wave voltammetry (SWV). Electrochemical investigation and characterization of the modified electrode was achieved using cyclic voltammetry (CV) and scanning electron microscopy (SEM). A principal component artificial neural network (PCANN) with three layer back-propagation network was utilized for the analysis of the voltammogram data. It is possible to simultaneously determine the tetracycline and cefixime concentrations in the ranges of...