Sharif Digital Repository

In this thesis, a novel graphene oxide (GO)/sodium alginate (SA)/polyacrylamide (PAM) ternary nanocomposite hydrogel with excellent mechanical performance has been fabricated through freeradical polymerization of acrylamide (AAm) and SA in the presence of GO in an aqueous system followed with ionically crosslinking of calcium ions. Physical and chemical characteristics of the composite were investigated by Fourier transform infrared spectroscopy and scanning electron microscopy. The swelling behaviors of the composite hydrogels were investigated under varying conditions of time and pH. The optimized swelling capacity in standard conditions was found to be 1711% per gram of the hydrogel. The... 

This study investigated the effect of oxidized molybdenum disulfide (MoS2) nanosheets on the anti-corrosion and rheological properties of epoxy resin. Raw MoS2 sheets were obtained as layered nanosheets with a thickness of 50 to 100 nm using acid washing, oxidation, and heat shock methods. The use of nanoparticle characterization tests such as XRD, FT-IR, FE-SEM, EDS, and TGA supports this claim. Then, in the next step, epoxy coatings containing different percentages (0, 0.3, 0.5, 0.8, and 1.5 wt%) of MoS2 nanosheets were prepared with polyamide hardener to investigate the effect of adding nanosheets and the optimal percentage. The best effect on the corrosion properties of the coating in a... 

Two-dimensional (2D) nanomaterials are ultrathin nanomaterials with a high degree of anisotropy and chemical functionality. Research on 2D nanomaterials is still in its infancy, with the majority of research focusing on elucidating unique material characteristics and few reports focusing on biomedical applications of 2D nanomaterials. Here we report the properties and application of 2Dnanomaterials in field of bio technology while used main material in our project is graphene oxide for investigating its antibacterial properties. Because the properties of graphene oxide (GO)-based materials strongly depend on the lateral size and size distribution of GO nanosheets; therefore, GO and its... 

In this study non-linear bending of circular sandwich plates with functionally graded (FG) porous core reinforced with graphene nanoplatelets (GPL) is investigated using refined shear deformation theory (RSDT). Displacement field of this theory is considered so that different theories can be introduced to estimate transverse shear strain. Equilibrium equations and boundary conditions are derived using minimum total potential energy principle. The equations are reformulated using potential and stress functions and analytical solution is obtained using perturbation method along with Fourier series. Validations are performed for two cases of linear and non-linear bending of circular plate and... 

Antibacterial resistance towards existing antibiotics has become a major problem in medicine and health in recent years. Therefor it has become a challenge for scientists in different fields to find new antibiotics. Graphene and its derivatives, specially Graphene Oxide has gained attention in this area due to their unique physical properties. Graphene Oxide is considered to be a promising 2D nanomaterial for biomedical applications, due to its ease of production, stability in water, unique chemical and mechanical properties and its biocompatibility compared to other nanomaterials. In this study, graphene Oxide was synthesized using modified Hummers’ method. In order to investigate the... 

Heat pipes are useful devices in heat transfer, renewable energies and cooling systems in particular. According to various application of this systems in different industries, performance improvement of this devices has gained much importance. Working fluid is one of the effective factors on pulsating heat pipes. Since heat transfer in PHPs is natural convection and two-phase, specific heat and thermal conductivity of working fluid have an important role in the performance of pulsating heat pipes. In the present study, the effect of using nano-encapsulated PCM along with reduced graphene oxid (RGO) dispersed in water and their mixture as working fluid has on the performance of PHPs has been... 

ZnO semiconductor has a wide band gap (3.3eV) and high electron mobility, making it a possible candidate for an effective structure-based Dye-sensitized solar cell (DSSC) semiconductor. Efficiency of DSSC based on ZnO is lower than TiO2 due to its low chemical satability. It is well known that the energy conversion efficiency of DSSC depends on the electron transport in the photoelectrode so in this investigation we fabricated high transport photoelectrode by doping Al in ZnO nanostructures. DSSC based on Al doped and undoped ZnO nanosheet synthesized by electrochemical deposition. Current density-voltage (J-V) characterizations indicate that Al-doping in ZnO crystal structure increases... 

The sustainable development in societies and the global energy challenge requires usage of clean energy systems that have attracted the attention of many researchers in recent decades. One of the major challenges in generating renewable resources is the problem of energy storage and imbalance between supply and demand cycles. Hydrogen as one of the clean energy carriers and due to having the highest energy density in terms of weight, is one of the important research topics. From this point of view, the preparation of electrocatalysts for hydrogen production, based on available materials, via simple and environmentally friendly production methods, was considered in this research.... 

New methods of cancer treatment are always the attention of researchers all over the world, among which the photothermal treatment method is of particular importance. In addition to being easy, this treatment method has the least invasiveness. Studies have shown that combining this method with other methods such as chemotherapy not only can be very effective in destroying tumor tissue, but can significantly reduce the side effects of chemotherapy drugs.In order to apply the photothermal treatment method, an effective photothermal agent is needed. Molybdenum disulfide nanosheets have performed successfully in this field, which have been of great interest, due to their high efficiency in... 

In this research, Synthesis, characterization and photoelectrochemical application of two dimensional MoS2 and WS2 nanosheets have been carefully investigated. And finally, based on theoritical and experimental analysis results, the mechanisms of the observed photoelectrochemical (PEC) activities were suggested.The ab initio density functional calculations about Mo1-xWxS2 monolayer deposited over a TiO2 (110) substrate revealed a shift in band position of the Mo1-xWxS2 in favor of photoelectrochemical water splitting. Moreover, increase of W concentration in Mo1-xWxS2 could improve the charge separation and increase the effective mass ratio leading to an extension of the electron–hole... 

In the first part, we report a new and simple procedure for preparing reduced graphene oxide /nickel, cobalt hydroxide composite (Ni,Co-OH/rGO/NF via a fast and simple two-step electrochemical method including potentiostatic routes in the presence of Cetyl trimethyl ammonium bromide )CTAB( as a cationic surfactant. In the first step, a piece of nickel foam (NF) is sonicated in a suspension of graphene oxide (GO, 6 mg/L) after dried in an oven, reduced by electrochemically. After that, Ni, Co LDH were co-deposited on the surface of rGO/NF. The resulting modified electrode afforded extremely high specific capacitance of 2133.3 F/g at a current density of 4 A g-1. FE-SEM results showed that... 

Transition Metal Dichalcogenids (TMD) are types of 2D materials that exibit wide range of electronic, optical, mechanical, chemical, and thermal properties. These materials with MX2 general formula, have atract attentions with respect to their unusual properties because of their very limited dimensions. Their tunable properties and materials availibility make them attractive for wide range of applications. In recent years, chemical vapor deposition (CVD) methods are promising in preparing high quality TMD with scalable size, controllable thickness, and very excellent electronic properties. Also, chalenges are remaining in synthesis and transfering of TMD are difficulty for most of... 

The main purpose of this project is synthesis of the silica nano-sheets by means of microfluidic techniques. Continuous process, precise control of reaction condition, and higher production rate can be considered as main pros of silica nano-sheets synthesized by microfluidic platforms. General method can be explain as follow: first two oleic and aqueous phase are injected to the microfluidic system, then oleic phase breaks down in aqueous phase drop-wisely and by performing sol-gel reaction on the oil-water interface a silica crust is made on oil droplets. Eventually, oil droplets are left the system and broken down and silica nano-sheets are made. FESEM and microscopic images of... 

Nanotechnology with the tools, materials and their applications in areas such as engineering mechanics, materials, electronics, computers, and machines at the nanoscale is dealing. The Fnarvy, atoms and molecules as building materials, engineering bricks counts. In mechanical engineering branch, two aspects are discussed in view of nanotechnology, nano-scale structures and analyzing the behavior of phenomena that occur at the nanoscale. In this project, methods to analyze the behavior of nanoscale materials has been studied.
The present thesis examines the natural frequencies of nano graphene sheets on elastic foundation deals. The elastic foundation modeled with two springs.At first The... 

Recent years have witnessed an increasing interest in graphene and graphene-based materials due to their extraordinary electrical properties, large specific surface area, fascinating mechanical properties, good chemical stability and remarkable electrochemical activity. The combination of these properties make graphene an attractive candidate for a wide range of applications including energy conversion and storage devices (batteries and supercapacitors), electronic devices (transistors and memory devices) and solar cells. On the other hand, graphene has a potential application in constructing different kind of sensors such as biosensors and electrochemical sensors due to its planar... 

Development of electronic industries, compression of electronic equipment, and removing lead from electronic circuits for environmental reasons, a significant challenge was created in the design and development of tin-based lead-free solders with physical and mechanical properties close to old tin-lead alloys. In this regard, the set of Sn-Ag-Cu alloys with eutectic composition and related compounds have been proposed as alloys to replace Sn-Pb solders. As a lead-free solder alloy, low melting point (≈217℃), high reliability of joints, and compatibility with various fluxes are among the properties of this category of alloys. In order to improve the mechanical properties of the joint... 

Nowadays, beside of two-dimensional tungsten disulfide nanosheets, its hybrid nanostructures also provide active sites for physisorption of gas molecules due to their high surface-to-volume ratio, surface active site (such as sulfur vacancies, surface defects, and p-n junctions) and active edges, and are very attractive for gas sensing applications. In this research, tungsten disulfide layered crystallines were grown by chemical vapor phase transport and its two-dimensional nanoflakes were prepared by liquid exfoliation method. So, a thin film of the nanoflakes was deposited on a silicon oxide substrate by drop casting method, and its gas sensing properties were investigated for water and... 

In this research, synthesis and characterization of photocatalytic properties of g-C3N4 / TiO2 nanocomposite was carried out. The target of research was to increase the photocatalytic properties of g-C3N4. So at first, g-C3N4 was synthesized from melamine precursor via thermal pyrolysis. Then, TiO2 nanoparticles were synthesized via sol – gel method. g-C3N4 / TiO2 nanocomposite with heterojunction structure was synthesized in one step by thermal pyrolysis of certain amounts of melamine precursor and TiO2 nanoparticles mixture in 550 ℃. Characterization of synthesized samples was carried out by XRD, FT-IR, UV-Vis, PL, BET, DLS and FE-SEM tests. Characterization results showed that g-C3N4,...