Sharif Digital Repository

The produced crude oil from the petroleum reservoirs usually has a value of brine (water and salt) this matter can be caused the corrosion of refinery equipment. The large part of this brine creates a stable emulsion with oil, that it couldn't be separated easily. For separation and demulsification of this emulsion, some chemical, mechanical, thermal and electrical methods can be executed. In chemical method, demulsifier materials can be added to water-in-oil emulsion. Different parameters such as properties of oil, type and concentration of demulsifiers, volume factor of water and etc., can affect the efficiency of water-in-oil emulsion separation. In this study, emulsification mechanism,... 

Today, the determination and therapy of numerous illnesses, including malignant growth, relies upon the information and assessment of platelets, so blood testing and cell examination is fundamental to survey the movement of disease. The lab on a chip innovation is utilized as an extremely productive device in cell studies. The lab on a chip is used as a foundation and a substrate for making a legitimate stream for cell processes in medication. This innovation is a gadget or framework with millimeters or centimeters aspects like a chip, and it performs research facility handling on a micron-scale. In spite of the fact that it has a few impediments, it has so many values; for example, it... 

A new microfluidic device is introduced for sorting the particles based on the hydrodynamic resistance induced in a microchannel which is not needed for additional detection or sorting modules. Hydrodynamic resistance affects physical properties, such as size and deformability of the particle. This device could apply application in cell sorting for remedies, diagnostics, and industrial applications. The device design is performed using an equivalent resistance model, and also numerical simulations are performed. For validation of the results, they are compared with experimental results. Moreover, we will discuss threshold particle size and will introduce a way to approximate it to ... 

Supersonic separators with neither rotating parts nor chemical process, physically separate particles in a multi-phase flow. In comparison with general separation techniques, which are utilized in industries, specifically this equipment is cheaper, smaller and lighter. Condensation and separation at supersonic velocity is the key to achieve a significant reduction in both capital and operating costs. In this study, a two dimensional de Laval nozzle and few three-dimensional supersonic separator have been modeled. The 3D models modified in shape and dimensions. Impellers were created to form swirl flow. The models were simulated by the use of CFD software ANSYS FLUENT. Diverse inlet pressures... 

One of the newest technologies in order to separate oil from water and also oil wastewater is the axial vortex separator technology (with commercial name of voraxial). In the current project, we analyze one of the voraxial (2000) separator systems types. In the modeling of voraxial system, we utilize a 3D model which is developed on the basis of commercial sample of voraxial 2000 technology, and conduct the solution of particles and fluid with Lagrangian Eulerian approach. Considering the k-ɛ turbulence model and an incompressible flow with the input of 30GPM and rotational velocity of 400RPM was another segment of the project. Due to the largeness of 10µ particles diameter, the Brownian... 

Chemical dispersants applied to the surface of Persian Gulf during the oil spill in 2010 were more than one million gallons. Following the addition of dispersants, oil mixes below the seawater surface and can be degraded or dissolved into the water column. The aforementioned condition is a perfect opportunity for degradation of organic pollutants using Ultraviolet light emitting diodes Advanced Oxidation Processes (AOPs). These methods are based on activation of oxidants such as persulfate and hydrogen peroxide to generate extremely reactive radicals. Dispersants would increase the degradation rate by providing more active area (homogenous solution) for these radicals. AOPs have shown to... 

Composite membranes are one of the promising membranes for overcoming the limitations of conventional membranes in gas separation application by improving the permeability and selectivity. However, it is still very challenging to achieve adhesion interface between the top selective layer and the bottom support layer. The present study demonstrates that this challenge can be overcome appropriately by utilizing a series of adhesive polymer as selective layer to prepare composite membrane. To this end, in the first section a series of acrylate-terminated polyurethanes (APUs) based on poly(ethylene glycol) (PEG) with different molecular weights (Mn) of 600, 1000, 1500, 2000 and 4000 g/mol,... 

Natural Boron consists of two stable isotopes, 10B (19.3%) and 11B (80.7%). 10B isotope has a large thermal neutron absorption and therefore, use widely in such aspects as modern industry, atomic energy industry (as control rods, chemical shim and etc.), Medical science and applications in disclosing neutrons to measure neutron reactors fluxes. Boron trifluoride is most importantly used as a reagent in organic synthesis, typically as a Lewis acid. In this study, we designed and built the related setup for preparation of high purity BF3 gas. And then we tried to optimize the efficiency with process design tools such as response surface methodology (RSM). At the end of this study, we were able... 

One of the challenging issues in Iran's nuclear talks and Group 5+1 countries is the amount of Iran's enrichment capacity and the number of centrifuges needed to meet this demand. In this regard, Iran has recently announced that the basis for determining its enrichment capacity is the supply of fuel for the Bushehr power plant.Modeling and optimizing of gas centrifuge cascade is one of the most important problems in fuel cycle and isotope separation fields. To achieve this goal it is needed to comprehend of single centrifuge operation. Knowing the effectofsingle centrifuge parameters, it is easy to design a desired cascade. Minimizing the number of machines in the cascade is an anticipated... 

Uranium recovery from wastes produced in every stage of nuclear fuel cycle is very important from both the economic and environmental points of view. Zircon, zirconium-containing ore that is the input feed to Zirconium sponge production factories, contains considerable amounts of uranium compounds. The majority of this uranium will enter to the different waste streams of the plant. In this study, by analyzing the waste streams of the Zirconium Production Plant (ZPP) located at Isfahan, Iran, total mass balance of uranium in waste streams was identified. It was concluded that bottom residuals at furnaces of the chlorination unit is the primary uranium-containing waste stream. The preliminary... 

The most abundant source of deuterium, of course, is natural water. Other potential natural sources are natural gas and petroleum. Of these, natural water is by far the most significant. Until 1943, all the heavy water produced commercially was made by electrolysis. The largest single producer of heavy water was the Norsk Hydro Company, which operated the world's largest electrolytic hydrogen plant at Rjukan, Norway. In a detailed laboratory investigation of the effect of cell variables on the deuterium separation factor in electrolysis of water, Brun and co-workers [B13] have found that a: depends on the cathode material, electrolyte composition, and cell temperature, generally as... 

Lithium has two stable isotopes, 6Li and 7Li. Abundance of these isotopes are 7.53% and 92.43% respectively. Each isotope has an important role in nuclear industry. For example, 6Li compounds is used in production of tritium in nuclear fusion reactors coated with DT fuel and as fuel in nuclear fusion reactors that operate with laser inertial confinement method applied. 7LiOH is used to adjust the pH of the fluid coolant in light water reactors and also in Breeding Reactors. Lithium isotope separation in different ways so far been brought into operation. The other aspect to this work, it can be both continuous and batch for action. Lithium isotopes for the first time by electrolysis using... 

In the nuclear industry, gas centrifuges are considered of high importance for the purpose of uranium enrichment. Today, with advances in science and technology, the use of gas centrifuges for separating isotopes other than uranium, is so common. With respect to the use of conventional methods such as Pancake equation in calculating the velocity profile in centrifuges, it is needed that A^2=(MV^2)/2RT≫1 (M: Feed molecular weight; V: Peripheral speed of centrifuge; T: Mean temperature of feed; R: The universal constant of gases). While the molecular weight of the feed mixture gets lower, the A2 parameter gets closer to one. So, other methods for modeling the behavior of the gas in the... 

According to, increasing use of energy in the world, issues such as increasing reenhouse gas’ emission, rising temperature on planet earth and air pollution have appeared Carbon dioxide is a major greenhouse gas that has a significant impact on increasing the temperature of earth. In recent years, attentions to carbon dioxide capturring and sequestration technologies have been increased. In this project molten carbonate fuel cell which is used as a new method for separating carbon dioxide from gaseous compounds of combustion process, is discussed. The aim of the project is to, investigate technical and
economic feasibility of using molten carbonate fuel cell for separating carbon... 

The phenomenon of vortex flow, is one of the most predominant streams in the nature. This phenomenon yielded by the motion of vortices, produces up to 1000 times acceleration of the Earth’s gravity. The issues of uncontrolled harvesting of oil wells and increase the life of the wells, which cause to increase in the extracted crude salt, reveal the importance of waste management and both handling and refining petroleum. According to global statistics, for every extracted barrel of oil, three barrels of water are yielded. Therefore, 250 million produced water barrels per day is produced.The separator technology with vortex core (brand Voraxial) is one of the latest technologies in waste-water... 

Nowadays, the reduction of crude oil quality and the growth of environmental restrictions are the main challenges in oil refineries worldwide. The high demand of lighter refinery products and the shrinking market of the heavy products, highlighted the role of heavy residues conversion technologies.Gasification technology consumes these heavy refinery residues and produces clean syngas. By this way and the integration of gasification with power generation cycles, more value added products such as electrical energy, steam and hydrogen can be provided. For this aim to be achieved, three different scenarios are developed and investigated in this project. The first scenario includes the... 

Lithium has 9 isotopes which two isotopes are stable and remaining isotopes are unstable and have half-life. Lithium stable isotopes include 6Li and 7Li that their abundance is 7.53% and 92.47% respectively. Importance of lighter lithium isotope appears for its small cross section against thermal neutron and producing fusion reactors fuel in nuclear industries. Thermal neutron absorption cross section for 6Li and 7Li are 950 barn and 37 mbarn respectively. Interesting of these isotopes in nuclear industry is due to the large difference in the absorption cross section.6Li compounds implied for tritium producing in coat of nuclear fusion reactor with DT fuel. Following tritium is used in... 

Due to environmental and economical impacts, recovery of the uranium from nuclear wastes is of continuing interest.This work reports the separation of uranyl ionusing transport technique through chloroform liquid membrane containing a mixture of DBDA15C4 and oleic acidas cooperative carrier.The pH of the feed phase (10-4 M of UO22+) was adjusted with nitric acid and acetic acid/NaOH for pHrange of 2-6.The receiving phase was hydrochloric acid 1M.The organic phase was chloroform which includesthe carrier DBDA15C4 (0.0001 M) and also the oleic acid (0.015M).The results showed that the transport increased with increasing pH and reached to maximumat pH of 5.Maximum cooperative effect of oleic... 

Natural boron includes two stable isotopes 10B and 11B with 19.3 and 80.7 weight percent respectivley.10B isotope has a high thermal neutron absorption cross section. So isotope 10B material is suitable for making atomic reactor control rods. Other and even more important applications of 10B are in disclosing neutrons in order to measure neutron reactors fluxes and also are in nuclear physics laboratories and medical radiation. This isotope also is used in the pharmaceutical and the military industries. There are several methods for separating boron isotopes. Among the distillation methods, thermal diffusion of BF3, distillation of BF3, distillation of methyl borate, boric acid distillation... 

Natural boron consists of two stable isotopes, mass 10 (19.3%) and mass 11 (80.7%). 10B isotope has a large thermal neutron capture cross-section and it therefore, used widely in such aspects as modern industry, military equipment, medical science and so on. specially the demand of atomic energy industry for the boron isotope is increased severely. So the separation of 10B from natural boron has received very wide attention at present. There are many kinds of methods on the boron isotopes separation, such as chemical exchange reaction and distillation in boron trifluoride method, ion exchange in boric acid solution method, counter current recycle membrane cascades in boron trifluoride...