Sharif Digital Repository

The effects of Sr additions (0.3, 0.6 and 0.9 wt%) on the microstructural evolution, thermal stability, and mechanical properties of a cast Mg–4Zn alloy were investigated. The extent of grain growth and stability of the intermetallic compounds were studied by optical and scanning electron microscopy (SEM), respectively. Mechanical properties of the studied alloys were evaluated by shear punch testing (SPT) method and also the hardness test. Hardness and shear strength of the base alloy were increased by Sr additions in the as-cast condition, due to the grain refinement effect of Sr and also presence of the Sr-containing Mg17Sr2 and Mg70Zn25Sr5 precipitates. However, the optimum amount of Sr... 

Due to size minimization and increment in the frequency of electronic devices, efficient and reliable methods for thermal management are required to reduce operating temperature, enhance stability, increase lifetime and user comfort. To prevent the damages of leakage and corrosion which occur in conventional heat sinks, proposing innovative thermal management methods has always been welcomed. Regarding these issues and based on the energy storage unit concept, in this study, a passive heat sink (HS) is fabricated and characterized for electronic chipset cooling with heat fluxes of 2000 to 4000 W/m2 utilizing phase change material (PCM) and nano-additive PCM (NPCM). The presented cooling... 

Fabrication of an appropriate skin scaffold needs to meet several standards related to the mechanical and biological properties. Fully natural/green scaffolds with acceptable biodegradability, biocompatibility, and physiological properties quite often suffer from poor mechanical properties. Therefore, for appropriate skin tissue engineering and to mimic the real functions, we need to use synthetic polymers and/or additives as complements to green polymers. Green nanocomposites (either nanoscale natural macromolecules or biopolymers containing nanoparticles) are a class of scaffolds with acceptable biomedical properties window (drug delivery and cardiac, nerve, bone, cartilage as well as skin... 

Given the growing need for renewable energy and related technologies, researches have shifted to develop low-cost, stable, high-efficiency electrocatalysts in clean energy generation reactions such as water electrolysis. In the present paper, a three-dimensional Fe2TiO5/nitrogen-doped graphene (3D FTO/NG) nanocomposite is prepared using a simple, cheap and fast method, called chemical bath deposition (CBD). Structural and physical characterizations of the prepared electrocatalysts are performed by different methods such as Field Emission Scanning Electron Microscopy (FE-SEM), Energy Dispersive X-ray spectroscopy (EDX), Fourier Transform InfraRed spectra (FT-IR), Dynamic Light Scattering... 

Perovskite solar cells fabrication process need inert or low humidity atmospheres. While highly efficient perovskite solar cells to overcome the photovoltaic marketing should be achieved stability at any environmental conditions. At high humidity, water molecules react with the perovskite layer and increase the degradation rate, leading to a drastic decrease in device performance and perovskite crystallinity. In this work, the effect of environmental humidity on photophysical parameters of wide bandgap, (WBG) perovskite layer and solar cells stability is systematically investigated and tBP is proposed as an additive in perovskite precursor to increase the moisture resistance and improve the... 

This research investigates the effect of process parameters on the geometry and properties of In625 parts, manufactured by the direct laser metal deposition (DLMD) process. For this purpose, eight parts, consisting of 5 layers on top of each other, were manufactured, and the effect of laser power, laser focal plane position, and scanning speed on the height, width, and surface smoothness of each of them was investigated using design of experiment (DOE). The experimental results showed that the height of the parts manufactured by 800 W/mm and 200 W/mm of energy density is 3.69 mm and 6.12 mm, respectively. The thickness of the parts manufactured by 80 W/mm and 200 W/mm of energy density is... 

The aim of this research is the study of hexyltriphenylphosphonium bromide (HTPB) ionic liquid as a bifunctional promoter (solvent and catalyst) in the presence of cerium(IV) ammonium nitrate as a single electron oxidant for the Michael reaction at room temperature and solvent-free conditions. A novel, one-pot and environmentally benign the process to achieve the chemoselective of 2-(3-oxo-1,3-diarylpropyl)malononitrile derivatives instead of 2-(1,3-diarylallylidene)malononitriles using a three-component reaction involving acetophenone derivatives, various aromatic aldehydes and malononitrile was developed. This protocol is simple and provides biologically interesting products in good... 

Multistimuli-responsive hyperbranched polymers were synthesized in one-step polymerization using reversible addition-fragmentation chain transfer self-condensing vinyl polymerization (RAFT-SCVP). These hyperbranched polymers responded to UV-vis or sunlight, pH changes, and temperature changes. 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid known as DDMAT participated in esterification with 2-hydroxyethyl methacrylate to obtain a chain transfer monomer in the name of 2-((2-(((dodecylthio)carbonothioyl)thio)-2-methylpropanoyl)oxy)ethylmethacrylate (MACDT). For the first time, smart hyperbranched polymers were produced with the RAFT-SCVP method in one step by using... 

We conduct a study on the problem of fair allocation of indivisible goods when maximin share [1] is used as the measure of fairness. Most of the current studies on this notion are limited to the case that the valuations are additive. In this paper, we go beyond additive valuations and consider the cases that the valuations are submodular, fractionally subadditive, and subadditive. We give constant approximation guarantees for agents with submodular and XOS valuations, and a logarithmic bound for the case of agents with subadditive valuations. Furthermore, we complement our results by providing close upper bounds for each class of valuation functions. Finally, we present algorithms to find... 

Tunable microwave absorption characteristics are highly desirable for industrial applications such as antenna, absorber, and biomedical diagnostics. Here, we report BiNdxCrxFe1-2xO3 (x = 0, 0.05, 0.10, 0.15) nanoparticles (NPs) with electromagnetic matching, which exhibit tunable magneto-optical and feasible microwave absorption characteristics for microwave absorber applications. The experimental results and theoretical calculations demonstrate the original bismuth ferrite (BFO) crystal structure, while Nd and Cr injection in the BFO structure may cause to minimize dielectric losses and enhance magnetization by producing interfacial defects in the spinel structure. Nd and Cr co-doping plays... 

Rod-shaped samples of maraging steel were additively fabricated in vertical and horizontal directions using laser powder bed fusion technique. The samples were first aged at 490 °C for 6 h and then subjected to dynamic compressive tests using Split Hopkinson Pressure Bar apparatus. The dynamic compression tests were conducted on vertical samples at strain rates of 190, 460, 810, 1100, 1300 s−1. However, the high strain rate tests were performed at strain rates of 120, 615, 745, 890, 2200 s−1 on horizontal samples. After applying the compressive impact loads on the samples, it was found that although horizontally built samples exhibit higher dynamic strength, vertically built samples show... 

Herein, an efficient and sustainable one-pot, four-component access to rhodanine-oxindole derivatives is achieved by a reaction between primary amines, carbon disulfide, ethyl chloroacetate, and cyano-substituted alkenyl oxindoles. The reaction was conducted without any harsh conditions as well as exhausting workup in polyethylene glycol (PEG) as a green solvent at room temperature and delivered rhodanine-oxindole products in high yield. This publication is the first easy protocol to be reported for the rapid construction of new rhodanine-oxindole derivatives at room temperature without harsh conditions and via multicomponent reaction. © 2021 Taylor & Francis Group, LLC  

The aim of this research is the study of hexyltriphenylphosphonium bromide (HTPB) ionic liquid as a bifunctional promoter (solvent and catalyst) in the presence of cerium(IV) ammonium nitrate as a single electron oxidant for the Michael reaction at room temperature and solvent-free conditions. A novel, one-pot and environmentally benign the process to achieve the chemoselective of 2-(3-oxo-1,3-diarylpropyl)malononitrile derivatives instead of 2-(1,3-diarylallylidene)malononitriles using a three-component reaction involving acetophenone derivatives, various aromatic aldehydes and malononitrile was developed. This protocol is simple and provides biologically interesting products in good... 

Nanofluids are widely used as the continuous phase during droplet formation in microsystems due to their impressive features such as excellent thermal, magnetic, and interfacial properties. Although it is well-known that nanofluids are susceptible to exhibit non-Newtonian behavior even at a low concentration of nanoparticles, effects of non-Newtonian behavior of nanofluids have not been studied on droplet formation thus far. In this study, oil-in-water droplet formation with a relatively high viscosity ratio of the immiscible phases was studied numerically in a T-junction microchannel. To inspect the non-Newtonian effects of aqueous nanofluids on droplet formation, empirical data on the... 

Conventional additives used in drilling fluid may have detrimental short- and long-term impacts on the surrounding environment. The employment of biodegradable green material in drilling fluid as alternative additives will eliminate these harmful impacts. In this study, acorn shell powder is proposed as a novel biodegradable additive for application in drilling fluid. First, the acorn shell powder was prepared and then characterized in terms of chemical structure, particle size, and morphology. The acorn shell powder, with four different concentrations, was then introduced into a water-based fluid; its functionality in the fluid system was evaluated with respect to rheological and filtration... 

In this article, a novel cooperative secondary voltage/frequency control considering time-varying delays and noises in fading channels is presented for an autonomous alternating current (AC) voltage sourced-based converter (VSC)-based microgrid (MG), including inverter-interfaced distributed generations (DGs). Fading phenomenon makes complex random fluctuations on the voltage and frequency of every DG received from its neighbor DGs. In multi-agent cooperative systems, in addition to the total additive noise and time-variant delay, a multiplicative complex random variable is considered to model the main received signal and its replicas due to multipath propagation. The proposed... 

In the present contribution, the capability of isotopic ratio mass spectrometry (IRMS) for saffron authentication and detection of four common plant-derived adulterants (marigold flower, safflower, rubia, and saffron style) was investigated. For this purpose, 62 authentic saffron samples were analyzed by elemental analyzer-IRMS (EA-IRMS) and gas chromatography-combustion-IRMS (GC-C-IRMS). In this regard, EA-IRMS and GC-C-IRMS isotope fingerprints of carbon-13 and nitrogen-15 isotopes of saffron components were provided and then analyzed by chemometric methods. Principal component analysis (PCA) showed two different behaviors regarding two main regions. Then, a representative saffron sample... 

In this research, the effect of surface characteristics on boiling heat transfer has been investigated experimentally. For this purpose, a device with the ability to automatically record the liquid temperature of the inlet and outlet of the test area, calculate the coefficient of boiling heat transfer, and heat flux has been developed. The automatic temperature stability of the working fluid and the ability to investigate the effect of surfaces with different characteristics (in terms of material and surface structure) on the boiling heat transfer parameters are the most important features of this device. The performance of the experimental setup was evaluated by the modified "Chen" equation... 

Heat pipes are useful devices in heat transfer and particularly, in cooling systems. Given the high demand for cooling systems in various applications, an improvement in the performance of heat pipes has gained much attraction in recent years. In this study, the effects of utilizing working fluids with different thermal properties on the performance of pulsating heat pipes (PHP) are experimentally studied. Hence, nano-encapsulated phase change material (NPCM), reduced graphene oxide nanosheets, and their mixture, as a novel hybrid nanofluid, are prepared and dispersed in water as a working fluid. NPCM at 3 concentrations of 5, 10, and 20 g/L, as well as nanosheets at three concentrations of... 

Peridynamics is a nonlocal theory of solid mechanics which is suitable for modeling discontinuities and fractures without requiring external theories. In the original peridynamic equation of motion, the internal forces are integrated over the entire domain of the body. Although this equation complies perfectly with physical principles, its heavy calculations make it practically impossible to use. To avoid this difficulty, we can benefit from a special case of the peridynamic equation of motion in which the integration domain of the internal forces is limited to the family of particles. A limitation of this special equation, which is the most common equation in the peridynamic literature, is...