Sharif Digital Repository

Smart coatings which prevent corrosion by several mechanisms recently have been carefully planned. One of these mechanisms is the use of ion exchangers like Layered Double Hydroxide (LDH) in the coating network. In this study, the LDH containing a kind of green inhibitor (sodium molybdate) was synthesized and utilized in a Poly-Vinyl Alcohol (PVA) base coating applied on the aluminium (5054 series) surface. After evaluating the LDH performance, the inhibitor release from the LDH crystals was examined by changing significant parameters like MII/MIII (the molar ratio of divalent ions into trivalent ions), pH, aging time and temperature. Considering the LDH morphology or the thickness of the... 

In recent years, nanodiamond (ND) has been used as reinforcement in polymeric nanocomposites in order to improve mechanical properties, thermal conductivity, etc. The surface of nanodiamond has several functional groups which make it appropriate adsorbent. In this study, nanodiamond was modified with dodecylamine corrosion inhibitor and was utilized (1wt %) in epoxy based nanocomposite. Fourier transform infrared spectroscopy (FTIR) analysis was used to confirm the surface modification of Nanodiamond. In order to estimate the loading amount of corrosion inhibitor, thermogravimetric analysis was investigated. FE-SEM analysis demonstrated nanoparticle dispersibility in epoxy matrix. Regarding... 

Nowadays, proper design and retrofitting of structures against natural and manmade disasters, is among the main concerns of researchers and designers in order to reduce financial and human costs. Extensive research has been carried out on the structures resistance against earthquake up to now. Although, the vast amount of research has resulted various regulations and guidelines, there is still a long way ahead to achieve the desirable results. Due to high sensitivity of the steel to temperature variations, fire exposure is more destructive for steel structures compared with the concrete ones. The performance of an intermediate three-storey steel moment frame with 4 spans was studied in this... 

In this paper, a finite element formulation is presented to study the thermoelastic behavior of Functionally Graded (FG) axisymmetric coating in shell structures. The power law distribution model is assumed for the composition of the constituent materials in thickness direction. The Plasma Spray with multi steps coating method is considered for coating method. The procedure adopted to derive the finite element formulation contains the analytical through-the-thickness integration inherently. So the explicit through-the-thickness integration becomes possible after defining a two-noded, three parameters degenerated axisymmetric FG element. The nonlinear heat transfer equation is used for... 

Plasma electrolytic oxidation (PEO) was implemented to produce a ceramic coating on AZ31 magnesium alloy, using an alternate power source (AC), in a silicate based electrolyte containing zirconia nanoparticles in different concentrations. Prior to adding nanoparticles to electrolyte, working parameters such as current density, frequency and coating duration were examined and studied concerning the equipment and coating conditions. And after reaching the optimized condition, ZrO2 nanoparticles were added to the electrolyte to create composite coatings. To examine the properties of the coatings before and after the creation of composite PEO coatings, scanning electron microscopy (SEM) was used... 

In this study TiO2/SiO2 thin films were prepared by sol-gel method from Tetra isopropylortho Titanate(TIPT) as the principle of TiO2 material with Tera ethoxysilane(TEOS) as the principle of SiO2 material to achieve high scratch-resistant , antibacterial and self-cleaning surface area under the effect of various percentage of SiO2 . Film deposition was carried out using a dip-coating technique and heat-treatment was used at 700ºC to achieve crystalline of films with excellent adherence the of substrate.
The surface morphology of the films has been observed by Scanning Electron Microscope (SEM) and the tribological properties of the surface were investigated by Atomic Force Microscope... 

With the increase in the average age of the world's population, osteoporosis is a worldwide incidence. This disease, along with natural disasters, are important factors in the occurrence of fractures in various bones of the body. One of the methods for solving this problem and replacing with broken body bones is the use of metal implants with hydroxyapatite-based coatings. One of the common problems with using implants in the body is the infection in the adjacent parts of the implant. To overcome this problem, several studies have been carried out on the use of hydroxyapatite coatings with metal ions or antibacterial oxide compounds. In the present study, the influence of factors such as the... 

In this study, cationic polyurethane resin was synthesized by use of the reflux technique under N2 atmosphere. At first TDI was reacted with GMS to form prepolymer with terminal –NCO, also DBTDL was used as catalyst. This prepolymer was then reacted for chain-lengthening with N-methyl diethanolamine compound containing tertiary nitrogen atoms. The chain-lengthened product was then converted into an ammonium compound or cationic compound, by reacting with HCl as reactive hydrogen containing compound. The structure of product was studied by FT-IR spectroscopy. Then the cationic product was used as adduct resin with commercial tow-components polyurethane with proportion of 25%wt, 50%wt and... 

Today, the process of corrosion and compensation of minor injuries, without the need for tracing or any other physical interference, has become one of the subjects of interest to researchers. Inhibitors have been considered as one of the anti-corrosion agents. In this research, safflower extract as a green inhibitor in sodium chloride corrosive environment was used to evaluate the rate of corrosion of mild steel. Also the MoS2 nanoparticles were used as carrier of this green inhibitore in the epoxy coating to allow the activation of the coating in a scratched state in sodium chloride solution of 3.5%. In the first step, the extract of the safflower was prepared to reach the best part of this... 

Process of casting with evaporative patterns and unbonded sand is a new method that due to different economic, environmental and technological benefits is considered to large and small industrial parts manufacturing in recent years. Different parameters are effective on the surface and metallurgical quality in this process, such as foam density, sand type and size, level and mode of vibration, sand compaction, coating and pouring time and temperature. If coating permeability that is function of type, thickness and concentration of coating is chosen improper, pyrolysis vapor of foam don’t exit completely and in this condition carbon of vapor deposit on the metal surface and produces defect... 

Casting process with foam is a relatively new process which because of having multiple benefits (like elimination of muscle and segregation line, high dimensional precision and using sand without using glue) in recent years has been considered. Considering that during pouring, melt replaces with sand surrounded foam, successfulness of this method depends on complete elimination of foam model during Pouring for preventing formation of some defects like carbon defects in cast irons, or cold work and porosity in aluminum alloys. Parameters like Pouring temperature, alloy type, foam type, density of foam model, type of gating system, and some other parameters are affecting the way of filling of... 

The main purpose of this study is simulation of in-situ release of nano-size coated polymer particles at the water-oil interface during the polymer flooding. Reaching at the flooding interface, the hydrophobic coating starts dissolving into the oil phase. Subsequently, the hydrophilic core polymer starts diffusing back and simultaneously solves into the water phase and increase the in-situ viscosity of the flooding interface. Because of the in-situ release of the polymer and consequently the viscosity reduction of the injected fluid, the driving force for injection of the polymer as well as the amount of polymer used in flooding will reduce. In addition, smart coating can decrease the... 

In this thesis the effects of vibro absorbing coating on vibration behavior of an aluminum sheet and also on a stiffened aluminum panel are investigated using experimental approach. Since there wasn't any information available about the used coating, to find its viscoelastic material properties, the method mentioned in ASTM E756-05 standard is employed and corresponding tests are performed.
In the next step, an analytical solution developed for the aluminum sheet with viscoelastic coating and the obtained results compared with experimentation, in order to find its prediction accuracy for loss in “loss factor” of the system in presence of coating.
To study the effect of... 

In the present study, it has been tried out to increase the hardness and wear resistance of anodized aluminum coating byadding Si3N4 nanoparticles to the anodizing bath and making a composite coating. In order to investigate the influence of other effective parameters on the properties of anodized coating before the compositing process, hardness and thickness were optimized in the Sulphoric/oxalic bath using design of experimental method (central composite design). The properties of these coatings are dependent on various parameters among which time, temperature and pulse current parameters (current density limit, frequency and duty cycle) were considered in the present study. Analysis of... 

In this project, graphene oxide was produced by chemical method (modified hummers method) because of simplicity and reproductiblity in the manufacuring process. Zinc nanoparticles were produced from pure zinc anode in the graphene oxide solution (anodic dissolution). Nanocomposite coating of reduced graphene oxide – zinc was created by electrochemical reduction with voltage pulse. Optimization of corrosion current density of the coating was done by design of experiments software (central composite design). To achieve this goal, several parameters such as cycles of zinc dissolution, frequency, duty cycle, total time of coating and applied voltage were examined. Using analysis of variance... 

In this study performance of tack coat (thin layer bonding asphalt concrete layers) was evaluated. The shear strength of tack coat layer was considered as its measure of performance. Direct shear tests were conducted on two layered HMA specimens. The test variables included the type of tack coat material, application rate (amount of residual bitumen per unit area), substrate condition, normal stress and shear loading rate. Four types of liquid asphalt (CSS, CRS, modified CRS and MC-250) were applied as tack coat. Three substrates conditions were used in the tests. These were 3-days old, 17-days old and long term aged substrates were used. It was found that optimum application rate depends... 

At a unit in zirconium production plant under the supervision of Soure Co. nuclear grade zirconium is produced. In the process it is required that hafnium get separated from Zirconium. Zirconium and hafnium separation are performed by nitric acid (4N) and hydrochloric acid (4N). This isolation environment is considerably corrosive and damaging for the equipment. Powder coating is one of the solutions to deal with the corrosion. To do so, electrostatic powder coating method was used for ECTFE polymer. After the coating, according to spark test, roughness analysis, thickness, elasticity and adhesion; temperature and time of the spraying and the spraying of top coating was determined. In... 

Ni-Co/SiC composite coatings with various contents of SiC nano particles were electrodeposited in a modified watt type of Ni-Co bath containing 20 nm SiC nano particles to be codeposited. The influences of the SiC concentration, current density, stirring rate of the deposition bath on the composition of the coatings were investigated and these parameters optimized for highest amount of SiC codeposition. The optimized deposition parameters were 40 g/l SiC and 480 rpm stirring rate and current density equal to 4 A/dm2. Ni-Co/SiC composite coating was deposited with the maximum particles content of 30.5 volume percent. Linear voltammetry demonstrates addition of the SiC to the Ni-Co deposition... 

Recently, Aluminum alloys have been the materials of choice for both military aircraft and automotive industries due to their high strength-to-weight ratio, high electrical and thermal conductivities and excellent corrosive resistance. However, their applications have been limited due to the low yield stress and wear resistance. In order to improve the surface wear resistance, structural and chemical surface modifications such as producing composite coatings could be applied. Gas Tungsten Arc welding (GTAW) process can be used to produce alloy and composite surface layers on different substrates. In this research, GTAW process and aluminum cored wires were used for coating of Al/Al3Ti...