Sharif Digital Repository

Metal-oxide gas sensors are widely used for detection of detrimental H2S gas. Among them, SnO2-CuO system has been proved to be an excellent candidate. The previous theoretical 2D thin bilayer model was able to explain some aspects of H2S sensing performance of this promising system. However, experimental researches have indicated that response values for this system are very diverse and various SnO2-CuO multicomponent heterostructures such as rods, wires and particles have much higher response than their thin bilayer counterparts. Understanding the reason behind this differences would help fabrication of optimized sensor element. However, the previous model cannot address this issue mainly... 

Ultra fine CuO nanoparticles In the range of 2 ± 0.2 nm were synthesized by the supercritical hiydrotliermal method in a batch reactor. Itwas demonstrated that elevating the pH of the Cu2+ precursor solution to around 6 (neutral condition) not only does not lead to excessive agglomeration of the particles, but also reduces particle size and in general promotes their nanoscale characteristics. Prepared nanoparticles were immobilized in the biopolymcric matrix of barium alginate and calcined at different temperatures resulting in micro spherical granules of high porosity and elevated mechanical strength. The fabricated samples were characterized using x-ray diffractometry (XRD), transmission... 

In this paper, the effect of highly conductive copper oxide nanoparticles on the effective thermal conductivity (ETC) of rock samples was mathematically investigated. To solve the governing conservation equations for the ETC a commercial finite element package (COMSOL Multiphysics) was used. It should be stressed that the single-phase approach was employed to mathematically model the effect of nanofluid on the heat transfer improvement. The computational geometry of the rock samples was obtained by analyzing the microscopic images of the limestone rock samples. The results obtained from the mathematical modeling of the rock samples showed that the conductive heat transfer through porous... 

Here, cobalt oxide nanostructures synthesized on vertically aligned copper oxide nanowires (NWs) have been investigated as a possible anode material for Lithium-ion batteries (LIBs). Copper oxide NWs were formed by thermal oxidation of electrochemically deposited copper on the stainless steel mesh substrate. The process used allows the formation of highly dense copper oxide NWs with excellent adhesion to the conductive current collector substrate. A simple hydrothermal method was implemented for the deposition of cobalt oxide nanostructures on the copper oxide NWs. The as-prepared binder-free copper oxide@cobalt oxide NWs electrode exhibits a high initial specific capacity of 460 mAh g-1 at... 

Evolution of renewable energies in the era of the modernized world has been strongly tied up to the incessant development of high-performance energy storage systems benefiting from both high energy and power densities. In the present work, binder-free positive electrodes are fabricated via a facile electrochemical deposition route in which copper oxide nanorods (CuO NRs) directly grown onto the copper foam (CF) are decorated with bimetallic cobalt-zinc sulfide nanoarrays (Co-Zn-S NAs). The fabricated Co-Zn-S@CuO-CFs represent promising specific capacity of 317.03 C.g−1 at 1.76 A.g−1, along with superior cyclic stability (113% retention after 4500 cycles). Negative electrodes were further... 

By fabrication of several bolometric detectors on the YBCO film made of Metal-Organic Deposition (MOD) and the effect of pattering and film parameters on the optical responsivity of transition edge sensors is investigated. The low cost nonfluorine (MOD) method has been applied to fabricate YBCO thin films with different patterning parameters. The measurement results of the optical responsivity versus modulation frequency up to 100 KHz for these devices are reported  

A simple, efficient, and practical procedure for the synthesis of imidazo[1,2-a]quinoline and quinolino[1,2-a]quinazoline derivatives using CuO nanoparticles as a novel catalyst in excellent yields is described. The catalyst can be recovered conveniently and reused at least four times without any loss of activity  

A RF SQUID electronic system has been implemented which works at the frequency range of 650MHz to 1GHz. By incorporating particle swarm algorithm for the optimization of the system parameters, the readout system could automatically set its parameters for a desired RF SQUID. Using the implemented system, the noise characteristics of a RF SQUID gradiometer is being measured. The measured flux noise of the High-Tc YBCO magnetometer is below 100μ Φ0/ √ Hz at 100Hz in unshielded environment  

CuO flower-like microcrystals, prepared by a facile template-free thermal method, showed incredible photocatalytic activity towards degradation of Acid Blue 92 (AB92), an organic wastewater, Escherichia coli and Staphylococcus aureus pathogenic bacteria under visible light. The products were well characterised by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscope (SEM), Fourier transform infrared (FTIR), photoluminescence spectroscopy (PL) and diffuse reflectance spectra (DRS) analysis methods. The XRD pattern of the products well confirmed the formation of copper oxide crystalline phase without any other impurities. The results of the photocatalytic... 

SnO2-CuO is one the most promising systems for detection of detrimental H2S gas. Although previous experimental research has suggested a sulfidation reaction to explain selectivity toward H2S, little is known about the origin of change of electrical response of this system by changing the H2S gas concentration. In this study the relation between sensing response of continuous SnO2-CuO bilayer thin film and H2S gas concentration is computed based on changeability of chemical composition of covellite CuxS. For this purpose, chemical activity of sulfur as a function of atomic fraction in covellite copper sulfide is estimated using Gibbs energies of formation and chemical thermodynamics. By... 

The effect on the thermal parameters of superconducting transition-edge bolometers produced on a single crystalline SrTiO3 (STO) substrate with and without a CeO2 buffer layer was investigated. Metal-organic deposition was used to deposit the 20-nm CeO2 buffer layer, whereas RF magnetron sputtering was applied to fabricate 150-nm-thick superconducting YBa2Cu3O7-δ (YBCO) thin film. The critical transition temperature for both of the YBCO films was 90 K, and the transition width was ∼1.9 K. The bolometers fabricated from these samples were characterized with respect to the voltage phase and amplitude responses, and the results were compared with that of simulations conducted by applying a... 

CuO flower-like microcrystals, prepared by a facile template-free thermal method, showed incredible photocatalytic activity towards degradation of Acid Blue 92 (AB92), an organic wastewater, Escherichia coli and Staphylococcus aureus pathogenic bacteria under visible light. The products were well characterised by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET), scanning electron microscope (SEM), Fourier transform infrared (FTIR), photoluminescence spectroscopy (PL) and diffuse reflectance spectra (DRS) analysis methods. The XRD pattern of the products well confirmed the formation of copper oxide crystalline phase without any other impurities. The results of the photocatalytic... 

Metal Organic Frameworks (MOFs) have received enormous attention in catalysis field due to their special structures and various promising applications. One of the intriguing applications of MOFs is utilization of them as precursors for synthesis of metal oxide nanomaterials. Base on this strategy, in this work, we have applied Cu-MOF to prepare a series of noble metal nanoparticles (Ag and Au) decorated CuO (M/CuO) as efficient catalyst. As-prepared nanocomposites were characterized by various analytical techniques and their catalytic performances appraised by using of the catalytic reduction of p-nitrophenol to p-aminophenol as a reliable model reaction. Experimental results suggest that... 

In order to achieve stable operation for a developed high-Tc SQUID-based magnetocardiography system, a two-stage active magnetic shielding technique is implemented. This technique is based on a combination of fluxgate and high-Tc SQUID magnetometers feedback loops. While two YBCO rf SQUIDs in a gradiometric configuration are used at liquid Nitrogen temperature as the main sensors for the heart signal detection and low-amplitude noise signals cancellation in one stage, a fluxgate is used to cancel large far-field environmental noise in the other stage feedback loop. The fluxgate sensors working in the fundamental mode under the optimized bias conditions have white noise levels less than 10... 

Nanowire arrays of copper oxide were first grown vertically using simple and cost effective thermal oxidation method on a copper foil. Subsequently, in order to deposit and grow PbS nanocyrstalline thin films on CuO NWs by utilizing the chemical bath deposition technique, these arrays were immersed as the substrate in the reaction solution consisting of Pb(NO3)2, (NH2)2CS and NaOH. The final products were characterized in detail by which the formation of uniform, unique arrays of CuO@PbS core–shell NWs was confirmed. Due to the nature of methods employed in synthesis of this hetero structure, the tuning of core and shell size and consequently properties of the novel structure is easily... 

Resistive sensors composed of SnO2 and CuO, are known to be highly efficient in detection of detrimental H2S gas in terms of sensitivity, selectivity and speed. Recently, dependency of electrical response of the sensor toward H2S gas concentration has been related to the selective mechanism (formation of CuS) by a theoretical model. Another important factor in design of gas sensors is the working temperature which so far has not been explicitly explained for H2S sensing process of SnO2-CuO system. In present study, origin of this temperature for SnO2-CuO thin bilayer based on the selective mechanism has been theoretically interpreted. For this purpose, Poisson, Laplace and continuity...