Sharif Digital Repository

In this research, we studied the effect of compatibilizer and short glass fiber on microstructure and mechanical properties of PBT/PC blends. Fisrt, Antioxidants and sodium pyrophosphate dibasic were used to suppress transesterification in PBT/PC Blend. The results showed that best composition occur when both of them are used. In the next step, we used 3%wt MBS (methyl methacrylate-butadiene-styrene) and saw that this weight percent of this compatibilizer doesn’t useful. Moreover addition of short glass fiber to PBT/PC was examined and the results showed that mechanical properties of composite are extensively increased. Also in this step, we proved this idea that we can replace some of PBT... 

Concrete structures require reinforcement and retrofitting because of possible mistakes in design or calculation, inconformity between plan and implementation, change in occupancy or applied loads, and decay. Development in technology, production of materials, and new methods play important roles in development of structure construction and reinforcement methods. Emerge of new materials creates great demand in studying, surveying, and determining design characteristic and criteria for these materials. One of these materials is FRP composite which is used in concrete structure reinforcement in different ways. In this laboratory research, the effect of external wrapping by GFRP composite... 

Recently, to improve the dynamic behavior of Reinforced Concrete (RC) slabs under impact load, the methods of externally bonding Glass Fiber Reinforced Polymer (GFRP) sheets to slab and internally reinforcing concrete by steel fibers have been proposed. Nevertheless, it is required to investigate the comparison between these two methods on response of RC slabs under impact loads. In this study, the influence of volume fraction of steel fibers, the number of GFRP sheet layers (one or two) and the arrangement of GFRP sheets (covering the whole or parts of surface), are examined. Performance of fourteen mm concrete slabs including one plain slab, one steel RC slab, three steel RC slabs... 

Ultrasonically assisted machining process has been introduced as an effective solution to improve machining quality of mechanical parts. This study aims to reduce the drilling induced delamination to increase mechanical properties of CFRP laminates. Delamination decreases the strength of laminates under static and dynamic loads. Drilling parameters (feed and spindle speed) and ultrasonic vibrations amplitude are chosen as design experiment factors. Taguchi design of experiments method is used to study the effect of input factors on drilling thrust force, delamination factor and residual strength of drilled laminates. Input factors are in three levels and Taguchi L9 array is utilized. To... 

In this thesis, we aim to study the elastic-plastic behavior of short fiber reinforced composites experimentally and analytically. The experimental investigation is applied to glass fiber-polypropylene composites (PP/GF). The samples are produced by injection process with maximum temperature of 190C. Fibers are randomly oriented in this procedure of fabrication. The samples are tested in tension, and the mechanical strength is measured by changes in fiber content. The Young's modulus is also investigated in these experiments.Also in this thesis, an analytical model for calculation of Young’s modulus of fiber reinforced composite materials is proposed. In this analysis a displacement field is... 

Today, microreactors come into focus due to their exclusive characteristics including high surface-to-volume, lower consumption of reagents and fast mixing. In this study, optimization of the Br-Li exchange reaction as a consecutive reaction using glass microreactor is investigated. To construct glass microreactor, laser ablation and thermal bonding method are utilized. In order to find the best yield and selectivity of the reaction, various parameters, such as solvent, equivalent ration of the two reagents, concentration of the reagents, residence time and flow rates of the reagents are examined. In addition, atomic force microscopy (AFM) analysis was used to determine the surface... 

By consideration of increasing demands to use implants and efforts to get technical knowledge and localization of this implants, considerable research in this field is needed. Therefore, presentation of a coating which is able to provide parameters needed for an acceptable implant is the aim of this study. In this direction, modification of surface of metallic implants in order to achieve nanotubes of titanium oxide, with the purpose of providing biocompatibility was done. On the other hand, because chronic infection of the implant’s surrounding is one of the main important reasons in rejection of implants, 〖TiO〗_2 nanotubes as a drug carrier were used in order to solve this problem. So,... 

Considering the operation of the current nuclear reactors and the country's policy to achieve 10,000 megawatts of nuclear power in the horizon of 1420, as well as the construction of research reactors, we will face a huge amount of radioactive waste in the coming years. Meanwhile, spent ion exchange resins constitute a large amount of low and intermediate level (LILW) solid radioactive waste produced from the nuclear industry. Therefore, appropriate precautionary measures should be taken for the immobilization and disposal of these radioactive wastes in order to ensure the sustainable development of the nuclear industry and the protection of the environment and human health. In this study,... 

In order to prevent electrostatic attraction on non-conductive surfaces, the most practical solution is to put antistatic coatings to reduce surface resistance. Nano tin oxide coatings are designed to produce surfaces with antistatic properties in the resistance range of 108-1012 Ω/cm. In this project, using a simple method, low temperature, without heat treatment and without the use of additive (dopant), tin oxide films with antistatic property were placed on the glass. Further, in order to obtain a coating with a suitable morphology and structure to increase the surface conductivity, the synthesis of tin oxide using the sol-gel method at ambient temperature was used. And to place the... 

Considering the operation of the current nuclear reactors and the country's policy to achieve 10,000 megawatts of nuclear power in the horizon of 1420, in the coming years we will face a huge amount of radioactive waste, the majority of which is waste with low and intermediate levels of radioactivity (LILW). A large percentage of the radioactive waste production in Bushehr power plant is concentrated waste with a low and intermediate level of radioactivity (about 70% by volume). Due to the commisining of phase 2 and 3 of Bushehr power plant in the coming years and the increase in the radioactive waste production, proper planning should be done for waste management in order to reduce the... 

This study has investigated the effects of different environmental conditions on the bond at the interface between two fiber reinforced polymer (FRP) layers. A total of 945 single lap splice coupons with three bond length were made using wet lay-up technic. There were used three unidirectional fabrics and one type of epoxy resin. A Uniaxial tensile test was performed on samples after 2, 4, 12, 20, 28, 36 and 48 weeks of exposure. Also series of test were conducted in order to determine the minimum lap splice length of single splice FRP samples. The experimental results indicated reduction of bond strength in glass specimens that was 17 % after 48 weeks of exposure while for same amount of... 

The following dissertation discusses Ionic Liquids (ILs) as an alternative to commercial surfactants for use in the Enhanced Oil Recovery process. Ionic Liquids came to researchers’ attention due to their environmental nature and their tolerance for high temperatures and salinity. In this work, firstly, an extensive literature review is carried out, and then, experiments are designed and performed to evaluate ILs’ surface activity and performance in a lab-scale EOR set-up. The Ionic Liquids used in this work consist of three types of methylimidazolium nitrate, [MIM]+[NO3]-, with three different alkyl chain lengths. This combination, and specifically the effect of nitrate anions on EOR and... 

bulk metallic glass Unlike metal materials that have a crystalline structure, amorphous glass is an amorphous material with an irregular atomic structure that simultaneously has the same physical properties as metals. Due to the absence of crystal defects such as dislocation and grain boundaries, these materials show unique mechanical properties such as high strength and elastic strain, abrasion resistance and proper corrosion. However, their plastic deformation is heterogeneous, concentrated, and accompanied by sudden failure. Unlike metals, these materials do not have a long-range crystalline order, and their atomic structure includes short-range and mid-range order. The short-range order... 

This study inspects the flexural response of RC beams at the presence of compressive GFRP bars as well as tensile bars. Total of 9 reinforced beams were investigated. Three values of tensile reinforcement percentage were considered. For each tensile reinforcement value, three types of compressive reinforcement were taken into account which are classified into zero compressive bars, less than tensile reinforcement value and similar to tensile reinforcement value. The concrete was used in this study is C45 and as a constant parameter.Specimens were tested with four-point bending method using the actuator equipped at the strong floor laboratory to attain maximum flexural strength and... 

Currently, using biocompatible and injectable polymeric microcarriers as one of the efficient methods to transfer cells and active agents has gained much attention for bone regenerative medicine. However, they have some drawbacks such as weak mechanical stability and lack of mineral materials, which are the major ingredients of the bone tissues. Accordingly, it is expected that mimicking the chemical and physical structure of bone tissues could be valuable in their medical applications. Herein, a new porous biodegradable microcarriers (MCs) made of silk fibroin-oxidized alginate-bioactive glass was fabricated by electrospraying method. Response surface methodology (RSM) was used to study the... 

Nowadays, with the increasing number of polyethylene terephthalate wastes, the issue of its recycling has become very important. Among the problems of polyethylene terephthalate recycling are its loss of crystallinity and mechanical properties. Recycled polyethylene terephthalate does not have the properties of new polyethylene terephthalate and using its mixture with other materials is an effective way to remove its waste from nature and return it to the production cycle. The aim of this study is to produce a mixture of recycled polyethylene terephthalate with polycarbonate and glass fibers with mechanical properties such as good impact strength, which ultimately leads to the production of... 

This research studies the feasibility of the BK7 optical glass milling process with ultrasonic vibrations. Due to the fragility of glasses, especially optical glasses, machining is very sensitive and complex. For this reason, it is necessary to think for the glass machiners to minimize the defects and failures of the process. So far, efforts have been made to reduce the defects caused by machining on brittle materials, such as increasing the speed of the period, reducing the feed rate of the tool, changing the geometry and the type of tool, the type of process lubrication, etc. In addition, other operations performed to improve the surface of the glass are of better quality, using hybrid or... 

Polycaprolactone (PCL) scaffolds and its composites containing bioactive glass particles (45S5) and TiO2 nanostructures with pre-defined and controlled external and internal architecture were prepared via an indirect three-dimensional (3D) printing process. The scaffolds had an interconnected structure with macro- (400-500 μm) and micro- (~25 μm) pores. Bioactivity, mechanical behavior and kinetics of tissue growth in 3D scaffolds were studied. The size effect of biogactive glass particles (6 μm, 250 nm, <100 nm) and morphology of titania nanostructures (spherical, tube, leaf-like, and flower-like particles) were elaborated. The biogactive glass particles with different sizes were prepared... 

The main purpose of this project is synthesis of the silica nano-sheets by means of microfluidic techniques. Continuous process, precise control of reaction condition, and higher production rate can be considered as main pros of silica nano-sheets synthesized by microfluidic platforms. General method can be explain as follow: first two oleic and aqueous phase are injected to the microfluidic system, then oleic phase breaks down in aqueous phase drop-wisely and by performing sol-gel reaction on the oil-water interface a silica crust is made on oil droplets. Eventually, oil droplets are left the system and broken down and silica nano-sheets are made. FESEM and microscopic images of... 

FRP rebars due to various properties such as high resistance to weight ratio, high corrosion resistance, high tensile strength, low weight, resistance to electrical and magnetic conductivity, and other desirable properties, have always been an interesting topic for researchers as an alternative to steel rebars in special conditions.In this research, a two-dimensional sway intermediate concrete frame with three stories and two bays reinforced with GFRP bars was designed and studied. Unlike previous researches and design codes, the compressive strength of the bars was considered in the design process. With computer coding in Matlab software, column interaction diagrams and a special contour...