Sharif Digital Repository

The g-C3N4/Fe2O3 nanocomposite was produced by the combustion synthesis. The product was characterized by x-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), Fourier-transform infrared spectroscopy (FTIR), Brunauer-Emmett-Teller study (BET), Ultraviolet-visible analysis (UV-vis) and photoluminescence measurement (PL). Effect of iron nitrate on stability and photocurrent density under simulated visible-light irradiation was determined. The highest photocurrent density obtained (4.25 μA/Cm2) was twelve times the pure g-C3N4. This improvement was due to a bandgap decrease, the specific surface area increase, reduction of the electron-hole recombination, and... 

Herein, cupric oxide (CuO)/graphitic carbon nitride (g-C3N4) is synthesized under microwave irradiation for enhanced photoelectrochemical (PEC) performance and photostability. A facile, one-pot method was utilized to directly deposit the nanocomposite onto FTO from a solution containing copper precursor and urea. Possible mechanisms of CuO/g-C3N4 formation and PEC performance improvement were examined via XRD, FTIR, FESEM, XPS, UV-Vis, and PL. Controlled amounts of urea determined the morphological evolution of CuO and the formation of a protective carbon layer, while its excess quantity converted to g-C3N4 in the presence of CuO. Through heat treatment of the nanocomposite, carbon-doped... 

In this research, synthesis and characterization of photocatalytic properties of g-C3N4 / TiO2 nanocomposite was carried out. The target of research was to increase the photocatalytic properties of g-C3N4. So at first, g-C3N4 was synthesized from melamine precursor via thermal pyrolysis. Then, TiO2 nanoparticles were synthesized via sol – gel method. g-C3N4 / TiO2 nanocomposite with heterojunction structure was synthesized in one step by thermal pyrolysis of certain amounts of melamine precursor and TiO2 nanoparticles mixture in 550 ℃. Characterization of synthesized samples was carried out by XRD, FT-IR, UV-Vis, PL, BET, DLS and FE-SEM tests. Characterization results showed that g-C3N4,... 

In this research, aluminum matrix composites (AMCs) reinforced by different contents of zirconium dioxide nanoparticles, graphite microparticles, and a mixture of both with various hybrid ratios, into a cold-rolled Aluminum1050 as base metal, fabricated by 4-passes friction stir processing. Observations show that the processing of composites reinforced by Gr particles is significantly hard due to the low friction coefficient of graphite resulting in the decline in the maximum temperature during the process and the type of base metal. The mixtures of graphite and zirconia resulted in more homogenous dispersion of particles in the matrix due to deterring a drastic drop in friction coefficient... 

Developing an efficient visible-light-driven photocatalyst is believed to be a practical solution for clean energy and environmental remediation. The present study aimed to broaden current knowledge of the graphitic carbon nitride (g-C3N4)-based plasmonic photocatalysts by decorating polydopamine-grafted g-C3N4 (PDA/g-C3N4) with silver nanoparticles (AgNPs). The ternary nanocomposite was prepared using a facile synthesis method, while XPS and electron microscopy measurements confirmed the homogenous dispersion of AgNPs on PDA/g-C3N4. It was revealed that AgNPs successfully reduced the recombination rate of photoinduced electron-hole charge carriers. The calculated bandgap energy was... 

Today, due to changes in lifestyle and environmental changes, the incidence of cancer is increasing worldwide. With the advancement of science and technology, humans have always sought ways to improve their quality of life and lifespan. The most common cancer related to bone tissue is osteosarcoma. One of the most effective treatment methods is photodynamic therapy. This method requires a photosensitizer with appropriate optical and biological properties. The ideal photosensitizer should be excited with light in the NIR range and produce ROS or active oxygen species. In this research, oxygen-doped graphitic carbon nitride modified by heterojunction with Mn3O4 was used as a photosensitizer.... 

Cancer is one of the most important problems that affects public health. If this disease is diagnosed quickly in the patient's body, it can be prevented and treated by determining the stage of the disease and establishing a treatment protocol. Magnetic resonance imaging (MRI) and fluorescence imaging (FI) are among the imaging methods. In order to increase the contrast of images, researchers have turned to the synthesis of materials under contrast agents, which improve diagnostic sensitivity. Synthesis of nanoparticles as multi-mode contrast agents can enhance imaging methods. In this research, the synthesis and characterization of the multifunctional Fe3O4-Mn3O4-LCysteine@g-C3N4 QDs system... 

In this research, the instability analysis of single-walled carbon nanotubes (SWCNTs) and graphitic shells conveying fluid is investigated based on the molecular structural mechanics. Using the reduced order models for fluid and structure, the dynamic behavior of carbon nanotubes (CNTs) conveying fluid is accurately modeled via a few number of lowest flow modes and natural frequencies and mode shapes of CNTs structure. In addition, the boundary element method (BEM) is used to model the potential flow. The molecular mechanics (MM) model is applied to modal analysis and driving the natural frequencies and mode shapes of SWCNTs. The effect of chirality on flow-induced instability is taken into... 

Fuel system is one of the most important parts of pulse detonation engine which has the responsibility of fuel, oxidizer and also purge gas in the different operational frequencies of engine. Although pulse detonation engines are sort of air breathing engines and purge gas and oxidizer one in the same unit in their structure, due to existence idea in the pulse detonation rocket engines coverage of functional condition, fuel, oxidizer and purge gas, will study it in three different structures.
In this study purpose is improvement of the pulse detonation engine of Sharif University which will provide as the possibility of safe functional condition and high operational frequency in... 

A global concern has arisen owing to rapid industrial development and population growth, resulting in energy scarcity and earth pollution. In this regard, developing green and sustainable methods for producing clean energy and solving environmental pollution problems have absorbed enormous attention. Among various auspicious strategies, semiconductor photocatalysis has been widely studied in recent years owing to its capabilities to obtain hydrogen as an energy carrier, to remove organic pollutants, and to reduce CO2 emission by converting solar energy into chemical energy. Recently, a metal-free semiconductor photocatalyst based on graphitic carbon nitride, g-C3N4, has received much...