Sharif Digital Repository

It is well established that the heavy oil components including asphaltenes and resins play vital roles on the interfacial tension (IFT) of acidic crude oil (ACO) and aqueous solutions. Therefore, this experimental work is designed to investigate the possible synergism between salt ions, resin, and asphaltene on the IFT of ACO/low and high salinity brines containing MgCl2/NaCl and CaCl2. The results demonstrate that a complex ion of MgCl2 - resin component created in the solution could occupy the sites at the interface at high MgCl2 concentration. However, the results show that on the contrary, the molecular arrangement of MgCl2 and asphaltene at low and high MgCl2 concentration could be... 

ABSTRACT: Pyrolysis, so-called devolatilization, is one of the first steps of all thermochemical processes occurring in an inert atmosphere. The authors discuss the main kinetic features of heavy oil pyrolysis, on the basis of the data derived m from a TGA analysis and by using a kinetic model. The samples were heated over a range of temperature from 400 K to 430°C at various heating rates between 10 and 80°C/min. Experimental results showed that the effect of time is considerable in the case of tar conversion, compared to char and gases  

In this work, high-pressure microscopy technique was used to measure the size and fractal dimension of asphaltene aggregates formed in different live oil samples at elevated pressures and temperatures. It was found that the asphaltene aggregates in live oil samples are irregular fractal-like structures with pressure−temperature-dependent fractal dimensions. By monitoring the variation of the fractal dimension and size of the asphaltene aggregates with pressure and temperature, the mechanisms responsible for asphaltene aggregation process at elevated pressures and temperatures can be well predicted. The range of fractal dimension of asphaltene aggregates in live oils is similar to that... 

Although alkaline-surfactant-polymer (ASP) flooding has proven efficient for heavy oil recovery, the displacement mechanisms and efficiency of this process should be discussed further in fractured porous media. In this study, several ASP flooding tests were conducted in fractured glass-etched micromodels with a typical waterflood geometrical configuration, i.e. five-spot injection-production pattern. The ASP flooding tests were conducted at constant injection flow rates but different fracture geometrical characteristics. The ASP solutions consisted of five polymers, two surfactants, and three alkaline types. It was found that using synthetic polymers, especially hydrolyzed polyacrylamide... 

The main issue in heavy oils enhanced recovery methods is to reduce their viscosity in order to get a better mobility. This is commonly obtained by blending the oil with light hydrocarbons. Co-solvents are good candidates to improve the hydrocarbon recovery efficiency especially in miscible processes. However, the effect of co-solvents on miscible flooding of heavy oil reservoirs at different pore geometries is not well understood. In this work different one-quarter five-spot network patterns along with those generated from reservoir rocks' thin sections were etches on glass surfaces. The models that had been initially saturated with the heavy crude oil were used to perform a series of... 

Thermal recovery by steam injection has proven to be an effective means of recovering heavy oil. Forecasts of reservoir response to the application of steam are necessary before starting a steam drive project. Thermal numerical models are available to provide forecasts. However, these models are expensive and consume a great deal of computer time. An alternative to numerical modeling is to use a semi-analytical model. The objective of the current study was to investigate thermal applications of horizontal wells for displacement and gravity drainage processes using analytical modeling as well as reservoir simulation. The main novelties presented in the paper are: a) the transient temperature... 

Water-in-oil emulsion usually forms during waterflooding in some heavy oil reservoirs. The composition and salinity of the injected water critically affect the w/o emulsion droplet size distribution, which control the emulsion stability and emulsion flow in porous media. The aim of the present work is to assess the effect of different sea water salinities on w/o emulsion stability through microscopic imaging. Therefore, w/o emulsions were prepared with different sea water samples, which were synthesized to resemble Persian Gulf, Mediterranean, Red Sea, and North Sea water samples. The results showed that log-normal distribution function predicts very well the experimental data to track the... 

Enhanced oil recovery (EOR) methods assisted by gravity drainage mechanism and application of sophisticated horizontal wells bring new hope for heavy oil extraction. Variety of thermal and non-thermal EOR techniques inject an external source of energy and materials such as steam, solvent vapor, or gas through a horizontal well at the top of the reservoir to reduce in-situ heavy oil viscosity. So, the diluted oil becomes mobile and flows downwards by gravity drainage to a horizontal producer located at the bottom of the reservoir. In this paper, a sector model of an Iranian fractured carbonate heavy oil reservoir was provided to simulate and evaluate capability of some EOR techniques such as... 

The strength of a newly formulated surfactant with an alkali and polymer (AS/ASP) to improve an acidic heavy oil recovery was laboratory evaluated by various flooding experiments. The comparative role of the parameters like chemical nature, surface wettability, salinity, temperature and injection scheme were explored at high temperature and pressure on Berea sandstone rocks. According to the results the anionic surfactant is capable of providing proper oil displacement under high salinity conditions around 15 wt%. Continuous monitoring of differential pressure response and effluents’ state clearly represented the formation of an emulsified oil in high saline solutions with both alkali and... 

The highly viscous property of heavy oil often causes problems in its transportation in pipelines. Mixing heavy oil with light oil as well as ultrasound treatment are viable solutions to this problem. In this study, extra heavy crude oil samples were first diluted with 0, 0.05, 0.1, and 0.15 mL/mL (0, 5, 10, and 15 vol%) of a light crude oil; then the mixture was irradiated by ultrasonic waves for 0, 5, 10, 15, and 20 min; finally the viscous shear functions of all mixtures was measured at different values of shear rate at different temperature levels. The results revealed that the minimum viscosity of the diluted extra heavy crude oil samples was obtained at 10 min of ultrasonic... 

The main objective of this study is to investigate the effect of temperature on asphaltene destabilisation (precipitation/aggregation) in live oils at elevated pressure conditions. Here, the asphaltene related experiments were performed using solid detection systems, high pressure microscope, and high pressure-high temperature filtration apparatuses in two Iranian light and heavy live oils with different characteristics and stability. The obtained results were interpreted in terms of asphaltene onset pressure, size distribution and average diameter of the aggregates, fractal analysis of the aggregates structures, and the amount of asphaltene precipitation. As well, the results of the... 

The performance of CO2 injection into a semi-heavy oil reservoir was investigated at reservoir conditions, using highly permeable sandstone in a complete series of PVT tests and coreflooding experiments. Analysis of involved parameters such as: injection rate, injectant type and reservoir pressure were also considered. Oil viscosity reduction and oil swelling are the most influential mechanisms of enhanced oil recovery in this process. The results demonstrated that CO2 injection would decrease the interfacial tension for the high permeable medium in the absence of capillarity, but this reduction may not improve the recovery drastically. One of the main important aspects of this work is the... 

In this work, the potential for the auto-ignition of Iranian heavy oil during in situ combustion (ISC) process conditions was studied. Kinetic studies were carried out using thermal analysis techniques. Effects of oxygen partial pressure, reservoir pressure, and clay on the auto-ignition condition were investigated. Based on the experimental results obtained, a kinetic equation was derived for each of the different oil samples in the presence of different sands. The effect of partial pressure of oxygen in the injected air showed that at atmospheric pressure, low temperature combustion (LTC) was initiated at 275°C. Also, enriching the injected air by oxygen lowers the initial LTC temperature... 

Water-in-oil emulsion usually forms during waterflooding in some heavy oil reservoirs. The composition and salinity of the injected water critically affect the w/o emulsion droplet size distribution, which control the emulsion stability and emulsion flow in porous media. The aim of the present work is to assess the effect of different sea water salinities on w/o emulsion stability through microscopic imaging. Therefore, w/o emulsions were prepared with different sea water samples, which were synthesized to resemble Persian Gulf, Mediterranean, Red Sea, and North Sea water samples. The results showed that log-normal distribution function predicts very well the experimental data to track the... 

The performance of CO2 injection into a semi-heavy oil reservoir was investigated at reservoir conditions, using highly permeable sandstone in a complete series of PVT tests and coreflooding experiments. Analysis of involved parameters such as: injection rate, injectant type and reservoir pressure were also considered. Oil viscosity reduction and oil swelling are the most influential mechanisms of enhanced oil recovery in this process. The results demonstrated that CO2 injection would decrease the interfacial tension for the high permeable medium in the absence of capillarity, but this reduction may not improve the recovery drastically. One of the main important aspects of this work is the... 

The Conventional Fire Flooding (CFF) process application feasibility on fractured carbonated reservoirs remained questionable. In this paper first combustion parameters and reaction kinetics of a naturally fractured low permeability carbonated heavy oil reservoir in Iran called Kuh-E-Mond applied to simulation study. After that, simulator has been validated with Kuh-E-Mond combustion tube experiment. Recovery mechanism in single block matrix is different from one in conventional model since oxygen first flows into the fractures and then diffuses from all sides into the matrix. Combustion of the oil in the fractures produces some water ahead of fracture combustion front which prohibits oxygen... 

The Steam Assisted Gravity Drainage (SAGD) process, a developed Enhanced Oil Recovery (EOR) process to recover oil and bitumen, has been studied theoretically and experimentally in conventional reservoirs and models and is found a promising EOR method for certain heavy oil reservoirs. In this work simulation studies of the SAGD process were made on different fractured models consisting of fractures in both Near Well Region (NWR) and Above Well Region (AWR) and even in the presence of networked fractures. At early stage of the SAGD process in fractured system, steam moves through the fractures first and then the matrix blocks are heated primarily by conduction and possibly some steam... 

Reservoir fluid modelling is one of the most important steps in reservoir simulation and modelling of flow lines as well as surface facilities. One of the most uncertain parameters of the reservoir fluids is the plus fraction. An accurate and consistent splitting scheme can reduce this uncertainty and as a result, enhance the modelling of reservoir fluids. The existing schemes for splitting plus fractions are all based on assuming a specific mole fraction-molecular weight distribution with predefined constant values that may yield inaccurate and inconsistent results. In this study, an optimization-based algorithm was developed to determine the aforementioned controlling parameters of the... 

A numerical framework was carefully developed to simulate the combustion of heavy-fuel-oil (HFO) in a large-scale boiler. The present numerical solutions were compared with the measured data of a laboratory benchmark test and on-site operational data of the chosen HFO-fired boiler. Next, the developed framework was used to perform sensitivity analyses aiming to reduce the NO emission from the HFO-fired boiler without any adverse effect on its combustion performance. Practically, this study focused on re-adjustments of 24 working burners, which could control combustion in the HFO-fired boiler. The early outcome showed that the boiler NO emission and its combustion performance could be... 

In this work, high-pressure microscopy technique was used to measure the size and fractal dimension of asphaltene aggregates formed in different live oil samples at elevated pressures and temperatures. It was found that the asphaltene aggregates in live oil samples are irregular fractal-like structures with pressure−temperature-dependent fractal dimensions. By monitoring the variation of the fractal dimension and size of the asphaltene aggregates with pressure and temperature, the mechanisms responsible for asphaltene aggregation process at elevated pressures and temperatures can be well predicted. The range of fractal dimension of asphaltene aggregates in live oils is similar to that...