Sharif Digital Repository

In present research, nanocrystalline Fe100-xSix (x = 6.5, 10, 13.5, 20 and 25 at.%) and Fe83.5Si13.5Nb3 alloy powders were prepared by mechanical alloying using high-energy ball milling. The resulting powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. According to the XRD test results, by increasing the milling time and/or the Si content the lattice parameter decreases and the internal microstrain increases. In addition, the specific saturation magnetization diminishes as Si content increases. The coercive forces of the as-milled nanocrystalline powders are much higher than those of corresponding Fe-Si bulk alloys with a minimum at 13.5 at.% Si.... 

In this study, the effects of milling time, chemical composition and heat treatment on microstructure and magnetic properties of nanocrystalline Fe-Si (6.5-25 at.% Si) alloys prepared by mechanical alloying have been investigated. The results show that increasing the milling time or the Si content, decreases the lattice parameter and increases the internal microstrain. The prepared powders mainly consist of micron-sized particles with an average grain size of less than 20 nm. The specific saturation magnetization values are slightly less than those of single crystal or conventional Fe-Si alloys and decrease as Si content increases. The coercive force values of the nanocrystalline as-milled... 

Nanocrystalline Al-4 wt% Cu alloy reinforced with nanometric Al2O3 particles was synthesized by in situ reactive milling of Al and CuO powder mixture. X-ray diffraction (XRD), differential thermal analysis (DTA) and transmission electron microscopy (TEM) techniques were employed to study the mechanically induced solid state reaction between the blended powders. The mechanical milling stages were studied by scanning electron microscopy (SEM), bulk density measurement and laser particle size analyzer. It was shown that the reaction between Al and CuO occurs progressively as the mechanical milling continues, leading to formation of nanoscaled alumina particles. The grain refinement of the... 

Electrocatalytic activity of electrodeposited nanocrystalline CoNiFe alloy in hydrogen evolution reaction (HER) was studied in 1 M NaOH solution. The steady-state polarization measurement and electrochemical impedance spectroscopy were used to determine the Tafel slope, the exchange current density and the activation energy. The simulation of the data obtained from these two methods, using a nonlinear fitting procedure, allowed us to determine the surface coverage and the rate constants associated with the mentioned reaction. The ac-impedance spectra measured at various overpotentials in the HER region exhibited three semicircles in the complex plane plots. The high-frequency semicircle was... 

WO3-SiO2 compound thin films were deposited on glass substrates using the sol-gel method, and then all the samples were dried at 100 °C and annealed at 400 °C in air. The effect of WO3 concentration on the hydrophilicity of WO3-SiO2 compound films was studied for the first time and it was shown that the films containing 85 mol% of the concentration possessed a superhydrophilic surface without UV or visible irradiation. Optical properties of the films such as transmittance, reflectance and bandgap energy were investigated using a UV-visible spectrophotometer. According to atomic force microscopy, the surface ratio was maximized in 85 mol% concentration of WO3 similar to hydrophilicity.... 

The nitrate-citrate gel exhibits auto-catalytic behavior, which can be used to synthesize nanocrystalline YIG powders. In this study, yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of metal nitrates to citric acid molar ratio (MN/CA) of the precursor solution on the combustion behavior and crystallite size of synthesized powders was investigated by scanning electron microscopy (SEM), thermal analyses (DTA/TGA) and X-ray diffraction (XRD). The results show that with increasing MN/CA value, the combustion rate increases and the single-phase YIG forms at a higher temperature. The crystallite size of the single phase YIG... 

The nitrate-citrate gels exhibit auto-catalytic behavior, which can be used to synthesize the nanocrystalline YIG powders. In this study yttrium iron garnet (Y3Fe5O12) nanocrystalline powders were prepared by a sol-gel auto-combustion process. The influence of pH value of the precursor solution on the combustion behavior and the garnet phase formation of synthesized powders were investigated by scanning electron microscopy (SEM), thermal analysis (DTA/TGA), infrared (IR) spectroscopy and X-ray diffraction technique (XRD). The results show that with increasing pH value, the combustion rate increases. The as-burnt powder prepared with pH 1 yielded a single phase YIG after calcination at 800...