Sharif Digital Repository

More than 50 percent of countries in the world will likely face water stress or water shortages by 2025, and by 2050, as much as 75 percent of the world's population could face water scarcity. Desalination technologies, particularly the reverse osmosis (RO) process, have increasingly been adopted to produce freshwater from alternative sources such as seawater and brackish water due to water scarcity. However, desalination applications have always been limited by the disposal costs of RO brine and the adverse impact of brine on the receiving environment. The scope of this paper is to identify technically and commercially RO brine disposal and treatment methods such as deep well injection,... 

Increasing demand of fresh water, and limitation water resources, with respect to world economic growth brings up the importance of utilization of saline water. At the current research the sensitivity analysis of ROSA was conducted. For this analysis, a single stage reverse osmosis is designed for well water specifi cation in southern Tehran under following condition: Feed fl ow: 40 m3/h and membrane Element: BW30–400 FR. The sensitivity analyses for all chemical element of base water were performed. As a result of sensitivity analysis shortest sensitivity gap, belongs to boron, and longest sensitivity gap, belongs to calcium. Which refl ects, under the same conditions, the least element to... 

Crude oil desalter effluent from a Tehran oil refinery was treated by a hybrid UF/RO membrane separation process. Ultrafiltration (UF) was used primarily to remove the emulsified oil droplets followed by the removal of total dissolved solids (TDS) via reverse osmosis (RO). The UF membrane was a hydrophilic flat sheet polysulfone ultrafiltration membrane with MWCO of 100 kDa while the RO membrane was a spiral-wound thin-film composite polyamide. Effect of operating conditions such as transmembrane pressure and crossflow velocity were studied in UF pretreatment. The experimental results showed that the UF membrane removed more than 75% of the oil and can be considered as an effective... 

In this article, a new group contribution model is suggested for obtaining the thermodynamic properties of biomolecules in aqueous solutions. Accordingly, a Freed-FV model has been applied for the combinatorial free-volume term. The activity coefficients, solubilities, densities, and vapor pressures of amino acids and simple peptides in aqueous solutions were correlated, using the proposed group contribution model. Group interaction parameters of the proposed model were obtained by use of experimental data from amino acids available in the literature. The results demonstrate that the group contribution model can accurately correlate activity coefficient, solubility, density, and vapor... 

The canonical problems in control of the biped robots arise from underactuation, impulsive nature of the impact with the environment and existence of the many degrees of freedom in their mechanism. Since biped walkers have fewer actuators than degrees of freedom, they are underactuated mechanical systems. In this paper according to the humans and animals locomotion algorithms, the stability of an underactuated biped walker with point feet is done by central pattern generator and feedback networks. For tuning the parameters of the CPG network, the control problem is defined as an optimization problem. This optimization problem is solved by using of Genetic algorithm. Also a new feedback... 

In this work a modified form of the Ghotbi-Vera Mean Spherical Approximation model (MGV-MSA) has been used to correlate the mean ionic activity coefficients (MIAC) for a number of symmetric and asymmetric aqueous electrolyte solutions at 25 °C. In the proposed model the hard sphere as well as the electrostatic contributions to the MIAC and the osmotic coefficient of the previously GV-MSA model has been modified. The results of the proposed model for the MIAC of the electrolyte solutions studied in this work are used to directly calculate the values of the osmotic coefficients without introducing any new adjustable parameter. In the MGV-MSA model the cation diameter as well as the relative... 

As the membrane technology developed at the last 30 years, the relevant processes have been significantly developed. One of which is the chlor alkali technology. The development of membrane technology and its effect on Chlor-Alkali process is capable of evaluation in to two different fields, environmental and energy consumption. Some of environmental problems of mercury and diaphragm processes because of their technological development have been eliminated the energy consumption of these processes is significantly decreased especially in membrane and diaphragm processes. Recently investigation in the field of membrane cell is more focused on cell construction, depolarized cathodes, and fluid... 

Catalyst layers are one the important parts of the PEM fuel cells as they are the main place for electrochemical reaction taking place in anode and cathode of the cells. The amount of catalyst loading of this layer has a large effect on PEM fuel cell performance. Non-uniformity of reactant concentration could lead to a variation of current density in anode and cathode catalyst layer. The main reason for this phenomenon is porosity variation due to two effects: 1. compression of electrode on the solid landing area and 2. Water produced at the cathode side of diffusion layer. In this study the effect of variable current density in anode and cathode electrode on cell performance is... 

The GV-MSA, the BMCSL-MSA and the Pitzer models were used to correlate the individual, the mean ionic activity coefficients and the osmotic coefficients of symmetric and asymmetric electrolyte solutions. In order to compare the results obtained from the GV-MSA with those obtained from the Pitzer and the BMCSL-MSA models, the same experimental data and the same minimization procedure were used and the new sets of parameters for the BMCSL-MSA and the Pitzer models were also reported. The values for the osmotic coefficients of electrolyte solutions were calculated directly using the values of the mean ionic activity coefficients obtained from the models studied in this work. The results for the... 

Separation of multicomponent mixtures, in particular ternary systems, was investigated theoretically and experimentally. The interactions in various multicomponent mixtures were determined. Using data from literature as well as the limited data obtained in our laboratory, we identified the situations where the multicomponent effects are strong. A correlation between the coupled permeability coefficients and straight permeability coefficients and concentration of components in ternary systems was obtained. Capabilities of thermodynamic models in describing the electrolyte-nonelectrolyte systems consisting of a weak acid were also investigated. The results of this work show that the...